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燃料电池——并不十分遥远的环保型电化学发动机 被引量:2
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作者 陆天虹 邢巍 《新材料产业》 2003年第9期23-29,共7页
关键词 燃料电池 化学发动机 环境保护 阴极 阳极 电解质
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联合循环内可逆等温化学发动机最优特性
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作者 何广坤 陈林根 孙丰瑞 《电站系统工程》 1997年第5期45-47,共3页
分析由两级串接组成的联合循环内可逆等温化学发动机性能,导出其最佳功率输出与效率关系。
关键词 有限时间热力学 化学发动机 联合循环
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燃料电池的未来——用于车辆的电化学发动机 被引量:1
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作者 A.JohnAppleby 向俊 郭凯声 《科学》 1999年第10期32-39,共8页
1839年,英国物理学家William R.Grove证实氢和氧的电化学结合能发电。但是,人们对基于此概念的燃料电池所持的好奇心仍只限于实验室范围内。这种状况持续了一个多世纪,直到20世纪60年代,美国国家航空航天管理局开始使用轻巧的——... 1839年,英国物理学家William R.Grove证实氢和氧的电化学结合能发电。但是,人们对基于此概念的燃料电池所持的好奇心仍只限于实验室范围内。这种状况持续了一个多世纪,直到20世纪60年代,美国国家航空航天管理局开始使用轻巧的——也是昂贵的设备作为宇宙飞船的能量来源。今天,这项可望实现清洁、高效和安静运行的技术正被竭力推荐为众多应用服务,包括移动电话、便携式计算机、汽车及家庭电源供给。 展开更多
关键词 燃料电池 车辆 化学发动机 铂催化剂
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内可逆化学发动机最佳功率与效率的关系
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作者 曹水 陈林根 孙丰瑞 《电站系统工程》 1997年第4期46-49,共4页
分析有限时间约束条件下等温化学发动机的性能,导出内可逆化学发动机最佳功率与效率间的关系和最大功率输出时的性能界限。对化学发动机与热动力循环性能作了比较。
关键词 有限时间热力学 化学发动机 最佳功率
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低推力化学火箭发动机技术
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作者 陈祖奎 王衍芳 《火箭推进》 CAS 1994年第2期17-36,共20页
本文回顾了旨在改进星船上推进系统应用的低推力化学火箭发动机的性能而正在进行的研究计划。通过建立燃烧和流动物理过程的新的预估方法;采用高温材料;改进部件设计优化性能;利用高性能推进剂等项措施.提高低推力化学火箭发动机的性能... 本文回顾了旨在改进星船上推进系统应用的低推力化学火箭发动机的性能而正在进行的研究计划。通过建立燃烧和流动物理过程的新的预估方法;采用高温材料;改进部件设计优化性能;利用高性能推进剂等项措施.提高低推力化学火箭发动机的性能和工作寿命。改进的预估方法是通过局部和全局的预估值与试验数据的比较得到的。预估值是从有限反应速率动力学的 RPLUS Navier-Stokes 的计算机程序和联合军队、宇航局的方法中得出的。数据是从激光珍断系统和发动机试车实测性能得到的。结果表明,喷注器和燃烧过程的模型需要改进,流动显影技术,例如二维激光—感应莹光(LIF)显影技术对解决流动对称和剪切层的燃烧过程有所帮助。高温材料的制造工艺还在探索中,利用这些材料的小发动机正在进行设计、生产和试验工作。防氧化的铼涂铱保护层用化学气桕沉积工艺制成,从而使燃烧室工作温度升高800K。在地球可贮存推进剂(四氧化二氮和-甲基肼或无水肼)的发动机上,取消液膜冷却,改善燃烧效率.并控制喷注器的热沉温度,通过组合件的重新没计。获得了性能增益。铼铱两种材料互相扩散情况和抗氧化特性表明,推力室要求的几十小时的使用寿命是可以达到的。推力为22、62、440和559N 的火箭发动机已经设计、生产和试验了。试验证明,比冲性能提高了98~196N·S/kg。更高性能的推进剂通过了鉴定。这些推进剂(定义为空间可贮存推进剂),包括作为氧化剂的液氧,作为燃料的氮氢化合物或碳氢化合物。为此,专门设计和生产了液氧/肼发动机,其特征速度效率高达95%,面积比204:1时换算的真空比冲为3381N·S/kg。利用液氧/液氢推进剂,尤其在载人飞船上,其比冲性能可以得到进一步的提高,然而,某些特殊的设计必须改进,并通过飞行考核进一步完善。 展开更多
关键词 低推力化学火箭发动机
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鲜为人知的苏联核火箭发动机项目
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作者 张雪松 《太空探索》 2021年第3期62-65,共4页
空间活动能力的核心是推进系统,而推进系统发动机的比冲量,直接决定了空间活动的范围和规模。传统化学火箭发动机受到推进剂能量的限制,高能氢氧推进剂的理论最大比冲也只有520秒,实用氢氧发动机更是只有465秒。相比化学能推进剂,核物... 空间活动能力的核心是推进系统,而推进系统发动机的比冲量,直接决定了空间活动的范围和规模。传统化学火箭发动机受到推进剂能量的限制,高能氢氧推进剂的理论最大比冲也只有520秒,实用氢氧发动机更是只有465秒。相比化学能推进剂,核物质蕴含的能量要高得多,核火箭发动机能实现更高的比冲,具有光明的应用前景,核火箭发动机也得到了航天强国的高度重视。 展开更多
关键词 氢氧发动机 核火箭发动机 航天强国 化学火箭发动机 比冲量 核物质 化学 推进剂
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英航天局与罗罗开展空间核动力技术合作
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作者 伍浩松 李颖涵 《国外核新闻》 2021年第2期10-10,共1页
【英国罗尔斯·罗伊斯公司网站2021年1月12日报道】英国罗尔斯·罗伊斯公司(Rolls-Royce)近日与英国航天局(UKSA)签署合同,未来将合作开展空间核动力技术研究。航天局表示,核推进系统可以将前往火星的时间缩短到3至4个月,大约... 【英国罗尔斯·罗伊斯公司网站2021年1月12日报道】英国罗尔斯·罗伊斯公司(Rolls-Royce)近日与英国航天局(UKSA)签署合同,未来将合作开展空间核动力技术研究。航天局表示,核推进系统可以将前往火星的时间缩短到3至4个月,大约是使用化学发动机所需时间的一半。 展开更多
关键词 空间核动力 签署合同 化学发动机 核推进 罗尔斯
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世界电动汽车发展动态
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《机电新产品导报》 1996年第Z4期54-55,共2页
日本 丰田新型电动汽车已投入试用。此车的特点是加大了蓄电能量,用镍氢蓄电池代替铅酸蓄电池,克服了电动汽车行驶距离不足的问题。新电池的电解质使用氢氧化钾,正极为镍,负极为含氢合金,其蓄电量约为铅酸蓄电池的2倍。将其装在RAV-4型... 日本 丰田新型电动汽车已投入试用。此车的特点是加大了蓄电能量,用镍氢蓄电池代替铅酸蓄电池,克服了电动汽车行驶距离不足的问题。新电池的电解质使用氢氧化钾,正极为镍,负极为含氢合金,其蓄电量约为铅酸蓄电池的2倍。将其装在RAV-4型跑车上,一次充电行驶距离要比铅酸蓄电池多120~200km。丰田公司决定由美国加州电力公司及日本爱知县试用该车2年,以便收集必要的数据。 展开更多
关键词 电动汽车 铅酸蓄电池 化学发动机 金属间化合物 铝空气电池 美国通用汽车公司 燃料电池 含氢合金 镍氢蓄电池 距离不足
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Automated bolting and meshing on a continuous miner for roadway development 被引量:4
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作者 van Duin Stephen Meers Luke +1 位作者 Donnelly Peter Oxley Ian 《International Journal of Mining Science and Technology》 SCIE EI 2013年第1期55-61,共7页
Automated installation of primary roof support material can potentially increase productivity and operator safety in the roadway development process within underground coal mining. Although the broader manufacturing s... Automated installation of primary roof support material can potentially increase productivity and operator safety in the roadway development process within underground coal mining. Although the broader manufacturing sector has benefited from automation, several challenges exist within the Australian underground coal industry which makes it difficult to fully exploit these technologies. At the University of Wollongong a series of reprogrammable electromechanical manipulators have been designed to overcome these challenges and automatically handle the installation of roof and rib containment consumables on a continuous miner. The automated manipulation removes personnel from hazards in the immediate face area, particularly those associated with working in a confined and unstable working environment in close proximity to rotating and moving equipment. In a series of above ground trials the automated system was successfully demonstrated without human intervention and proven to be capable of achieving cycle times at a rate of 10 m per operating hour, consistent with that required to support high capacity longwall mines. The trials also identified a number of refinements which could further improve both cycle times and system reliability when considering the technology for underground use. The results have concluded that conventional manual handling practices on a continuous miner can be eliminated, and that the prototypes have significantly reduced the technical risk in proceeding to a full underground trial. 展开更多
关键词 Automation Robotics Roadway development Manipulation Roof support
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等离子火箭! 一级准备!
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作者 桂祺莹 无右 郝鹏飞 《新知客》 2009年第9期80-83,共4页
从地球到火星,传统的液体火箭需要250天。而等离子火箭能把这段旅途缩短至一个多月。一位传奇的航天员兼物理学家正在准备将它带上太空。
关键词 离子火箭 液体火箭 化学火箭发动机 地球时 至一 发动机工作时间 离子推进 发动机点火 ROCKET
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Study on Using Mixed Fuel of Jet Fuel/Gasoline as Fuel of Gasoline Engine
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作者 L.L. Ren B. Su J. Qu 《Journal of Energy and Power Engineering》 2011年第4期300-307,共8页
This paper has integrated various methods such as laboratory physical and chemical analysis, engine bench test and actual road test, etc. to conduct a feasibility study on the emergency alternative fuel of gasoline by... This paper has integrated various methods such as laboratory physical and chemical analysis, engine bench test and actual road test, etc. to conduct a feasibility study on the emergency alternative fuel of gasoline by mixed jet fuel and gasoline. The study shows that both the evaporability and anti-knock quality decrease after mixing jet fuel with gasoline. While the mixing proportion increases, the engine power decreases and the fuel consumption increases gradually. When the proportion reaches 40%, the engine power drops by 5.3% to 11.7%, the fuel consumption rises by an average of 3.8%, and meantime the oil dilution and emission of the engine power become worse. Therefore, as for the gasoline engine, the mixed oil can only be used as emergency alternative fuel due to its harm to the engine. 展开更多
关键词 Auto gasoline jet fuel EMERGENCY SUBSTITUTE engine.
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Matching between mechanics and thermodynamics among 4 individual strokes in a 4-stroke engine by non-circular gear mechanism
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作者 ZHAO Yuan-ping HE Chang-hua 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第7期2112-2126,共15页
The relationship between engine mechanics and thermo-dynamics has been investigated by means of numerical simulation.The inherent mismatching between the mechanical behaviors and the thermodynamic process in internal ... The relationship between engine mechanics and thermo-dynamics has been investigated by means of numerical simulation.The inherent mismatching between the mechanical behaviors and the thermodynamic process in internal combustion engine is identified,which is believed to be one of the important limiting factors of energy efficiency for conventional engines available in the current market.An approach for engine efficiency improvement through optimal matching between mechanics and thermodynamics(OMBMT)is proposed.An ideal matching model is defined and the conflicts due to the constraints among the mapping strokes in a 4-stroke engine are analyzed.A novel mechanical model is built for approaching optimal matching among all 4 individual strokes in a 4-stroke spark-ignition engine,which is composed of non-circular gears(NCG)and integrated with conventional slider crank engine mechanism.By means of digital mechanical model and numerical simulation,the matching gains among all 4 strokes are defined and calculated for quantifying the NCG engine efficiency improvement by comparing with a baseline engine.The potentials with the OMBMT implemented and the enhancements made by NCG mechanism for engines in terms of overall engine efficiency are reported.Based on the results achieved,it is recommended that the feasibility studies and the experimental validations should be conducted to verify the engine matching concept and effectiveness of the NCG mechanism engine model proposed,and the engine performance and NCG design parameters should be further optimized. 展开更多
关键词 ENGINE engine matching optimization optimal matching between mechanics and thermodynamics(OMBMT) matching gain engine efficiency improvement non-circular gears(NCG) NCG engine
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燃料电池 被引量:1
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作者 朱海峰 金碧辉 《中国基础科学》 2005年第4期12-13,F0002,共3页
19世纪,科学家更多地从原子层次上认识和研究化学。20世纪科学家则更多地从分子层次上认识和研究化学。进入21世纪,化学会在哪些方面取得重大突破?会遇到哪些挑战和难题?什么是未来化学的新生长点?化学在整个科学体系中占有什么地位?这... 19世纪,科学家更多地从原子层次上认识和研究化学。20世纪科学家则更多地从分子层次上认识和研究化学。进入21世纪,化学会在哪些方面取得重大突破?会遇到哪些挑战和难题?什么是未来化学的新生长点?化学在整个科学体系中占有什么地位?这些都是对化学有全局性、战略性指导意义的问题。中国科学院院士徐光宪先生曾说过这样一段耐人寻味的话,“我的专业是化学,我从学化学、教化学、到研究化学已有几十年了,可是现在我却有点搞不清楚化学的定义了。我深深感到科学的发展太快了,需要对本门科学重新认识、重新定位,这是我进入21世纪首先要关注的问题”。在新的世纪如何定位和审视化学,《世界科学前沿发展态势分析》课题组对此进行了探讨。课题组首先选定了化学领域具有代表性的20种期刊,对这些期刊1999—2003年出现的关键词进行了统计分析,确定出了化学领域这几年的热点词,并通过与有关专家进行研讨,进一步整合出了下面13个重要研究方向催化不对称合成、单分子、多孔材料、分子器件、光子晶体、化学动力学、活性自由基聚合、密度泛函理论、酶催化、烯烃复分解反应、组合化学、超分子化学分子自组装、燃料电池。课题组针对这些研究方向,邀请国内专家学者就这些研究方向的发展趋势进行了分析,同时佐以文献计量学分析。通过定性与定量分析,课题组注意到,中国科学家对于化学领域的重要研究方向已经具备一定的鉴赏能力,但是在科学问题的选择上还普遍缺乏具有挑战性的切入点。在目前已经具有论文数量基础的一些重要研究方向上,中国科学家需要更密切关注国际同行的研究进展,高度重视科学问题的选择,同时也需要注意在第一时间发表原创性科研成果的问题。本刊上期已对催化不对称合成、单分子、多孔材料、分子器件、光子晶体、化学动力学、活性自由基聚合和密度泛函理论8个方向进行了介绍,本期将对酶催化、烯烃复分解反应、组合化学、超分子化学分子自组装、燃料电池等后5个方向进行介绍。 展开更多
关键词 燃料电池 化学发动机 化学过程 发展趋势 直接转化 能源产业 21世纪 直流电
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用离子推进飞船 被引量:1
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作者 方晨 《科学世界》 2018年第12期94-100,共7页
充满科幻感的“离子发动机”,现在已经越来越多地实际应用在航天器上。它的工作机制是什么,有哪些独到的本领?能完全取代传统的化学发动机吗?科幻作品中的常客看2015年的科幻大片《火星救援))(The Marian)时,你有没有想过,影... 充满科幻感的“离子发动机”,现在已经越来越多地实际应用在航天器上。它的工作机制是什么,有哪些独到的本领?能完全取代传统的化学发动机吗?科幻作品中的常客看2015年的科幻大片《火星救援))(The Marian)时,你有没有想过,影片里那艘往返于地球和火星之间的大型飞船赫尔墨斯号(Hermes),需要使用什么样的发动机? 展开更多
关键词 离子推进 飞船 离子发动机 科幻作品 化学发动机 航天器 火星
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Study on Aerodynamic Design Optimization of Turbomachinery Blades 被引量:3
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作者 Naixing CHEN Hongwu ZHANG Weiguang HUANG Yanji XU 《Journal of Thermal Science》 SCIE EI CAS CSCD 2005年第4期298-304,320,共8页
This paper describes the study on aerodynamics design optimization of turbomachinery blading developed by the authors at the Institute of Engineering Thermophysics, Chinese Academy of Sciences, during the recent few y... This paper describes the study on aerodynamics design optimization of turbomachinery blading developed by the authors at the Institute of Engineering Thermophysics, Chinese Academy of Sciences, during the recent few years. The present paper describes the aspects mainly on how to use a rapid approach of profiling a 3D blading and of grid generation for computation, a fast and accurate viscous computation method and an appropriate optimization methodology_ including a blade parameterization algorithm to optimize tm-bomachinery blading aerodynamically. Any blade configuration can be expressed by three curves, they are the camber lines, the thickness distributions and the radial stacking line, and then the blade geometry can be easily parameterized by a number of parameters with three polynomials. A gradient-based parameterization analytical method and a response surface method were applied herein for blade optimization. It was found that the optimization process provides reliable design for turbomachinery with reasonable computing time. 展开更多
关键词 aerodynamic design optimization response surface method blade parameterization 3D aerodynamics of turbomachinery.
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Thermodynamic analysis for a chemically recuperated scramjet 被引量:2
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作者 QIN Jiang BAO Wen +2 位作者 ZHANG SiLong SONG YuFei YU DaRen 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第11期3204-3212,共9页
Endothermic hydrocarbon fuel is regarded as an optimal fuel for a scramjet with regenerative cooling,which provides extra cooling through endothermic chemical conversion to avoid the severly limited cooling capacity w... Endothermic hydrocarbon fuel is regarded as an optimal fuel for a scramjet with regenerative cooling,which provides extra cooling through endothermic chemical conversion to avoid the severly limited cooling capacity when conventional fuels are adopted for cooling.Although endothermic cooling is proposed from the view point that the heat sink of a conventional fuel is insufficient,the heat-absorbing through endothermic chemical reaction is actually a chemical recuperation process because the wasted heat dissipated from the engine thermal structure is recovered through the endothermic chemical reaction.Therefore,the working process of a scramjet with endothermic hydrocarbon fuel cooling is a chemical recuperative cycle.To analyze the chemical recuperative cycle of a chemically recuperated scramjet engine,we defined physical and chemical recuperation effectivenesses and heating value increment rate,and derived engine performance parameters with chemical recuperation.The heat value benefits from both physical and chemical recuperations,and it increases with the increase in recuperation effectiveness.The scramjet performance parameters also increase with the increase in chemical recuperation effectiveness.The increase in chemical recuperation effectiveness improves both the performances of the fuel cooling system and the combustion system.The results of analysis prove that the existence of a chemical recuperation process greatly improves the performance of the whole scramjet. 展开更多
关键词 SCRAMJET endothermic hydrocarbon fuel chemical recuperation regenerative cooling chemical reaction
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Steady-state coupled analysis of flowfields and thermochemical erosion of C/C nozzles in hybrid rocket motors 被引量:2
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作者 ZHAO Sheng TIAN Hui +2 位作者 WANG PengFei YU NanJia CAI GuoBiao 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第3期574-586,共13页
A hybrid rocket can be used in various applications and is an attractive propulsion system. However, serious erosion of nozzles is common in motor firing operations, which could restrict the application of hybrid rock... A hybrid rocket can be used in various applications and is an attractive propulsion system. However, serious erosion of nozzles is common in motor firing operations, which could restrict the application of hybrid rocket motors. Usually, the serious erosion is attributed to the high concentration of oxidizing species in hybrid motors, while the details of flowfields in the motors are not paid special attention to. In this paper, first the thermochemical erosion of C/C nozzle is simulated coupled with the flowfields in a 98% H2O2/hydroxyl-terminated polybutadiene(HTPB) hybrid rocket motor. The simulation is made on a typical axisymmetric motor, including a pre-combustion chamber, an aft-combustion chamber and nozzle structures. Thermochemica reactions of H2 O, CO2, OH, O and O2 with C are taken into account. Second, the change of flowfields due to fuel regression during motor firing operations is considered. Nozzle erosion in different flowfields is evaluated. Third, the results of nozzle erosion in the coupled simulation are compared with those under uniform and chemical equilibrium flow and motor firing test results. The results of simulation and firing tests indicate that the thermochemical erosion of nozzles in hybrid motors should be calculated coupled with flowfields in the motor. In uniform and chemical equilibrium flowfields, the erosion rate is overestimated. The diffusion flame in hybrid motors protects the nozzle surface from the injected oxidizer and high temperature products in flowfields, leading to a relatively fuel-rich environment above the nozzle. The influence of OH and the geometry of motor should also be considered in the evaluation of nozzle erosion in hybrid motors. 展开更多
关键词 hybrid rocket motor C/C nozzle thermochemical erosion
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Analyses of surrogate models for calculating thermophysical properties of aviation kerosene RP-3 at supercritical pressures 被引量:9
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作者 XU KeKe MENG Hua 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第3期510-518,共9页
Aviation kerosene is commonly used in combustion and regenerative engine cooling processes in propulsion and power-generation systems,including rocket,scramjet,and advanced gas turbine engines.In this paper,many surro... Aviation kerosene is commonly used in combustion and regenerative engine cooling processes in propulsion and power-generation systems,including rocket,scramjet,and advanced gas turbine engines.In this paper,many surrogate models proposed in the open literature are examined for their applicability and accuracy in calculating thermodynamic and transport properties of the China aviation kerosene RP-3 at supercritical pressures,based on the extended corresponding-states methods.The enthalpy change from endothermic decomposition and low heating value from combustion of the jet fuel are also evaluated.Results from a number of simple and representative surrogate models,which contain species components ranging from 1 to10,are analyzed in detail.Data analyses indicate that a surrogate model with four species is the best choice for thermophysical property calculations under the tested conditions,with fluid temperature up to 650 K at various supercritical pressures.The surrogate model is particularly accurate in predicting the pseudo-critical temperature of aviation kerosene RP-3 at a supercritical pressure.A simple surrogate model containing the n-decane species and a surrogate model containing 10 species are the other two acceptable options.The work conducted herein is of practical importance for theoretical analyses and numerical simulations of various physicochemical processes at engine operating conditions. 展开更多
关键词 thermodynamic property transport property hydrocarbon fuel COMBUSTION heat transfer PYROLYSIS
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Numerical simulation of turbulent combustion: Scientific challenges 被引量:5
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作者 REN ZhuYin LU Zhen +1 位作者 HOU LingYun LU LiuYan 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2014年第8期1495-1503,共9页
Predictive simulation of engine combustion is key to understanding the underlying complicated physicochemical processes,improving engine performance,and reducing pollutant emissions.Critical issues as turbulence model... Predictive simulation of engine combustion is key to understanding the underlying complicated physicochemical processes,improving engine performance,and reducing pollutant emissions.Critical issues as turbulence modeling,turbulence-chemistry interaction,and accommodation of detailed chemical kinetics in complex flows remain challenging and essential for highfidelity combustion simulation.This paper reviews the current status of the state-of-the-art large eddy simulation(LES)/probability density function(PDF)/detailed chemistry approach that can address the three challenging modelling issues.PDF as a subgrid model for LES is formulated and the hybrid mesh-particle method for LES/PDF simulations is described.Then the development need in micro-mixing models for the PDF simulations of turbulent premixed combustion is identified.Finally the different acceleration methods for detailed chemistry are reviewed and a combined strategy is proposed for further development. 展开更多
关键词 turbulence-chemistry interaction detailed chemistry probability density function mixing models large eddy simulations
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Mechanistic study and kinetic properties of the CF_3CHO+Cl reaction
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作者 GAO Hong WANG Ying +1 位作者 WANG Qin LIU JingYao 《Science China Chemistry》 SCIE EI CAS 2012年第10期2197-2201,共5页
Theoretical investigations have been carried out on the mechanism and kinetics for the reaction of CF 3 CHO + Cl using duallevel direct dynamics method. The potential energy surface information was obtained at the MCQ... Theoretical investigations have been carried out on the mechanism and kinetics for the reaction of CF 3 CHO + Cl using duallevel direct dynamics method. The potential energy surface information was obtained at the MCQCISD/3//MP2/cc-pVDZ level and the kinetic calculations were done using variational transition state theory with interpolated single-point energy (VTST-ISPE) approach. The calculated results show that the reaction proceeds primarily via the H-abstraction channel, while the Cl-addition channel is unfavorable due to the higher barriers. The improved canonical variational transition-state theory (ICVT) with the small-curvature tunneling correction (SCT) was used to calculate the rate constants. The theoretical rate constants at room temperature are in general agreement with the experimental values. A three-parameter rate constant expression was fitted over a wide temperature range of 200-2000 K. 展开更多
关键词 direct dynamics rate constant variational transition-state theory
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