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基于光化学损失的郑州市夏季VOCs污染特征、来源及环境影响
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作者 李卓 王冰 +7 位作者 王甜甜 张栋 宋鑫帅 袁明浩 卢轩 王文举 尹沙沙 张瑞芹 《环境科学》 EI CAS CSCD 北大核心 2024年第9期5157-5167,共11页
为明确郑州市夏季大气挥发性有机物(VOCs)污染特征和来源,于2022年8月对郑州市大气VOCs开展多点位离线采样及实验室分析,对比该时期观测和初始VOCs的体积分数水平、臭氧生成潜势(OFP)、二次气溶胶生成潜势(SOAFP)和来源.研究期间三点位... 为明确郑州市夏季大气挥发性有机物(VOCs)污染特征和来源,于2022年8月对郑州市大气VOCs开展多点位离线采样及实验室分析,对比该时期观测和初始VOCs的体积分数水平、臭氧生成潜势(OFP)、二次气溶胶生成潜势(SOAFP)和来源.研究期间三点位观测与初始φ(VOCs)平均值分别为(31.83±13.51)×10^(−9)和(35.92±15.30)×10^(−9),烯烃(52.5%)和芳香烃(29.7%)是光化学损耗率较高的组分,各点位TVOCs观测浓度空间变化大小为:郑州大学>岗李水库>经开区管委,烷烃和OVOCs在各点位的贡献均较高;烯烃和芳香烃是对臭氧和二次气溶胶形成贡献较大的组分;机动车源、溶剂使用源和工业源是郑州市大气VOCs的主要贡献源,与基于初始浓度的源解析结果相比,机动车源、工业源和溶剂使用源贡献率相对较高,燃烧源、植物源和油气挥发源的贡献率相对较低. 展开更多
关键词 挥发性有机化合物(VOCs) 来源解析 臭氧生成潜势(OFP) 二次有机气溶胶生成潜势(SOAFP) 化学损失
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深圳市夏季大气挥发性有机物的光化学反应特征及来源解析
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作者 吴浩然 彭杏 +4 位作者 符楠 李志杰 钟文君 何凌燕 黄晓锋 《中国环境科学》 EI CAS CSCD 北大核心 2024年第8期4145-4154,共10页
选取深圳市城市点位在2022年6~8月(夏季)光化学反应活跃季节开展VOCs连续在线观测,利用光化学龄的参数化方法对VOCs测量浓度进行光化学损失校正以获得VOCs初始浓度,并分析VOCs的光化学反应特征,使用特征物种比值分析法和正交矩阵因子模... 选取深圳市城市点位在2022年6~8月(夏季)光化学反应活跃季节开展VOCs连续在线观测,利用光化学龄的参数化方法对VOCs测量浓度进行光化学损失校正以获得VOCs初始浓度,并分析VOCs的光化学反应特征,使用特征物种比值分析法和正交矩阵因子模型(PMF)进行VOCs来源解析.研究表明,各类VOCs光化学消耗的浓度在总VOCs(TVOCs)消耗浓度占比为:烯烃(53.5%)、OVOCs(30.8%)、烷烃(10.9%)、芳香烃(4.7%)、乙炔(0.2%).烷烃的初始浓度与测量浓度均在TVOCs中占主导地位,但其光化学损失OFP仅有1.2×10^(-9)远低于烯烃(47.8×10^(-9))、OVOCs(15.8×10^(-9))和芳香烃(4.7×10^(-9)),所以烯烃是臭氧污染防治的关键物种.本研究基于初始值与测量值进行PMF源解析得到6个主要排放源的浓度贡献为(初始-PMF,测量-PMF):工业过程(0.91×10^(-9),0.87×10^(-9))、溶剂使用(2.75×10^(-9),1.84×10^(-9))、汽车尾气(3.49×10^(-9),2.01×10^(-9))、汽油挥发(3.20×10^(-9),2.62×10^(-9))、天然源(0.74×10^(-9),0.56×10^(-9))、燃烧源(2.35×10^(-9),1.16×10^(-9)).结果显示PMF源解析结果受光化学反应影响显著,在进行源解析时应考虑到利用VOCs的初始值而非测量值,否则会对烯烃占主导的汽车尾气与天然源造成显著的低估. 展开更多
关键词 挥发性有机物(VOCs) 化学损失 特征物种比值分析法 正交矩阵因子分析
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复合驱过程中化学剂损失与超低界面张力有效作用距离 被引量:21
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作者 侯吉瑞 张淑芬 +1 位作者 杨锦宗 刘中春 《大连理工大学学报》 EI CAS CSCD 北大核心 2005年第4期496-500,共5页
以大庆天然油砂制作填砂管模型,通过改变复合体系的注入量,研究了碱、活性剂、聚合物3种组分的动态吸附特性,并模拟计算了不同注入量下各组分在地层中运移距离与损失量的关系.结果表明,活性剂的损失量最大,在运移1/5井距后即损失约80%;... 以大庆天然油砂制作填砂管模型,通过改变复合体系的注入量,研究了碱、活性剂、聚合物3种组分的动态吸附特性,并模拟计算了不同注入量下各组分在地层中运移距离与损失量的关系.结果表明,活性剂的损失量最大,在运移1/5井距后即损失约80%;而聚合物和碱的损失分别只有12%和15%.结合界面张力随运移距离的变化情况可以判断,超低界面张力在油层中的有效作用距离有限,而体系在非超低界面张力状态下对采收率的贡献应予以足够的重视. 展开更多
关键词 复合驱油体系 采收率 化学损失 运移距离 超低界面张力
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城市煤气甲烷化工艺的化学能损失 被引量:1
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作者 夏素兰 朱家骅 +1 位作者 周勇 夏代宽 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 1999年第5期16-20,共5页
通过解析城市煤气甲烷化过程化学能的损失,指出CO 变换应以满足甲烷化反应要求为限,过度变换会造成无谓的化学能损失且降低产品气热值。提出以国家标准规定的城市煤气热值下限和CO 含量上限为控制指标的参数准则,并在2-5L ... 通过解析城市煤气甲烷化过程化学能的损失,指出CO 变换应以满足甲烷化反应要求为限,过度变换会造成无谓的化学能损失且降低产品气热值。提出以国家标准规定的城市煤气热值下限和CO 含量上限为控制指标的参数准则,并在2-5L 级现场实验中得到了验证。 展开更多
关键词 煤气 甲烷化 变换 化学损失 一氧化碳
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保肝汤对小鼠四氯化碳致慢性化学性肝损伤的保护作用 被引量:3
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作者 李谚语 刘丽 +3 位作者 范颖 李军 张英利 卢健 《天津中医药》 CAS 2018年第12期935-938,共4页
[目的]研究保肝汤对四氯化碳(CCl4)致慢性化学性肝损伤的保护作用。[方法]将84只昆明小鼠随机分为正常组、模型组、护肝片组、保肝汤高、中、低剂量组共6组,每组14只。除正常组外,其余各组分别在实验第1、3、10、16、22、25、28天腹腔注... [目的]研究保肝汤对四氯化碳(CCl4)致慢性化学性肝损伤的保护作用。[方法]将84只昆明小鼠随机分为正常组、模型组、护肝片组、保肝汤高、中、低剂量组共6组,每组14只。除正常组外,其余各组分别在实验第1、3、10、16、22、25、28天腹腔注射0.5%CCl4;于造模后第10天开始灌胃,其中正常组和模型组给予蒸馏水灌胃,护肝片及保肝汤高、中、低剂量组给予灌胃药液。第30天灌胃2 h后称质量、处死,并收集各组肝组织及血清标本,检测指标含量,计算肝脏指数并进行肝组织病理学检查。[结果]与正常组比较,模型组丙氨酶转氨酶(ALT)、天门冬氨酶氨基转移酶(AST)、丙二醛(MDA)明显升高(P<0.05)。模型组肝组织病理学,可见多处大片肝细胞脂肪变性,并见多处灶状坏死;与模型组比较,保肝汤高、中、低剂量组ALT、AST降低,AST/ALT升高(P<0.05),保肝汤中、低剂量组MDA降低(P<0.05);保肝汤各剂量组明显改善肝组织及形态结构。[结论]保肝汤能够减轻CCl4对肝细胞的损伤程度,以保肝汤中剂量组作用最优;作用机制与抑制肝损伤后脂质过氧化反应有关。 展开更多
关键词 保肝汤 小鼠 四氯化碳 化学性肝损失 保护作用
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浅谈加强化学管理提高产糖率的一些体会
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作者 陈小梅 陈益飞 《广西轻工业》 2008年第2期5-6,共2页
糖厂如果在生产操作和管理上不注意,造成0.1%的糖损失是较容易的。如果每天产糖量按1000吨计算,每天损失的糖为1000公斤,每年产糖量如果按10万吨计算,就是损失100吨糖,相当于损失人民币约40万元。
关键词 蔗糖转化 物理损失 微生物损失 化学损失
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石灰用量对矿石中金的浸出和吸附的影响 被引量:3
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作者 黄小荣 《矿产与地质》 2001年第z1期493-496,共4页
在炭浆法提金工艺的过程中发现 ,石灰的用量对矿石中金的浸出和浸出后对活性炭吸附金离子有着重大影响。这是由于石灰用量一过少 ,氰化物易造成化学损失 ,从而矿石中的金因氰化物不足而浸不出 ,而用量过多 ,又与积累在溶液中的过氧化氢... 在炭浆法提金工艺的过程中发现 ,石灰的用量对矿石中金的浸出和浸出后对活性炭吸附金离子有着重大影响。这是由于石灰用量一过少 ,氰化物易造成化学损失 ,从而矿石中的金因氰化物不足而浸不出 ,而用量过多 ,又与积累在溶液中的过氧化氢反应生成过氧化钙 ,在金表面和炭表面形成薄膜 ,从而影响金的浸出和金离子被吸附 ,因而 。 展开更多
关键词 炭浆法 浸出 过氧化钙 吸附 薄膜影响 化学损失
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Profile of Absolute Light Utilization Efficiency Within Leaves of Euonymus japonicus 被引量:2
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作者 樊大勇 韩涛 +2 位作者 李竟 王强 高荣孚 《Acta Botanica Sinica》 CSCD 2003年第2期169-176,共8页
Absolute light utilization efficiency across leaf section of Euonymus japonicus T. was calculated based on the measurements of photoacoustic technique (PA technique) and microscopic fiber optic probe. This new method ... Absolute light utilization efficiency across leaf section of Euonymus japonicus T. was calculated based on the measurements of photoacoustic technique (PA technique) and microscopic fiber optic probe. This new method was based on the principal of depth analysis by PA technique and the differential analysis of light gradients across leaf section by micro-optical probe technique. The depth analysis was shown by a sample of PA scan light absorption spectra. Results showed that the tissue layers between palisade tissue and spongy tissue used the smallest proportion of incident light energy for photochemical reactions (about 0.026% incident light energy of 660 nm light), while in tissue layer more close to the adaxial surface of leaf or the abaxial surface of leaf, the efficiency of utilization of light energy tended to be improved, e. g. 0.092% for tissue layers close to adaxial surface; 0.036% for tissue layers close to abaxial surface. The results that different leaf tissue layers utilized different proportion of incident light energy for photochemical reaction directly prove the hypothesis put forward by Han and Vogelmann. 展开更多
关键词 depth analysis by PA technique light gradients across leaf section photochemical loss light absorption profile
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浓香型白酒贮存过程中酯减少途径的研究 被引量:9
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作者 李家民 《酿酒科技》 CAS 2009年第6期62-64,共3页
根据酯水解途径以及相关化学反应,对浓香型白酒在贮存过程中酯减少途径进行分析,得出了酯减少主要为挥发损失和化学变化损失。
关键词 浓香型白酒 贮存 挥发损失 化学变化损失
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固体火箭发动机喷管效率计算 被引量:4
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作者 陈林泉 侯晓 +1 位作者 李岩芳 董新刚 《固体火箭技术》 EI CAS CSCD 北大核心 2002年第4期9-11,共3页
采用半经验法计算了固体火箭发动机喷管的效率,即用计算流场的方法确定了喷管二维两相流损失和边界层损失,用SPP经验法预示了喷管的化学动力学损失、喷管烧蚀损失和喷管潜入损失。利用该方法对几个实际固体火箭发动机喷管效率进行了计算... 采用半经验法计算了固体火箭发动机喷管的效率,即用计算流场的方法确定了喷管二维两相流损失和边界层损失,用SPP经验法预示了喷管的化学动力学损失、喷管烧蚀损失和喷管潜入损失。利用该方法对几个实际固体火箭发动机喷管效率进行了计算,计算结果与实际结果比较符合,精度偏差在1%之内。 展开更多
关键词 固体推进剂火箭发动机 喷管 化学动力学损失 工作效率
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浓香型白酒贮存过程中酯减少途径的研究 被引量:3
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作者 李家民 《酿酒》 CAS 2009年第4期12-14,共3页
实验根据酯水解途径以及相关化学反应,对浓香型白酒在贮存过程中酯减少途径进行分析,得出了酯减少主要为挥发损失和化学变化损失。
关键词 浓香型白酒 贮存 挥发损失 化学变化损失
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Inhibiting Effect of Ciprofloxacin,Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid 被引量:7
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作者 庞雪辉 冉祥滨 +2 位作者 匡飞 解建东 侯保荣 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第2期337-345,共9页
The inhibiting effect of ciprofloxacin,norfloxacin and ofloxacin on the corrosion of mild steel in 1 mol·L-1 HCl and the mechanism were studied at different temperatures using mass loss measurement,electrochemica... The inhibiting effect of ciprofloxacin,norfloxacin and ofloxacin on the corrosion of mild steel in 1 mol·L-1 HCl and the mechanism were studied at different temperatures using mass loss measurement,electrochemical method,and X-ray photoelectron spectroscopy(XPS) .Effective inhibition was shown by mass loss,potentiodynamic polarization and impedance spectroscopy measurement.The corrosion rate of the metal in the mass loss measurement,and the corrosion reaction on cathode and anode in the electrochemical measurement were accelerated when temperature was increased.XPS results showed that the inhibitors adsorbed effectively on the metal surface. 展开更多
关键词 CORROSION INHIBITION electrochemical impedance spectroscopy potentiodynamic polarization X-ray photoelectron spectroscopy
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Nutritional status changes in patients with advanced non-small cell lung cancer receiving first-line chemotherapy 被引量:1
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作者 Wei Sun Shunfang Liu +1 位作者 Ping Peng Dongbo Liu 《Oncology and Translational Medicine》 2018年第2期54-57,共4页
Objective This study aimed to assess the real-life nutritional status changes and gastrointestinal symptoms in patients with advanced non-small cell lung cancer(NSCLC) receiving chemotherapy.Methods A total of 104 pat... Objective This study aimed to assess the real-life nutritional status changes and gastrointestinal symptoms in patients with advanced non-small cell lung cancer(NSCLC) receiving chemotherapy.Methods A total of 104 patients with metastatic NSCLC receiving first-line chemotherapy were included in this study. Unintentional weight loss, body mass index(BMI) changes, and gastrointestinal symptoms were recorded and evaluated. Biochemical parameters [hemoglobin(Hb) and albumin levels] were compared before and after two chemotherapy cycles using SPSS software.Results Of these patients, 65.38%(68/104) experienced unintentional weight loss, whereas 30.77% and 12.5% presented with ≥ 5% and ≥ 10% degrees of weight loss, respectively, within 6 months before first-line chemotherapy was administered. Then, 48.08%(50/104) of the patients experienced unintentional weight loss after two chemotherapy cycles. The mean body weight after chemotherapy was 61.47 ± 10.37 kg, which was significantly decreased relative to that before chemotherapy(P < 0.05). The mean BMI after chemotherapy was 22.66 ± 3.34 kg/m^2, which was also significantly diminished with respect to that during the previous chemotherapy cycle(P < 0.05). The most common gastrointestinal symptoms reported among all the study patients were anorexia(80/104, 76.92%), nausea(53/104, 50.96%), constipation(49/104, 47.12%), vomiting(48/104, 46.15%), taste disorders(40/104, 38.46%), and early satiety(32/104, 30.77%). The mean Hb levels after chemotherapy were 117.06 ± 16.67 g/L, which were significantly lower than those before chemotherapy(132.73 ± 16.42 g/L)(P < 0.05). No significant difference was noted between the mean albumin levels before and after chemotherapy(38.29 ± 4.22 g/L vs 38.17 ± 4.54 g/L; P = 0.798). Conclusion Weight loss history, gastrointestinal symptoms, and Hb level decreases are determinant factors of nutritional status in patients with advanced NSCLC and must be included in the screening, evaluation, and treatment of lung carcinoma. 展开更多
关键词 lung cancer gastrointestinal symptoms weight loss CHEMOTHERAPY HEMOGLOBIN ALBUMIN
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工业锅炉热效率与节能潜力 被引量:8
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作者 管显兰 《应用能源技术》 2006年第4期23-25,共3页
锅炉节能的原因,锅炉热效率计算,造成锅炉热效率低的原因,排烟热损失高的原因,燃料燃烧不充分造成的损失的原因,机械不完全燃烧热损失的原因,散热损失的原因,节能的途径。
关键词 锅炉热效率 化学不完全燃烧损失 机械不完全燃烧损失 锅炉排烟温度 过剩空气系数 风机 受热面
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Assessment of Water Losses from Badovc Lake, Kosovo: Hydrochemical Implications
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作者 Skender Bublaku Arjan Beqiraj Agron Shala 《Journal of Environmental Science and Engineering(A)》 2015年第5期249-257,共9页
This paper aims to quantitatively assess water losses of Badovc Lake-Kosovo based on both water balance of the lake and water hydrochemistry. This attempt was strongly prompt by both the importance of this lake for wa... This paper aims to quantitatively assess water losses of Badovc Lake-Kosovo based on both water balance of the lake and water hydrochemistry. This attempt was strongly prompt by both the importance of this lake for water supply of Prishtina city and the lack of water. According to lake water balance, a water loss of 3,738,905 m^3 and 1,722,552 m^3 for the hydrologic year 2014 and the period January-May (2015) was evaluated. These consistent data favour the opinion that a continuous groundwater outflow from the lake is present and it is conditioned by the intensively developed fracture system in the lake basement formations. This was also supported by the chemical data (chloride, sulphate, hardness and electric conductivity etc.) of the water. Water from the leakages on the right side of the dam shows the same chemical signature as the water from the lake. Whereas, water from the piezometer, monitoring well and the gallery of Hajvalia mine show similar values with those of the water from the lake. The calculations of the chloride mass balance showed that the fractions of lake and rainfall waters in the water mixture of Hajvalia mine were 67% and 33% respectively. 展开更多
关键词 CHLORIDE mass balance RAINFALL lake water balance water inflow and outflow water runoff.
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Transport hindrances with electrodialytic recovery of citric acid from solution of strong electrolytes
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作者 Anusha Chandra Jogi Ganesh Dattatreya Tadimeti Sujay Chattopadhyay 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第2期278-292,共15页
Electrodialytic (ED) recovery of citric acid (CA) in the presence/absence of strong electrolytes (NaCl, CaCl2 and Feel3) was separately analyzed under different process conditions. Recovery effectiveness was qua... Electrodialytic (ED) recovery of citric acid (CA) in the presence/absence of strong electrolytes (NaCl, CaCl2 and Feel3) was separately analyzed under different process conditions. Recovery effectiveness was quantitatively estimated from current efficiency values. Efficiency attained optimum value with both flow rate and potential applied, while a monotonic rise was noted with temperature which got lowered beyond 0.1 tool. L 1 feed concentration. 40% drop in efficiency was recorded in the presence of strong electrolytes (Noel, CaCl2 and Feel3) in feed relative to their presence in concentrate. Severe transport hindrance and efficiency loss were attributed to adsorption and allied physicochemical changes occurred with anion/cation exchange membranes (AEM/CEM) and these were confirmed through contact angle/Chronopotentiometry/AFM/EDX. Sluggish potential rise (Galvanostatic mode) in Chronopotentiometric analysis indicated diffusion limiting transport of organic acids influenced AEM resistance. XRD and EDX analysis indicated the presence of salt hydrates/ions (Ca2+/Fe3+) over CEM justifying the resistance buildup due to adsorption of multivalent metal ion(s) and salts. 展开更多
关键词 Electrodialysis Adsorption Electrolytes Recovery Chronopotentiometry AFM
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Melanopsin-expressing retinal ganglion cell loss and behavioral analysis in the Thy1-CFP-DBA/2J mouse model of glaucoma 被引量:4
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作者 ZHANG Qi VUONG Helen +4 位作者 HUANG Xin WANG YanLing BRECHA Nicholas C. PU MingLiang GAO Jie 《Science China(Life Sciences)》 SCIE CAS 2013年第8期720-730,共11页
In this study, the role of melanopsin-expressing retinal ganglion cells (mRGCs) in the glaucoma-induced depressive behavioral response pattern was investigated. The CFP-D2 transgenic glaucoma animal model from five ... In this study, the role of melanopsin-expressing retinal ganglion cells (mRGCs) in the glaucoma-induced depressive behavioral response pattern was investigated. The CFP-D2 transgenic glaucoma animal model from five age groups was used in this study. Immunohistochemical labeling, quantitative analysis of mRGC morphology, open field test (OFT), and statistical analysis were used. In comparison with C57 BL/6 mice, the age-matched CFP-D2 mice had significantly elevated intraocular pressure (lOP). We observed parallel morphological changes in the retina, including a reduction in the density of cyan fluorescent protein- (CFP) expressing cells (cells mm^-2 at 2 months of age, 1309±26; 14 months, 878±30, P〈0.001), mRGCs (2 months, 48_+3; 14 months, 19±4, P〈0.001), Brn3b-expressing RGCs (2 months, 1283±80; 14 months, 950±31, P〈0.001), Brn-3b expressing mRGCs (5 months, 50.17%±5.5%; 14 months, 12.61%±3.8%, P〈0.001), and reduction in the dendritic field size of mRGCs (mm^2 at 2 months, 0.077±0.015; 14 months, 0.065±0.015, P〈0.05). CFP-D2 mice had hyperactive locomotor activity patterns based on OFT findings of the total distance traveled, number of entries into the center, and time spent in the center of the testing apparatus. The glaucoma induced hyperactive response pattern could be associated with dysfunctional mRGCs, most likely Brn-3b-positive mRGCs in CFP-D2 mice. 展开更多
关键词 pigmentary glaucoma Thyl-CFP-DBA/2J mouse retinal ganglion cells melanopsin-expressing retinal ganglion cells depression
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Sodium ion storage performance and mechanism in orthorhombic V_(2)O_(5) single-crystalline nanowires 被引量:6
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作者 Yanwei Li Jingcheng Ji +3 位作者 Jinhuan Yao Ying Zhang Bin Huang Guozhong Cao 《Science China Materials》 SCIE EI CSCD 2021年第3期557-570,共14页
A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavi... A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavior and mechanism of orthorhombic V_(2)O_(5) single-crystalline nanowires in the voltage window of 1.0–4.0 V(vs.Na/Na+).The single-crystalline nanowires exhibit a large irreversible capacity loss during the first discharge/charge cycle,and then show excellent cycling stability in the following cycles.At a current density of 100 mA g^(−1),the nanowires electrode delivers initial discharge/charge capacity of 217/88 mA h g^(−1),corresponding to a Coulombic efficiency of only 40.5%;after 100 cycles,the electrode remains a reversible discharge capacity of 78 mA h g^(−1) with a fading rate of only 0.09%per cycle compared with the 2nd cycle discharge capacity.The sodium ion storage mechanism was investigated,illustrating that the large irreversible capacity loss in the first cycle can be attributed to the initially formed single-crystalline α′-Nax V_(2)O_(5)(0.02<x<0.88),in which sodium ions cannot be electrochemically extracted and the α′-Na0.88 V_(2)O_(5) can reversibly host and release sodium ions via a single-phase(solid solution)reaction,leading to excellent cycling stability.The Na^(+) diffusion coefficient in α′-Nax V_(2)O_(5) ranges from 10^(−12) to 10^(−11.5) cm^(2) s^(−1) as evaluated by galvanostatic intermittent titration technique(GITT). 展开更多
关键词 sodium ion batteries V_(2)O_(5) SINGLE-CRYSTALLINE NANOWIRES sodium storage mechanism
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Absorption of light in InP nanowire arrays 被引量:2
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作者 Nicklas Anttu Alireza Abrand +4 位作者 Damir Asoli Magnus Heurlin Ingvar Aberg Lars Samuelson Magnus Borgstrom 《Nano Research》 SCIE EI CAS CSCD 2014年第6期816-823,共8页
An understanding of the absorption of light is essential for efficient photovoltaic and photodetection applications with III-V nanowire arrays. Here, we correlate experiments with modeling and verify experimentally th... An understanding of the absorption of light is essential for efficient photovoltaic and photodetection applications with III-V nanowire arrays. Here, we correlate experiments with modeling and verify experimentally the predicted absorption of light in InP nanowire arrays for varying nanowire diameter and length. We find that 2,000 nm long nanowires in a pitch of 400 nm can absorb 94% of the incident light with energy above the band gap and, as a consequence, light which in a simple ray-optics description would be travelling between the nanowires can be efficiently absorbed by the nanowires. Our measurements demonstrate that the absorption for long nanowires is limited by insertion reflection losses when light is coupled from the air top-region into the array. These reflection losses can be reduced by introducing a smaller diameter to the nanowire-part closest to the air top-region. For nanowire arrays with such a nanowire morphology modulation, we find that the absorptance increases monotonously with increasing diameter of the rest of the nanowire. 展开更多
关键词 indium phosphide SEMICONDUCTOR NANOWIRE absorption of light
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