Corrosion behavior of 2024 Al-Cu-Mg alloy of different tempers was assessed by potentiodynamic polarization studies in 3.5% NaCl solution, 3.5% NaCI+I.0% H2O2 solution and 3.5% NaCl solution at pH 12. Polarization cu...Corrosion behavior of 2024 Al-Cu-Mg alloy of different tempers was assessed by potentiodynamic polarization studies in 3.5% NaCl solution, 3.5% NaCI+I.0% H2O2 solution and 3.5% NaCl solution at pH 12. Polarization curves showed shifting of corrosion potential (φPcor) towards more negative potential with increasing ageing time and shifting of φcorr in the positive direction with the addition of H2O2 in NaCl solution. Polarization curves in 3.5% NaCl solution at pH 12 exhibited distinct passivity phenomenon. Optical micrographs of the corroded surfaces showed general corrosion, extensive pitting and intergranular corrosion as well. Cyclic potentiodynamic polarization curves exhibited wide hysteresis loop and the mode of corrosion attack confirmed that the alloy states are susceptible to pit growth damage. Attempts were made to explain the observed corrosion behavior of the alloy of various tempers in different electrolytes with the help of microstructural features.展开更多
Phase diverse speckle is a novel kind of imaging technique and can be used to overcome image degradation from unknown phase aberrations, such as atmospheric turbulence. The wave-front phase expanded on the Zernike pol...Phase diverse speckle is a novel kind of imaging technique and can be used to overcome image degradation from unknown phase aberrations, such as atmospheric turbulence. The wave-front phase expanded on the Zernike polynomials is esti- mated from a pair of images (in the focal and out of focus planes). In this paper the principle of PDS is analyzed, and genetic algorithm is used as the iterative algorithm to simulate some characteristics, such as the influence of Zernike polynomials’ mode, amplitude of turbulence on the phase estimation. Thus, a new method for recovery of images is explored.展开更多
Acupoints and trigger points in traditional Chinese medicine represent two different minimally invasive therapy systems-based,respectively,on traditional acupuncture and dry needles.Many studies argue that trigger poi...Acupoints and trigger points in traditional Chinese medicine represent two different minimally invasive therapy systems-based,respectively,on traditional acupuncture and dry needles.Many studies argue that trigger points and traditional acupoints are conceptually similar because they generally have identical locations on the human body.However,whether trigger points contribute to the formation of the traditional acupuncture technique is controversial.Although many relevant studies have been conducted,this controversy continues to hinder the development of both disciplines.Recently,researchers of Chinese acupuncture have proposed the“acupoint sensitization”theory,which postulates that traditional acupoints may be sensitized by diseases,environments,and therapies.This turns them into a“sensitized state.”Recent studies suggest that trigger points and sensitized acupoints share similar biological properties.To clarify the above-mentioned confusion,we reviewed relevant studies on these two concepts and attempted to analyze their relationship.In this paper,we provide a general summary of acupoint sensitization theory and sensitized acupoints.We then compare trigger points with sensitized acupoints by categorizing their similarities and differences,including location and range,pathological morphology,pain perception,surface temperature effects,and bioelectrical properties.We believe that,because trigger points and sensitized acupoints have many shared properties,they might constitute“the same book with different covers.”展开更多
Electrochemical CO2 reduction reaction(CO2RR)powered by renewable electricity has emerged as the most promising technique for CO2 conversion,making it possible to realize a carbon‐neutral cycle.Highly efficient,robus...Electrochemical CO2 reduction reaction(CO2RR)powered by renewable electricity has emerged as the most promising technique for CO2 conversion,making it possible to realize a carbon‐neutral cycle.Highly efficient,robust,and cost‐effective catalysts are highly demanded for the near‐future practical applications of CO2RR.Previous studies on atomically dispersed metal‐nitrogen(M‐Nx)sites constituted of earth abundant elements with maximum atom‐utilization efficiency have demonstrated their performance towards CO2RR.This review summarizes recent advances on a variety of M‐Nx sites‐containing transition metal‐centered macrocyclic complexes,metal organic frameworks,and M‐Nx‐doped carbon materials for efficient CO2RR,including both experimental and theoretical studies.The roles of metal centers,coordinated ligands,and conductive supports on the intrinsic activity and selectivity,together with the importance of reaction conditions for improved performance are discussed.The mechanisms of CO2RR over these M‐Nx‐containing materials are presented to provide useful guidance for the rational design of efficient catalysts towards CO2RR.展开更多
The intensity distribution of depolarized field in the focal region of a high numerical-aperture optical system was investigated and found that the depolarization effect is tunable by the plate. The depolarization eff...The intensity distribution of depolarized field in the focal region of a high numerical-aperture optical system was investigated and found that the depolarization effect is tunable by the plate. The depolarization effect gains with the increase of the inner convergence angle of the phase plate, goes through a dramatic descent when the angle is larger than 30°, and begins to come back when the angle reaches a threshold of respectively 60°and 65° for the orthogonal diffractive field and the longitudinal diffractive fields. This reveals two convergence points where the depolarization effect is the strongest and weakest, respectively, suggesting that the pure phase plate can be a promising method for altering depolarization diffractive fields and constructing optical instruments.展开更多
Tandem electrocatalysis is an emerging concept for effective electrochemical CO_(2) reduction reaction(CO_(2)RR)towards multicarbons(C_(2+)).This decouples the multiple steps of CO_(2)-to-C_(2+)into two steps of CO_(2...Tandem electrocatalysis is an emerging concept for effective electrochemical CO_(2) reduction reaction(CO_(2)RR)towards multicarbons(C_(2+)).This decouples the multiple steps of CO_(2)-to-C_(2+)into two steps of CO_(2)-to-CO and CO-to-C_(2+)catalyzed by individual catalysts,to improve the Faradic efficiency(FE).However,due to the mass-transport limitation of CO from the generation site to the long-distance consumption site,such a strategy still remains challenge for high-rate production of C_(2+)products.Herein,we designed CuO/Ni single atoms tandem catalyst,which made the catalytic sites of Ni and Cu for independently catalyzing CO_(2)-to-CO and CO-to-C_(2+)compactly neighbored,enabling the in-situ generation and rapid consumption of CO.The CuO/Ni SAs tandem catalyst achieved a particularly high partial current density of C_(2+)products(1220.8 mA/cm^(2)),while still maintained outstanding C_(2+)products FE(81.4%)and excellent selectivities towards ethylene(FE 54.1%)and ethanol(FE 28.8%),enabling the profitable production of multicarbons by CO_(2)RR.展开更多
文摘Corrosion behavior of 2024 Al-Cu-Mg alloy of different tempers was assessed by potentiodynamic polarization studies in 3.5% NaCl solution, 3.5% NaCI+I.0% H2O2 solution and 3.5% NaCl solution at pH 12. Polarization curves showed shifting of corrosion potential (φPcor) towards more negative potential with increasing ageing time and shifting of φcorr in the positive direction with the addition of H2O2 in NaCl solution. Polarization curves in 3.5% NaCl solution at pH 12 exhibited distinct passivity phenomenon. Optical micrographs of the corroded surfaces showed general corrosion, extensive pitting and intergranular corrosion as well. Cyclic potentiodynamic polarization curves exhibited wide hysteresis loop and the mode of corrosion attack confirmed that the alloy states are susceptible to pit growth damage. Attempts were made to explain the observed corrosion behavior of the alloy of various tempers in different electrolytes with the help of microstructural features.
文摘Phase diverse speckle is a novel kind of imaging technique and can be used to overcome image degradation from unknown phase aberrations, such as atmospheric turbulence. The wave-front phase expanded on the Zernike polynomials is esti- mated from a pair of images (in the focal and out of focus planes). In this paper the principle of PDS is analyzed, and genetic algorithm is used as the iterative algorithm to simulate some characteristics, such as the influence of Zernike polynomials’ mode, amplitude of turbulence on the phase estimation. Thus, a new method for recovery of images is explored.
基金financially supported by the National Natural Science Foundation of China(Nos.81590951,81973962,82004486)the National Key Research and Development Project(No.2019YFC1709701)+1 种基金the Key Research and Development Project of Science and Technology Department of Sichuan Province(Nos.2020YFS0304,2021YFS0087)Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine.(No.ZYYCXTD-D-202003).
文摘Acupoints and trigger points in traditional Chinese medicine represent two different minimally invasive therapy systems-based,respectively,on traditional acupuncture and dry needles.Many studies argue that trigger points and traditional acupoints are conceptually similar because they generally have identical locations on the human body.However,whether trigger points contribute to the formation of the traditional acupuncture technique is controversial.Although many relevant studies have been conducted,this controversy continues to hinder the development of both disciplines.Recently,researchers of Chinese acupuncture have proposed the“acupoint sensitization”theory,which postulates that traditional acupoints may be sensitized by diseases,environments,and therapies.This turns them into a“sensitized state.”Recent studies suggest that trigger points and sensitized acupoints share similar biological properties.To clarify the above-mentioned confusion,we reviewed relevant studies on these two concepts and attempted to analyze their relationship.In this paper,we provide a general summary of acupoint sensitization theory and sensitized acupoints.We then compare trigger points with sensitized acupoints by categorizing their similarities and differences,including location and range,pathological morphology,pain perception,surface temperature effects,and bioelectrical properties.We believe that,because trigger points and sensitized acupoints have many shared properties,they might constitute“the same book with different covers.”
基金supported by the National Key R&D Program of China(2017YFA0700102)the National Natural Science Foundation of China(21573222 and 91545202)+1 种基金the Outstanding Youth Talent Project of Dalian(2017RJ03)the DMTO Project of Dalian Institute of Chemical Physics,CAS(DICP DMTO201702),the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17020200),the Youth Innovation Promotion Association,CAS(2015145)~~
文摘Electrochemical CO2 reduction reaction(CO2RR)powered by renewable electricity has emerged as the most promising technique for CO2 conversion,making it possible to realize a carbon‐neutral cycle.Highly efficient,robust,and cost‐effective catalysts are highly demanded for the near‐future practical applications of CO2RR.Previous studies on atomically dispersed metal‐nitrogen(M‐Nx)sites constituted of earth abundant elements with maximum atom‐utilization efficiency have demonstrated their performance towards CO2RR.This review summarizes recent advances on a variety of M‐Nx sites‐containing transition metal‐centered macrocyclic complexes,metal organic frameworks,and M‐Nx‐doped carbon materials for efficient CO2RR,including both experimental and theoretical studies.The roles of metal centers,coordinated ligands,and conductive supports on the intrinsic activity and selectivity,together with the importance of reaction conditions for improved performance are discussed.The mechanisms of CO2RR over these M‐Nx‐containing materials are presented to provide useful guidance for the rational design of efficient catalysts towards CO2RR.
基金Funded by the Natural Science Foundation of China under the Grant No. 60608009.
文摘The intensity distribution of depolarized field in the focal region of a high numerical-aperture optical system was investigated and found that the depolarization effect is tunable by the plate. The depolarization effect gains with the increase of the inner convergence angle of the phase plate, goes through a dramatic descent when the angle is larger than 30°, and begins to come back when the angle reaches a threshold of respectively 60°and 65° for the orthogonal diffractive field and the longitudinal diffractive fields. This reveals two convergence points where the depolarization effect is the strongest and weakest, respectively, suggesting that the pure phase plate can be a promising method for altering depolarization diffractive fields and constructing optical instruments.
基金supported by the National Key R&D Program of China(2020YFA0710200)the DNL Cooperation Fund,Chinese Academy of Sciences(DNL201918)+6 种基金the Fundamental Research Funds for the Central Universities(WK2060000004,WK2060000021,WK2060000025,KY2060000180,and KY2060000195)the National Natural Science Foundation of China(21805191)Pengcheng Scholar Program,China Postdoctoral Science Foundation(2019M653004)Shenzhen Peacock Plan(KQTD2016053112042971)Shenzhen Science and Technology Program(JCYJ20190808142001745,JCYJ20200812160737002,and RCJC20200714114434086)Guangdong Basic and Applied Basic Research Foundation(2020A1515010982)Shenzhen Stable Support Project(20200812122947002)。
文摘Tandem electrocatalysis is an emerging concept for effective electrochemical CO_(2) reduction reaction(CO_(2)RR)towards multicarbons(C_(2+)).This decouples the multiple steps of CO_(2)-to-C_(2+)into two steps of CO_(2)-to-CO and CO-to-C_(2+)catalyzed by individual catalysts,to improve the Faradic efficiency(FE).However,due to the mass-transport limitation of CO from the generation site to the long-distance consumption site,such a strategy still remains challenge for high-rate production of C_(2+)products.Herein,we designed CuO/Ni single atoms tandem catalyst,which made the catalytic sites of Ni and Cu for independently catalyzing CO_(2)-to-CO and CO-to-C_(2+)compactly neighbored,enabling the in-situ generation and rapid consumption of CO.The CuO/Ni SAs tandem catalyst achieved a particularly high partial current density of C_(2+)products(1220.8 mA/cm^(2)),while still maintained outstanding C_(2+)products FE(81.4%)and excellent selectivities towards ethylene(FE 54.1%)and ethanol(FE 28.8%),enabling the profitable production of multicarbons by CO_(2)RR.