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工业危险废液热值的间接测定方法
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作者 张哲舟 赵立新 +4 位作者 秦松岩 李雪 李爱玲 李海青 张瑞玲 《高校化学工程学报》 EI CAS CSCD 北大核心 2019年第3期540-547,共8页
工业危险废液的热值准确测定对于保障热解处置工艺的正常运行至关重要。多相低热值工业危险废液不易燃烧、多相共存、成分难辨,故难以用氧弹直接燃烧法准确反映热值。今基于工业危废液的特性,提出对工业危废液分相测定热值,即固相残余... 工业危险废液的热值准确测定对于保障热解处置工艺的正常运行至关重要。多相低热值工业危险废液不易燃烧、多相共存、成分难辨,故难以用氧弹直接燃烧法准确反映热值。今基于工业危废液的特性,提出对工业危废液分相测定热值,即固相残余物直接燃烧结合含水馏出物间接估算的总思路。针对含水馏出物成分复杂难辨的特性,提出了基于气相色谱-质谱法对工业危险废液成分化学式及物质量相对比例的辨识,通过推导统一化学计量式计算热值的间接估算法。结果表明该方法估算热值误差小于 6%,核算同分异构体对热值的影响误差较小。针对危废液热值的日常监控,可选用 COD 为热值关联表征参数。选取 7 种不同行业危废液的热值实测及计算,验证了方法的普适性。 展开更多
关键词 工业危险废液 热值 色谱 化学计量式 间接估算法
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厌氧消化处理餐厨垃圾工艺 被引量:15
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作者 刘军 刘涛 +1 位作者 代俊 冯晓军 《中国资源综合利用》 2011年第9期54-57,共4页
结合餐厨垃圾的特性,对国内外餐厨垃圾处理现状进行了论述和分析比较。重点阐述了常用的餐厨垃圾厌氧消化处理工艺,对餐厨垃圾厌氧消化的影响因子提出了参考值,并以化学计量式为模型,计算了典型餐厨垃圾理论产生物气的能力。
关键词 餐厨垃圾 厌氧消化 化学计量式
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Experimental investigation of flame propagation characteristics in the in-line crimped-ribbon flame arrester
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作者 SUN ShaoChen DING ChunHui +3 位作者 HU XiYu LIU Gang YE Chen BI MingShu 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第5期678-691,共14页
An experimental system that consisted of gas mixing equipment, a sensor detection system, a data acquisition device, and an electric spark ignition device was set up to investigate fuel/air deflagration flame propagat... An experimental system that consisted of gas mixing equipment, a sensor detection system, a data acquisition device, and an electric spark ignition device was set up to investigate fuel/air deflagration flame propagation and quenching processes through a crimped-ribbon flame arrester in an enclosed horizontal pipe. Deflagration suppression experiments showed that when the concentration of flammable gas was close to the stoichiometric ratio, the evolution processes of explosion pressure for the propane-air and ethylene-air premixed gases in the pipe diameter (DN32-DN400) were similar and could be divided into four stages: isobaric combustion, slow pressure rise, quick pressure rise, and pressure oscillation. However, the explosion duration of the hydrogen-air premixed gas was relatively short, and the peak explosion pressure was high. The pressure rose quickly after the isobaric combustion stage. Therefore, the process can be divided into three stages in the pipe diameter (DN15-DN150). Deflagration speed results indicated that the propane-air flame speed initially increased and eventually decreased along with increases in the pipe diameter (DN32-DN400); however, the ethylene-air flame speed gradually increased with the increase of the pipe diameter (DNS0-DN400). No notable pattern of change in the hydrogen-air flame speed was observed in the pipe diameter (DN15-DN150). The maximum propane-air flame speed occurred at 5% concentration. The maximum flame speed for ethylene-air and hydrogen-air happened when the mixture was close to stoichiometric ratio. Under the conditions of the same size of experimental tube configuration and the same ignition distance but different pipe lengths, or the same pipe length but different ignition distances, experimental results showed that the flame arrester successfully stopped the flames at high flame speed and low explosion pressure, but failed at low flame speed and high explosion pressure. 展开更多
关键词 deflagration flame crimped-ribbon flame arrester explosion pressure flame speed flammable gas concentration
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