Modified humic acid (MHA) binder based on lignite humic substances is a novel sort of promising organic binder for iron ore pellets.Humic acid (HA) is one of the main ingredients of MHA binder.Pure HA was firstly isol...Modified humic acid (MHA) binder based on lignite humic substances is a novel sort of promising organic binder for iron ore pellets.Humic acid (HA) is one of the main ingredients of MHA binder.Pure HA was firstly isolated from lignite and then adsorption of HA onto magnetite particle surface was investigated.The final results indicate that the adsorption of HA onto magnetite surface accords with Langmuir model well,and it is evidently influenced by the initial HA concentration and solution pH value.Adsorption depends on chemical interaction at pH values above the PZC (the pH where the Zeta potentials of minerals are zero) of magnetite,while electrostatic attraction and chemical interaction both contribute to the adsorption at pH values below the PZC.展开更多
The interaction of cationic gemini surfactants(alkanediyl-α,ω-bis(alkyl dimethylammonium bromide)) with an antipsychotic drug(chlorpromazine hydrochloride(CPZ)) has been investigated. Various micellar and interfacia...The interaction of cationic gemini surfactants(alkanediyl-α,ω-bis(alkyl dimethylammonium bromide)) with an antipsychotic drug(chlorpromazine hydrochloride(CPZ)) has been investigated. Various micellar and interfacial parameters have been deliberated by surface tension measurement to report the nature of interactions between drug and novel surfactant mixtures. The behavior of mixed systems, their compositions and activities of components have been analyzed in the light of Rubingh's theory. The results indicate synergism in the binary mixtures.The binding study between CPZ and surfactants has been done by spectroscopic techniques such as UV–visible and fluorescence. The results are discussed in the light of the use of gemini surfactants as promising drug delivery agents for phenothiazine drugs, and hence, improve their bioavailability.展开更多
基金Project(50804059) supported by the National Natural Science Foundation of ChinaProject(50725416) supported by the National Natural Science Funds for Distinguished Young Scholars of China
文摘Modified humic acid (MHA) binder based on lignite humic substances is a novel sort of promising organic binder for iron ore pellets.Humic acid (HA) is one of the main ingredients of MHA binder.Pure HA was firstly isolated from lignite and then adsorption of HA onto magnetite particle surface was investigated.The final results indicate that the adsorption of HA onto magnetite surface accords with Langmuir model well,and it is evidently influenced by the initial HA concentration and solution pH value.Adsorption depends on chemical interaction at pH values above the PZC (the pH where the Zeta potentials of minerals are zero) of magnetite,while electrostatic attraction and chemical interaction both contribute to the adsorption at pH values below the PZC.
基金Chemistry Department and Centre of Excellence for Advanced Materials Research, King Abdulaziz University
文摘The interaction of cationic gemini surfactants(alkanediyl-α,ω-bis(alkyl dimethylammonium bromide)) with an antipsychotic drug(chlorpromazine hydrochloride(CPZ)) has been investigated. Various micellar and interfacial parameters have been deliberated by surface tension measurement to report the nature of interactions between drug and novel surfactant mixtures. The behavior of mixed systems, their compositions and activities of components have been analyzed in the light of Rubingh's theory. The results indicate synergism in the binary mixtures.The binding study between CPZ and surfactants has been done by spectroscopic techniques such as UV–visible and fluorescence. The results are discussed in the light of the use of gemini surfactants as promising drug delivery agents for phenothiazine drugs, and hence, improve their bioavailability.