An Immune Self-adaptive Differential Evolution Algorithm with Application to Estimate Kinetic Parameters for Homogeneous Mercury Oxidation

A new version of differential evolution （DE） algorithm, in which immune concepts and methods are applied to determine the parameter setting, named immune self-adaptive differential evolution （ISDE）, is proposed to improve the performance of the DE algorithm. During the actual operation, ISDE seeks the optimal parameters arising from the evolutionary process, which enable ISDE to alter the algorithm for different optimization problems and improve the performance of ISDE by the control parameters＇ self-adaptation. The .performance of the proposed method is studied with the use of nine benchmark problems and compared with original DE algorithm ~nd-other well-known self-adaptive DE algorithms. The experiments conducted show that the ISDE clearly outperforms the other DE algorithms in all benchmark functions. Furthermore, ISDE is applied to develop the kinetic model for homogeneous mercury. （Hg） oxidation in flue gas, and satisfactory results are obtained.

Kinetics of Oxidation of Lactose with Photochemically Generated Radicals

Lactose milk sugar is found only in the milk of mammals. In order to understand the mechanism of oxidation of lactose, a systematic kinetic study of oxidation of lactose with photochemicaUy generated radicals was carried out. The reaction has a first order dependence on chloramine-T as well as on substrate. The reaction is catalysed by H＋ ions as well. On the basis of kinetic results and product analysis a probable mechanism were suggested.

Chemical Dynamics Simulations of the Hydroxyl Radical Reaction with Ethene

We present a theoretical study of the reaction of the hydroxyl radical with ethene using electronic structure calculations and direct-dynamics simulations. High-accuracy electronic structure calculations at the CCSD（T）/aug-cc-pVTZ//MP2/aug-ce-pVDZ level have been carried out to characterize the representative regions of the potential energy surface of various reaction pathways, including OH-addition and H-abstraction. These ab initio calculations have been employed to derive an improved set of parameters for the MSINDO semiempirieal Hamiltonian specific to the OH＋C2H4 reaction. The specific-reaction-parameter Hamilto- nian captures the ab initio data accurately, and has been used to perform direct quasiclassica] trajectory simulations of the OH＋C2H4 reaction at collision energies in the range of 2-10 kcal/mol. The calculated cross sections reveal that the OH-addition reaction domi- nates at all energies over H-abstraction. In addition, the excitation function of addition is reminiscent of a barrierless capture process, while that for abstraction corresponds to an activated one, and these trends can be connected to the transition-state energies of both reactions. We note that the development of an accurate semiempirical Hamiltonian for the OH＋C2H4 reaction in this work required the inclusion of empirical dispersion corrections, which will be important in future applications for which long-range intermoleeular attraction becomes significant.

The optimal strategy of the college English teaching is the combination of the language teaching and the knowledge teaching

The requirements of the college English curriculum teaching put forward the teaching objectives to cultivate the English comprehensive application abilities of the students, and improve their cultural qualities and their abilities of the independent learning, which pointed out the direction for the reform of the college English teaching. The language teaching mode based on the contents of the subject advocates that the knowledge learning and the language learning with the combination of the contents of the discipline, to develop the students＇ independent learning abilities, is a feasible and effective way to achieve the goal of the college English teaching. To cultivate the students＇ practical ability of using English is the basic task of the English teaching and learning. But China＇s current college English education failed to organically and effectively combine the teaching of the language knowledge and the cultivation of the language abilities and the teaching of the knowledge, leading to the existence of the obvious price scissors in the students＇ language knowledge and the language abilities. Therefore, the key to the reform of the college English teaching is to correctly position the roles of the foreign language teachers, change the classroom teaching into the process of the two-way interaction between the teachers and the students, focus on the cultivation of the students＇ intercultural communicative competence, so that the students＇ language knowledge and their language abilities can promote each other, and obtain the coordinative development, to better adapt to the requirements of the times.

混凝土制品用抗裂增强材料制备及其性能

基于"有效膨胀窗口"模型和混凝土制品早强、脆性大和易开裂特点,研发了一种以C4A3S、Ca SO4和Ca O为主要矿相,以水化产物钙矾石、氢氧化钙为核心抗裂组分,以钙矾石为增强关键组分的制品用化学自应力抗裂增强材料。它具有化学自应力、膨胀能大、限制膨胀率与制品早强相匹配、抗裂、早强和增强等优点,水中7d限制膨胀率0.062%,1d抗压强度比134.6%,28d抗压强度比101.9%。

Edge-enriched MoS@C/rGO film as self-standing anodes for high-capacity and long-life lithium-ion batteries

Restraining the aggregation and polysulfide dissolution of edge-enriched metal sulfides is of significance for their applications as anode materials of lithium-ion batteries(LIBs)with high capacity and long cycle-life.In this work,we have reported the incorporation of MoS2 nanocrystals into amorphous carbon on the surface of reduced graphene oxide(rGO)by balancing the decomposition rates of phenolic resin(PF)-impregnated ammonium thiomolybdate(ATM),which subsequently forms the MoS2@C/rGO film through redispersion and vacuum filtration.Such structural design effectively avoids the aggregation of MoS2 nanocrystals and Li2S loss,and meanwhile ion enrichment in amorphous carbon and diffusion reinforcement can greatly accelerate the electrochemical reaction kinetics.When applied as the selfstanding anode,the MoS2@C/rGO film possesses high reversible capacities of 1164 mA h g^-1 at the current density of 0.2 A g^-1 and 810 mA h g^-1 at 6.4 A g^-1.It also exhibits quite a high capacity retention after 1000 cycles at 3.2 A g^-1.This work develops the formation theory of incorporation structures and promotes their applications in energy storage devices.

Self-powered electrochemical anodic oxidation： A new method for preparation of mesoporous Al2O3 without applying electricity

Anodic oxidization （AO） is one of the most important methods available for fabricating mesoporous Al2O3 , which can be conducted at either high potential or low potential; however, the need for an external electricity power source limits its applications. In this work, a novel self-powered electrochemical anodic oxidization （SPAO） system was introduced for preparing mesoporous Al2O3 , by using newly-invented triboelectric nanogenerator （TENG） arrays driven by wind power. Using the controllable voltage output of the TENG arrays, the SPAO system was shown to regulate the pore depth and pore size of the mesoporous Al2O3 . In contrast to traditional AO systems, this technique takes advantage of the high output voltage of TENG arrays without any additional energy costs. In addition, the SPAO system can be used for the preparation of other mesoporous materials.