Studies were carried out by using electrophoretic method on the effects of the specific adsorption of the anions,such as SO4^2-,PO4^3-,and F^- ions,the cations,such as Ca^2+,Mn^2+,Zn^2+,and Cu^2+,ions,and the anions a...Studies were carried out by using electrophoretic method on the effects of the specific adsorption of the anions,such as SO4^2-,PO4^3-,and F^- ions,the cations,such as Ca^2+,Mn^2+,Zn^2+,and Cu^2+,ions,and the anions and cations coexisting,such as Zn^2+ and SO4^2= ions,on electrokinetic properties of the red soils as typical variable charge soils in China concerning variation in the specific ion species and concentrations,with an emphasis on the interaction between soil colloid surfaces and the ions in soil solutions.The results showed that the adsorption of specific ions led to a very pronounced decrease in zeta potentials of the soil colloids and a shift of the IEPs to lower values for specific anions,and an obvious increase in zeta potentials of the soil colloids and a shift of the IEPs to higher values for specific cations.Under circumstances of the specific anions and cations coexisting,for instance,Zn^2+ and SO4^2- ions,the zeta potentials changed with values higher than the value for SO4^2- alone and lower than that for Zn^2+ alone,and the IEP was between that for Zn^2+ and that for SO4^2-.The adsorption of Zn^2+ and Cu^2+ ions resulted in a reversal of the zeta potentials,and appearance of two IEPs for Zn^2+ and no IEP for Cu^2+,exhibiting interesting special effects of these kinds of metal ions.The higher the concentrations of the ions,the greater the change of the electrokinetic properties.展开更多
The contribution of iron and aluminum oxides to electrokinetic characteristics of variable charge soils was studied through determination of electrophoretic mobilities of the red soils treated with either removal of i...The contribution of iron and aluminum oxides to electrokinetic characteristics of variable charge soils was studied through determination of electrophoretic mobilities of the red soils treated with either removal of iron oxides or coating of aluminum oxides, and of those deferrated under natural conditions. After removal of the iron oxides, zeta potentials of the latosol and the red earth decreased obviously with a shift of IEP to a lower pH, from 6.4 to 5.3 and 4.1 to 2.4 for the former and the latter, respectively, and the electrokinetic change for the latosol was greater than for the red earth. Zeta potentials of the kaolinite sample increased markedly after coated with iron oxides. The striking effect of iron oxides on electrokinetic properties of the soils was also demonstrated by the electrokinetic differences between the samples from the red and white zones of a plinthitic horizon formed naturally, and between the samples from the gley and bottom horizons of a paddy soil derived from a red earth. The coatings of aluminum oxides on the latosol and the yellow earth made their zeta potentials rise pronouncedly and their IEPs move toward higher pHs, from 6.2 to 6.8 and 4.3 to 5.3 for the former and the latter, respectively. The samples with different particle sizes also exhibited some electrokinetic variation. The experiment showed that the effects of iron and aluminum oxides were closely related to the pH and type of the soils.展开更多
From the group movement of the bed load within the bottom layer,details of the nonlinear dynamic characteristics of bed load movement are discussed in this paper.Whether the sediment is initiated into motion correspon...From the group movement of the bed load within the bottom layer,details of the nonlinear dynamic characteristics of bed load movement are discussed in this paper.Whether the sediment is initiated into motion corresponds to whether the constant term in the equation is equal to zero.If constant term is zero and no dispersive force is considered,the equation represents the traditional Shields initiation curve,and if constant term is zero without the dispersive force being considered,then a new Shields curve which is much lower than the traditional one is got.The fixed point of the equation corresponds to the equilibrium sediment transport of bed load.In the mutation analysis,we have found that the inflection point is the demarcation point of breaking.In theory,the breaking point corresponds to the dividing boundary line,across which the bed form changes from flat bed to sand ripple or sand dune.Compared with the experimental data of Chatou Hydraulic Lab in France,the conclusions are verified.展开更多
This paper performs an experimental study for inverse load reconstruction. By measuring and analyzing the load characteristics of different home and office electric devices, the author shows that a reconstruction of t...This paper performs an experimental study for inverse load reconstruction. By measuring and analyzing the load characteristics of different home and office electric devices, the author shows that a reconstruction of the individual power consumption of different loads from the total measurement of a single power meter is possible.展开更多
Based on the dynamic triaxial test system and using the fitted wave of the Wenchuan earthquake and 1 Hz constant amplitude sinusoid,the paper compares the results of tests on undisturbed loess samples under different ...Based on the dynamic triaxial test system and using the fitted wave of the Wenchuan earthquake and 1 Hz constant amplitude sinusoid,the paper compares the results of tests on undisturbed loess samples under different loads and vibration modes but under same saturated conditions.Results of the comparative experiment show:The stress-strain curves have a similar trend under random seismic loading and constant amplitude sinusoidal loading,but the random seismic loading is more sensitive to failure strength of the undisturbed loess samples under the same stress.展开更多
文摘Studies were carried out by using electrophoretic method on the effects of the specific adsorption of the anions,such as SO4^2-,PO4^3-,and F^- ions,the cations,such as Ca^2+,Mn^2+,Zn^2+,and Cu^2+,ions,and the anions and cations coexisting,such as Zn^2+ and SO4^2= ions,on electrokinetic properties of the red soils as typical variable charge soils in China concerning variation in the specific ion species and concentrations,with an emphasis on the interaction between soil colloid surfaces and the ions in soil solutions.The results showed that the adsorption of specific ions led to a very pronounced decrease in zeta potentials of the soil colloids and a shift of the IEPs to lower values for specific anions,and an obvious increase in zeta potentials of the soil colloids and a shift of the IEPs to higher values for specific cations.Under circumstances of the specific anions and cations coexisting,for instance,Zn^2+ and SO4^2- ions,the zeta potentials changed with values higher than the value for SO4^2- alone and lower than that for Zn^2+ alone,and the IEP was between that for Zn^2+ and that for SO4^2-.The adsorption of Zn^2+ and Cu^2+ ions resulted in a reversal of the zeta potentials,and appearance of two IEPs for Zn^2+ and no IEP for Cu^2+,exhibiting interesting special effects of these kinds of metal ions.The higher the concentrations of the ions,the greater the change of the electrokinetic properties.
文摘The contribution of iron and aluminum oxides to electrokinetic characteristics of variable charge soils was studied through determination of electrophoretic mobilities of the red soils treated with either removal of iron oxides or coating of aluminum oxides, and of those deferrated under natural conditions. After removal of the iron oxides, zeta potentials of the latosol and the red earth decreased obviously with a shift of IEP to a lower pH, from 6.4 to 5.3 and 4.1 to 2.4 for the former and the latter, respectively, and the electrokinetic change for the latosol was greater than for the red earth. Zeta potentials of the kaolinite sample increased markedly after coated with iron oxides. The striking effect of iron oxides on electrokinetic properties of the soils was also demonstrated by the electrokinetic differences between the samples from the red and white zones of a plinthitic horizon formed naturally, and between the samples from the gley and bottom horizons of a paddy soil derived from a red earth. The coatings of aluminum oxides on the latosol and the yellow earth made their zeta potentials rise pronouncedly and their IEPs move toward higher pHs, from 6.2 to 6.8 and 4.3 to 5.3 for the former and the latter, respectively. The samples with different particle sizes also exhibited some electrokinetic variation. The experiment showed that the effects of iron and aluminum oxides were closely related to the pH and type of the soils.
基金Supported by National Natural Science Foundation of China (No.50809045 and No.40776045)National Basic Research Program of China ("973" Program)(No.2007CB714101)Ministry of Education’s New Century Elitist Project of China
文摘From the group movement of the bed load within the bottom layer,details of the nonlinear dynamic characteristics of bed load movement are discussed in this paper.Whether the sediment is initiated into motion corresponds to whether the constant term in the equation is equal to zero.If constant term is zero and no dispersive force is considered,the equation represents the traditional Shields initiation curve,and if constant term is zero without the dispersive force being considered,then a new Shields curve which is much lower than the traditional one is got.The fixed point of the equation corresponds to the equilibrium sediment transport of bed load.In the mutation analysis,we have found that the inflection point is the demarcation point of breaking.In theory,the breaking point corresponds to the dividing boundary line,across which the bed form changes from flat bed to sand ripple or sand dune.Compared with the experimental data of Chatou Hydraulic Lab in France,the conclusions are verified.
文摘This paper performs an experimental study for inverse load reconstruction. By measuring and analyzing the load characteristics of different home and office electric devices, the author shows that a reconstruction of the individual power consumption of different loads from the total measurement of a single power meter is possible.
基金sponsored by the Earthquake Professional Special Program of China Earthquake Administration (2008419031)
文摘Based on the dynamic triaxial test system and using the fitted wave of the Wenchuan earthquake and 1 Hz constant amplitude sinusoid,the paper compares the results of tests on undisturbed loess samples under different loads and vibration modes but under same saturated conditions.Results of the comparative experiment show:The stress-strain curves have a similar trend under random seismic loading and constant amplitude sinusoidal loading,but the random seismic loading is more sensitive to failure strength of the undisturbed loess samples under the same stress.