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聚(2-乙烯吡啶)亲水改性聚苯乙烯-聚异戊二烯-聚苯乙烯热塑性弹性体及应用
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作者 冯道硕 王杰 +5 位作者 王锦昌 李辉阳 张文文 黄昊飞 荣卫锋 崔广军 《化工新型材料》 CAS CSCD 北大核心 2023年第S02期328-334,共7页
以聚(2-乙烯吡啶)(PVP)为亲水性改性剂,采用化学聚合改性和物理掺杂改性两种改性方法对聚苯乙烯-聚异戊二烯-聚苯乙烯(SIS)进行改性。前者是将2-乙烯吡啶作为共聚单体,制备出聚苯乙烯-聚异戊二烯-聚苯乙烯-聚乙烯吡啶(SISV)四嵌段聚合... 以聚(2-乙烯吡啶)(PVP)为亲水性改性剂,采用化学聚合改性和物理掺杂改性两种改性方法对聚苯乙烯-聚异戊二烯-聚苯乙烯(SIS)进行改性。前者是将2-乙烯吡啶作为共聚单体,制备出聚苯乙烯-聚异戊二烯-聚苯乙烯-聚乙烯吡啶(SISV)四嵌段聚合物、聚苯乙烯-聚异戊二烯-聚乙烯吡啶(SIV)三嵌段聚合物和聚异戊二烯-聚乙烯吡啶两嵌段(IV)。后者是将PVP按不同比例掺杂到SIS弹性体中。结果表明:改性后的材料水接触角均有降低,水膨张度均有明显提升,聚合改性效果更加明显。聚合改性SIS基热熔压敏胶的水接触角与改性前相比均有下降,IV基热熔压敏胶的水接触角降低幅度最大,亲水性最好。以上结果证明PVP可作为改性剂有效地提高了SIS的亲水性。 展开更多
关键词 聚(2-乙烯吡啶) SIS热塑性弹性体 化学聚合改性 物理掺杂改性
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Preparation of Novel Composite from Natural Rubber, Bagasse and Plaster 被引量:1
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作者 Sa-Ad Riyajan Isara Intharit +1 位作者 Suthikiat Thaiprasansup Pramuan Tangboriboonrat 《Journal of Chemistry and Chemical Engineering》 2010年第8期56-62,共7页
The sugar cane bagasse was treated with chemical treatment including sodium hydroxide and silane. The characterization of the modified bagasse was achieved with Fourier transform infrared spectroscopy (FTIR), and sc... The sugar cane bagasse was treated with chemical treatment including sodium hydroxide and silane. The characterization of the modified bagasse was achieved with Fourier transform infrared spectroscopy (FTIR), and scaning electron microscopy (SEM). Results showed that the presence Si-CH3 group occurred on bagasse surface after chemical modification. In addition, the roughness of the modified bagasse was higher than that of unmodified bagasse due to chemical modification from sodium hydroxide. Two polymer composite types, namely (1) natural rubber NR/sugar cane bagasse and (2) NR/plaster via two-roll mill method, were prepared. The optimum cure (t90) and torque of the NR/plaster increased with increasing plaster loading in composite. In case of NR/bagasse, the tgo of this sample decreased as a function of sugar cane bagasse while torque of this sample increased with increasing sugar cane bagasse. The modulus of the resulting composite increased with increasing both plaster and sugar cane bagasse, but the tensile strength and elongation at break of the composite decreased as a function of both piaster and sugar cane bagasse in composite. 展开更多
关键词 Natural rubber COMPOSITE BAGASSE PLASTER chemical modification.
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高分子表面活性剂的合成及其应用进展
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作者 王学川 赵军宁 《北京皮革(中外皮革信息版)(中)》 2004年第12期73-78,共6页
本文就高分子表面活性剂的合成及其应用进展做一简要评述。
关键词 高分子表面活性剂 分类 表面活性单体聚合 高分子聚合化学改性 化学改性
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