To determine the degree of oxidation in vegetable oil, a photochemical method using the electron spin resonance （ESR） spin trapping technique was developed, and the results were compared with those obtained using co...To determine the degree of oxidation in vegetable oil, a photochemical method using the electron spin resonance （ESR） spin trapping technique was developed, and the results were compared with those obtained using conventional peroxide-value （PV） and acid-value （AV） methods. Vegetable oil heat-treated were subjected to short UV illumination, and the produced alkyl-oxyl radicals were identified and quantified using the ESR spin trapping technique. ESR signal intensity was used as an indicator of oil oxidation, which monotonically increased as a function of the heat-treatment time. Commercially, available oils were selected and analyzed. The results were compared with those obtained using the PV and AV methods. The present method displayed some analogies with the PV method at least in the early stage of heating. Overall, the present method had highly sensitive and capable of detecting early-stage oxidation in vegetable oil.展开更多
Integrated Pest Management （IPM） technologies can reduce pest damage to crops by emphasizing non-chemical control methods thereby reducing potential negative effects of chemicals on the environment while preserving ...Integrated Pest Management （IPM） technologies can reduce pest damage to crops by emphasizing non-chemical control methods thereby reducing potential negative effects of chemicals on the environment while preserving profitability. This study investigates the adoption of eight IPM practices including intercropping, crop rotation, two improved varieties, incorporating a ＂striga chaser＂ in sorghum production, changing planting dates, altering planting density and fertilizer use. Explanatory variables include economic factors, social factors, management factors, and institutional factors. Results were consistent across logit and ordered logit analyses. Most factors affecting adoption across all crops and technologies are economic factors, including labor availability, technology resource requirements, technology complexity, and the level of expected benefits. Social factors are generally less associated with IPM technology adoption than either market or institutional factors. Results indicate that the evaluated technologies were scale-neutral and that farmer age and education level did not affect technology adoption.展开更多
Silver nanoparticles （Ag-NPs） were prepared using an electrochemical technique. The optical properties were measured by absorption spectroscopy. The dimension of the prepared nanoparticles as estimated by the Atomic...Silver nanoparticles （Ag-NPs） were prepared using an electrochemical technique. The optical properties were measured by absorption spectroscopy. The dimension of the prepared nanoparticles as estimated by the Atomic Force Microscope （AFM）, was 91.57 nm. This reaserch effort proposes a mechanism for reducing the size of silver nanoparticles by adding the hydrogen peroxide （H202）, and protecting the silver nanoparticle to inhibit agglomeration by adding PVP polymer.展开更多
The system ＂substrate--graphene island on its surface＂ was modeled with using semi-empirical quantum chemistry methods for various substrates. Such system imitates the graphene nucleation and growth when using CVD ...The system ＂substrate--graphene island on its surface＂ was modeled with using semi-empirical quantum chemistry methods for various substrates. Such system imitates the graphene nucleation and growth when using CVD （chemical vapor deposition） technique. Herewith the carbon atoms can enter the island from both the substrate and the bulk of the CVD reactor. The authors show that for a wide island size range the carbon nanowalls placed perpendicularly as to the substrate is the most favorable configuration. But a transfer to this configuration is only possible providing two conditions are realized： the CVD technique is stimulated by plasma, when a strong electrical field exists near the substrate surface and preliminary decomposition of carbon carrier is realized in the bulk of the CVD-reactor.展开更多
The labor market requires, increasingly, an updated and more professional preparation, mainly due to the rapid pace of scientific technical advancement means in the industry. From this point, it is important to encour...The labor market requires, increasingly, an updated and more professional preparation, mainly due to the rapid pace of scientific technical advancement means in the industry. From this point, it is important to encourage the development of the basic techniques of control systems, electronics and communication in order to produce knowledge in the mechatronic field and so apply them to industry. Considering the relevance of this subject, the students of Federal University of Para-Campus Tucumi through the Research Group of Electrical and Mechanical Systems apply their knowledge in multidisciplinary engineering fields in order to generate knowledge from creative techniques using low cost materials, together with the encouragement of social and environmental responsibility which is very important nowadays. At the same time, targeting the needs of the labor market, this work aims to foster in students the skills and requirements through team projects and innovative methods. Therefore, this paper presents a mechanical manipulator, where their operating characteristics are based on industrial robots in the literature, powered by DC （direct current） motors and fully developed from reusable materials. By adding a developed control from the Arduino, prototyping platform with an electronic strategic offers through the internet the long-distance control convenience.展开更多
In the past decades, combustion chemistry research grew rapidly due to the development of combustion diagnostic methods,quantum chemistry methods, kinetic theory, and computational techniques. A lot of kinetic models ...In the past decades, combustion chemistry research grew rapidly due to the development of combustion diagnostic methods,quantum chemistry methods, kinetic theory, and computational techniques. A lot of kinetic models have been developed for fuels from hydrogen to transportation fuel surrogates. Besides, multi-scale research method has been widely adopted to develop comprehensive models, which are expected to cover combustion conditions in real combustion devices. However, critical gaps still remain between the laboratory research and real engine application due to the insufficient research work on high pressure and low temperature combustion chemistry. Besides, there is also a great need of predictive pollutant formation model. Further development of combustion chemistry research depends on a closer interaction of combustion diagnostics, theoretical calculation and kinetic model development. This paper summarizes the recent progress in combustion chemistry research briefly and outlines the challenges and perspectives.展开更多
ZnTixFe2-xO4 and ZnTi0.6Fe1.4O4/Carbon nanotubes （ZT0.6F1.4/CNTs） composites were prepared by chemical co-precipitation method. The composition, microstructure, magnetic property, adsorption and photocatalytic activ...ZnTixFe2-xO4 and ZnTi0.6Fe1.4O4/Carbon nanotubes （ZT0.6F1.4/CNTs） composites were prepared by chemical co-precipitation method. The composition, microstructure, magnetic property, adsorption and photocatalytic activity of the prepared samples were characterized by means of modem analytical techniques. The results indicated that ZT0.6F1.4CNTs composites not only held the original special structure and excellent adsorption properties of CNTs, but also had suitable magnetic property and excellent photocatalytic activity. The removal rate of the samples on Rhodamine B （RhB） depended on the adsorption of CNTs and the photocatalytic degradation of ZTo.6F1.4 in the composites. The maximum adsorption amount （qm） of ZT0.6F1.4/CNTs with the mass ratios of ZT0.6F1.4 to CNTs （mz/c）=l was up to 17.153 mg g-t for RhB, its adsorption behavior was in accord with Langmuir model, and its photocatalytic degradation activity on RhB had a positive correlation with the content of ZT0.6F1.4 in the sample. The experimental results indicate that the total removal rate of composite with rnz/c=l on RhB was more than 95% and the composite had good decontamination capability on industrial dye wastewater. In addition, the samples can be recovered conveniently, activated easily and had good performance for recycling.展开更多
文摘To determine the degree of oxidation in vegetable oil, a photochemical method using the electron spin resonance （ESR） spin trapping technique was developed, and the results were compared with those obtained using conventional peroxide-value （PV） and acid-value （AV） methods. Vegetable oil heat-treated were subjected to short UV illumination, and the produced alkyl-oxyl radicals were identified and quantified using the ESR spin trapping technique. ESR signal intensity was used as an indicator of oil oxidation, which monotonically increased as a function of the heat-treatment time. Commercially, available oils were selected and analyzed. The results were compared with those obtained using the PV and AV methods. The present method displayed some analogies with the PV method at least in the early stage of heating. Overall, the present method had highly sensitive and capable of detecting early-stage oxidation in vegetable oil.
文摘Integrated Pest Management （IPM） technologies can reduce pest damage to crops by emphasizing non-chemical control methods thereby reducing potential negative effects of chemicals on the environment while preserving profitability. This study investigates the adoption of eight IPM practices including intercropping, crop rotation, two improved varieties, incorporating a ＂striga chaser＂ in sorghum production, changing planting dates, altering planting density and fertilizer use. Explanatory variables include economic factors, social factors, management factors, and institutional factors. Results were consistent across logit and ordered logit analyses. Most factors affecting adoption across all crops and technologies are economic factors, including labor availability, technology resource requirements, technology complexity, and the level of expected benefits. Social factors are generally less associated with IPM technology adoption than either market or institutional factors. Results indicate that the evaluated technologies were scale-neutral and that farmer age and education level did not affect technology adoption.
文摘Silver nanoparticles （Ag-NPs） were prepared using an electrochemical technique. The optical properties were measured by absorption spectroscopy. The dimension of the prepared nanoparticles as estimated by the Atomic Force Microscope （AFM）, was 91.57 nm. This reaserch effort proposes a mechanism for reducing the size of silver nanoparticles by adding the hydrogen peroxide （H202）, and protecting the silver nanoparticle to inhibit agglomeration by adding PVP polymer.
文摘The system ＂substrate--graphene island on its surface＂ was modeled with using semi-empirical quantum chemistry methods for various substrates. Such system imitates the graphene nucleation and growth when using CVD （chemical vapor deposition） technique. Herewith the carbon atoms can enter the island from both the substrate and the bulk of the CVD reactor. The authors show that for a wide island size range the carbon nanowalls placed perpendicularly as to the substrate is the most favorable configuration. But a transfer to this configuration is only possible providing two conditions are realized： the CVD technique is stimulated by plasma, when a strong electrical field exists near the substrate surface and preliminary decomposition of carbon carrier is realized in the bulk of the CVD-reactor.
文摘The labor market requires, increasingly, an updated and more professional preparation, mainly due to the rapid pace of scientific technical advancement means in the industry. From this point, it is important to encourage the development of the basic techniques of control systems, electronics and communication in order to produce knowledge in the mechatronic field and so apply them to industry. Considering the relevance of this subject, the students of Federal University of Para-Campus Tucumi through the Research Group of Electrical and Mechanical Systems apply their knowledge in multidisciplinary engineering fields in order to generate knowledge from creative techniques using low cost materials, together with the encouragement of social and environmental responsibility which is very important nowadays. At the same time, targeting the needs of the labor market, this work aims to foster in students the skills and requirements through team projects and innovative methods. Therefore, this paper presents a mechanical manipulator, where their operating characteristics are based on industrial robots in the literature, powered by DC （direct current） motors and fully developed from reusable materials. By adding a developed control from the Arduino, prototyping platform with an electronic strategic offers through the internet the long-distance control convenience.
基金supported by the National Natural Science Foundation of China(91541201,91641205,51622605)the National Basic Research Program of China(2013CB834602)+1 种基金the National Postdoctoral Program for Innovative Talents(BX201600100)China Postdoctoral Science Foundation(2016M600312)
文摘In the past decades, combustion chemistry research grew rapidly due to the development of combustion diagnostic methods,quantum chemistry methods, kinetic theory, and computational techniques. A lot of kinetic models have been developed for fuels from hydrogen to transportation fuel surrogates. Besides, multi-scale research method has been widely adopted to develop comprehensive models, which are expected to cover combustion conditions in real combustion devices. However, critical gaps still remain between the laboratory research and real engine application due to the insufficient research work on high pressure and low temperature combustion chemistry. Besides, there is also a great need of predictive pollutant formation model. Further development of combustion chemistry research depends on a closer interaction of combustion diagnostics, theoretical calculation and kinetic model development. This paper summarizes the recent progress in combustion chemistry research briefly and outlines the challenges and perspectives.
基金the National Nature Science Foundation of China (21071125) for financial support
文摘ZnTixFe2-xO4 and ZnTi0.6Fe1.4O4/Carbon nanotubes （ZT0.6F1.4/CNTs） composites were prepared by chemical co-precipitation method. The composition, microstructure, magnetic property, adsorption and photocatalytic activity of the prepared samples were characterized by means of modem analytical techniques. The results indicated that ZT0.6F1.4CNTs composites not only held the original special structure and excellent adsorption properties of CNTs, but also had suitable magnetic property and excellent photocatalytic activity. The removal rate of the samples on Rhodamine B （RhB） depended on the adsorption of CNTs and the photocatalytic degradation of ZTo.6F1.4 in the composites. The maximum adsorption amount （qm） of ZT0.6F1.4/CNTs with the mass ratios of ZT0.6F1.4 to CNTs （mz/c）=l was up to 17.153 mg g-t for RhB, its adsorption behavior was in accord with Langmuir model, and its photocatalytic degradation activity on RhB had a positive correlation with the content of ZT0.6F1.4 in the sample. The experimental results indicate that the total removal rate of composite with rnz/c=l on RhB was more than 95% and the composite had good decontamination capability on industrial dye wastewater. In addition, the samples can be recovered conveniently, activated easily and had good performance for recycling.
