Using the glucose and L-glutamic-acid to prepare the standard substance according to the ratio of 1:1, and the artificial seawater and the standard substance to prepare a series of standard solutions, the distributio...Using the glucose and L-glutamic-acid to prepare the standard substance according to the ratio of 1:1, and the artificial seawater and the standard substance to prepare a series of standard solutions, the distribution pattern of uncertainty in measurement of seawater COD is obtained based on the measured results of the series of standard solutions by the potassium iodide-alkaline potassium permanganate determination method. The distribution pattern is as follows: Uncertainty in measurement is big and not constant at the high end, but small and constant at the low end.展开更多
The effects of nitrate concentration in the main anoxic zone on denitrifying dephosphatation capability were conducted based on modified University of Cape Town (MUCT) process. Meanwhile the relation between optimal...The effects of nitrate concentration in the main anoxic zone on denitrifying dephosphatation capability were conducted based on modified University of Cape Town (MUCT) process. Meanwhile the relation between optimal nitrate concentration (Nopt) and influent C/N ratio was evaluated, in which the influont chemical oxygen demand (COD) concentration was stabilized at (2905:10)mg/L, the influent total phosphorus (TP) concentration was stabilized at (7.0±0. 5)mg/L. The results indicated that: (1) the nitrate concentration in the main anoxic zone had an effect on denitrifying dephosphatation capability, and the average percentages of anoxic phosphorus uptake in total phosphorus uptake (ηa) increased with nitrate cancentration increasing, i.e., increasing from 62.1% at2.0 mg/L to63.7%, 65.6%, 68.1%, and 72.3% at 2.2, 2.4, 2.6 and 2.8mg/L, respectively; (2) the Nopt as function of influent C/N ratio could be calculated by the equation: y = 0.67x^2-7.79x + 22. 21; the maximum percentages of anoxic phosphorus uptake in total phosphorus uptake (ηa,max) as function of the Nopt could be calculated by the equation: y=0.77-0.33e^-(x/1.52). The Nopt was the important control parameter that must be optimized for operation of conveational biological nutrieat removal activated sludge (BNRAS) system.展开更多
There are many factors affecting the performance of a treatment system especially in the treatment of palm oil mill effluent (POME) as its contains high amounts of suspended solid, low pH, high salt content and high...There are many factors affecting the performance of a treatment system especially in the treatment of palm oil mill effluent (POME) as its contains high amounts of suspended solid, low pH, high salt content and high chemical oxygen demand (COD). However, one factor at a time approach is complicated method in establishing relationship between multiple parameters. Response surface methodology (RSM) is a recommended approach as it is widely used to analyze and study the interactions between multiple parameters and provides optimum output as well as minimizing the defects which result in good treatment system. This paper overviews the recent and current research in the application of RSM in optimizing the treatment development of POME.展开更多
Biological treatment efficiency of six pharmaceutical compounds (acetazolamide, metronidazole, opipramol, piracetam, salicylamide and tinidazole) was evaluated using lab-scale Sequencing Batch Reactor (SBR). Compa...Biological treatment efficiency of six pharmaceutical compounds (acetazolamide, metronidazole, opipramol, piracetam, salicylamide and tinidazole) was evaluated using lab-scale Sequencing Batch Reactor (SBR). Comparative biological degradation processes of two types of activated sludge from municipal and pharmaceutical industry sewage treatment plants were examined. Three different organic loadings (0.05 g COD/g MLSS.d, 0.1 g COD/g MLSS.d and 0.2 g COD/g MLSS-d) and reaction time on the efficiency of Active Pharmaceutical Ingredient (API) decomposition were examined. Chemical oxygen demand, non-purgeable organic carbon as well as ammonium nitrogen contents were monitored by standard methods. Percentage of API decomposition was analysed by High Performance Liquid Chromatography (HPLC). The overall API removal efficiency was strictly dependent on the type of activated sludge origin. The main biodegradation products were identified using HPLC-MS,1H NMR and 13C NMR methods as e.g. ({4-[3-(5H-dibenzo[b,f]azepin-5-yl]piperazin-l-yl}methanamine) and (2-amino-1,3,4-thiadiazol-5-sulfonamide) for opipramol and acetazolamide respectively.展开更多
The K-COD (K-Complete Orthogonal Decomposition) algorithm for generating adaptive dictionary for signals sparse representation in the framework of K-means clustering is proposed in this paper,in which rank one approxi...The K-COD (K-Complete Orthogonal Decomposition) algorithm for generating adaptive dictionary for signals sparse representation in the framework of K-means clustering is proposed in this paper,in which rank one approximation for components assembling signals based on COD and K-means clustering based on chaotic random search are well utilized. The results of synthetic test and empirical experiment for the real data show that the proposed algorithm outperforms recently reported alternatives: K-Singular Value Decomposition (K-SVD) algorithm and Method of Optimal Directions (MOD) algorithm.展开更多
文摘Using the glucose and L-glutamic-acid to prepare the standard substance according to the ratio of 1:1, and the artificial seawater and the standard substance to prepare a series of standard solutions, the distribution pattern of uncertainty in measurement of seawater COD is obtained based on the measured results of the series of standard solutions by the potassium iodide-alkaline potassium permanganate determination method. The distribution pattern is as follows: Uncertainty in measurement is big and not constant at the high end, but small and constant at the low end.
基金Water Pollution Control and Management of Science and Technology Majon Projects (No.2008ZX07207005)The Programs for Development of Science and Technology of Jilin Province of China (No.20071105)
文摘The effects of nitrate concentration in the main anoxic zone on denitrifying dephosphatation capability were conducted based on modified University of Cape Town (MUCT) process. Meanwhile the relation between optimal nitrate concentration (Nopt) and influent C/N ratio was evaluated, in which the influont chemical oxygen demand (COD) concentration was stabilized at (2905:10)mg/L, the influent total phosphorus (TP) concentration was stabilized at (7.0±0. 5)mg/L. The results indicated that: (1) the nitrate concentration in the main anoxic zone had an effect on denitrifying dephosphatation capability, and the average percentages of anoxic phosphorus uptake in total phosphorus uptake (ηa) increased with nitrate cancentration increasing, i.e., increasing from 62.1% at2.0 mg/L to63.7%, 65.6%, 68.1%, and 72.3% at 2.2, 2.4, 2.6 and 2.8mg/L, respectively; (2) the Nopt as function of influent C/N ratio could be calculated by the equation: y = 0.67x^2-7.79x + 22. 21; the maximum percentages of anoxic phosphorus uptake in total phosphorus uptake (ηa,max) as function of the Nopt could be calculated by the equation: y=0.77-0.33e^-(x/1.52). The Nopt was the important control parameter that must be optimized for operation of conveational biological nutrieat removal activated sludge (BNRAS) system.
文摘There are many factors affecting the performance of a treatment system especially in the treatment of palm oil mill effluent (POME) as its contains high amounts of suspended solid, low pH, high salt content and high chemical oxygen demand (COD). However, one factor at a time approach is complicated method in establishing relationship between multiple parameters. Response surface methodology (RSM) is a recommended approach as it is widely used to analyze and study the interactions between multiple parameters and provides optimum output as well as minimizing the defects which result in good treatment system. This paper overviews the recent and current research in the application of RSM in optimizing the treatment development of POME.
文摘Biological treatment efficiency of six pharmaceutical compounds (acetazolamide, metronidazole, opipramol, piracetam, salicylamide and tinidazole) was evaluated using lab-scale Sequencing Batch Reactor (SBR). Comparative biological degradation processes of two types of activated sludge from municipal and pharmaceutical industry sewage treatment plants were examined. Three different organic loadings (0.05 g COD/g MLSS.d, 0.1 g COD/g MLSS.d and 0.2 g COD/g MLSS-d) and reaction time on the efficiency of Active Pharmaceutical Ingredient (API) decomposition were examined. Chemical oxygen demand, non-purgeable organic carbon as well as ammonium nitrogen contents were monitored by standard methods. Percentage of API decomposition was analysed by High Performance Liquid Chromatography (HPLC). The overall API removal efficiency was strictly dependent on the type of activated sludge origin. The main biodegradation products were identified using HPLC-MS,1H NMR and 13C NMR methods as e.g. ({4-[3-(5H-dibenzo[b,f]azepin-5-yl]piperazin-l-yl}methanamine) and (2-amino-1,3,4-thiadiazol-5-sulfonamide) for opipramol and acetazolamide respectively.
基金Supported by the National Natural Science Foundation of China under Grants (No. 60872123 & U0835001)by Natural Science Foundation of Guangdong Province, China (No. 07006496)
文摘The K-COD (K-Complete Orthogonal Decomposition) algorithm for generating adaptive dictionary for signals sparse representation in the framework of K-means clustering is proposed in this paper,in which rank one approximation for components assembling signals based on COD and K-means clustering based on chaotic random search are well utilized. The results of synthetic test and empirical experiment for the real data show that the proposed algorithm outperforms recently reported alternatives: K-Singular Value Decomposition (K-SVD) algorithm and Method of Optimal Directions (MOD) algorithm.