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甲烷对合成气层流预混火焰传播特性的影响 被引量:2
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作者 尚融雪 李刚 张培红 《中国安全科学学报》 CAS CSCD 北大核心 2019年第1期74-80,共7页
为研究甲烷对合成气层流预混火焰化学动力学特征及合成气层流预混火焰传播特性的影响,选用GRI3.0-机理,模拟研究300 K条件下含0~70%甲烷的合成气层流预混火焰传播速度、火焰温度、反应敏感性及重要自由基浓度等。结果表明:合成气层流... 为研究甲烷对合成气层流预混火焰化学动力学特征及合成气层流预混火焰传播特性的影响,选用GRI3.0-机理,模拟研究300 K条件下含0~70%甲烷的合成气层流预混火焰传播速度、火焰温度、反应敏感性及重要自由基浓度等。结果表明:合成气层流预混火焰传播速度、绝热火焰温度随甲烷比例的增加非线性下降,火焰传播速度峰值对应的当量比随甲烷增加显著向贫燃侧发展;富燃条件下,随着甲烷少量加入(≤30%),火焰中自由基H浓度显著下降,火焰传播速度受抑制作用显著;随着甲烷的继续增加,不足的自由基OH抑制自由基CH_3的生成,影响自由基H的消耗,削弱CH_4对层流预混火焰传播速度的抑制作用。 展开更多
关键词 合成气 甲烷 层流预混火焰 敏感性分析 化学动力学特征
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Rock-forming mechanism of Qingshanjiao intrusion in Dongguashan copper(gold) deposit, Tongling area, Anhui province, China
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作者 刘忠法 邵拥军 +1 位作者 隗含涛 汪程 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第9期2449-2461,共13页
Dongguashan deposit is a large porphyry-skarn copper(gold) deposit in Tongling ore district. The Qingshanjiao intermediate acid intrusion of Yanshanian had a direct genetic relationship with mineralization. The magm... Dongguashan deposit is a large porphyry-skarn copper(gold) deposit in Tongling ore district. The Qingshanjiao intermediate acid intrusion of Yanshanian had a direct genetic relationship with mineralization. The magma origin, rock-forming dynamic background and rock-forming process were studied, and the rock-forming mechanism of Qingshanjiao intrusion was discussed, based on geological characteristics, detailed observation of petrography and systematic investigation of petrochemistry, trace elements and REE geochemistry characteristics of Qingshanjiao intrusion. The results show that Qingshanjiao rock body belongs to high-K calc-alkaline series with higher LREE elements, Th, Rb and Sr abundance, but depleted in HREE elements, Ba, Nb and Ta. The primary magma originated from the mantle-crust mixtures which were caused by basaltic magma of mantle mixing with syenite magma of partial melting of the lower crust, and the formation environment of Qingshanjiao intrusion was emplaced in the transitional environment from compression to extension. The Harker diagram and hybrid structures of plagioclase and potassium feldspar indicate that the fractional crystallization occurred in the process of magmatic evolution. The petrochemistry, trace elements and REE geochemistry characteristics indicate that the magma was contaminated by crustal material during the rock-forming. These results suggested that the Qingshanjiao intrusion was formed by fractional crystallization and assimilation and hybridization of mantle-crust magma in the transitional environment from compression to extensional. 展开更多
关键词 Qingshanjiao intrusion geological and geochemical characteristics rock-forming and geodynamic setting magma derivation rock-forming Dongguashan copper(gold) deposit
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Mantle geochemistry: Insights from ocean island basalts 被引量:12
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作者 HUANG ShiChun ZHENG YongFei 《Science China Earth Sciences》 SCIE EI CAS CSCD 2017年第11期1976-2000,共25页
The geochemical study of the Earth's mantle provides important constraints on our understanding of the formation and evolution of Earth, its internal structure, and the mantle dynamics. The bulk Earth composition ... The geochemical study of the Earth's mantle provides important constraints on our understanding of the formation and evolution of Earth, its internal structure, and the mantle dynamics. The bulk Earth composition is inferred by comparing terrestrial mantle rocks with chondrites, which leads to the chondritic Earth model. That is, Earth has the same relative proportions of refractory elements as that in chondrites, but it is depleted in volatiles. Ocean island basalts(OIB) may be produced by mantle plumes with possible deep origins; consequently, they provide unique opportunity to study the deep Earth. Isotopic variations within OIB can be described using a limited number of mantle endmembers, such as EM1, EM2 and HIMU, and they have been used to decipher important mantle processes. Introduction of crustal material into the deep mantle via subduction and delamination is important in generating mantle heterogeneity; however, there is active debate on how they were sampled by mantle melting, i.e.,the role of olivine-poor lithologies in the OIB petrogenesis. The origin and location of high 3He/4He mantle remain controversial,ranging from unprocessed(or less processed) primitive material in the lower mantle to highly processed materials with shallow origins, including ancient melting residues, mafic cumulates under arcs, and recycled hydrous minerals. Possible core-mantle interaction was hypothesized to introduce distinctive geochemical signatures such as radiogenic 186 Os and Fe and Ni enrichment in the OIB. Small but important variations in some short-lived nuclides, including 142 Nd, 182 W and several Xe isotopes, have been reported in ancient and modern terrestrial rocks, implying that the Earth's mantle must have been differentiated within the first 100 Myr of its formation, and the mantle is not efficiently homogenized by mantle convection. 展开更多
关键词 Mantle structure Mantle composition Crustal components Crust-mantle interaction Crustal recycling
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