In order to improve the wear resistance properties of copper substrate, a layer of electroplated nickel was firstly deposited on copper substrate, subsequently these electroplated specimens were treated by slurry pack...In order to improve the wear resistance properties of copper substrate, a layer of electroplated nickel was firstly deposited on copper substrate, subsequently these electroplated specimens were treated by slurry pack cementation process with a slurry pack cementation mixture composed of TiO2 as titanizing source, pure Al powder as aluminzing source and also a reducer for titanizing, an activator of NH4Cl and albumen (egg white) as cohesive agent. The Ti-Al coating was fabricated on the surface of electro-deposited nickel layer on copper matrix followed by the slurry pack cementation process. The effects of slurry pack cementation temperature on the microstructures and wear resistance of Ti-Al coating were studied. The results show that the microstructure of the coating changed from NiAl+Ni3(Ti,Al) to NiAl +Ni3(Ti,Al)+Ni4Ti3 to Ni4Ti3+NiAl, and to NiAl+Ni3(Ti,Al)+NiTi with slurry pack cementation temperature ranging from 800 ℃ to 950 ℃ in 12 h. The friction coefficient of Ti-Al coating decreased and the hardness increased with increasing the slurry pack cementation temperature. The minimum friction coefficient was 1/3 and the minimum hardness was 5 times larger than that of pure copper.展开更多
The activated nitrogen-enriched novel carbons (NENCs) were prepared by direct carbonization using polyaniline coating activated mesocarbon microbead composites as the precursor. Herein the influences of the carbonizat...The activated nitrogen-enriched novel carbons (NENCs) were prepared by direct carbonization using polyaniline coating activated mesocarbon microbead composites as the precursor. Herein the influences of the carbonization temperature on the structure and morphology of the NENCs samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and N2 adsorption/desorption isotherm at 77 K. The electrochemical properties of the supercapacitors were characterized by cyclic voltammetry, galvanostatic charge/discharge, electrochemical impedance spectroscopy (EIS), cycle life, leakage current and self-discharge measurements in 6 mol/L KOH solution. The results demonstrate that the NENC samples carbonized at 600 °C show the highest specific capacitance of 385 F/g at the current density of 1 A/g and the lowest ESR value (only 0.93?). Furthermore, the capacity retention ratio of the NENCs-600 supercapacitor is 92.8 % over 2500 cycles.展开更多
The effect of temperature on the corrosion behavior of copper in simulated high-level nuclear waste environment wassystematically studied.Electrochemical methods,including electrochemical impendence spectra,Mott–Scho...The effect of temperature on the corrosion behavior of copper in simulated high-level nuclear waste environment wassystematically studied.Electrochemical methods,including electrochemical impendence spectra,Mott–Schottky technology,cyclicpolarization,and potentiostatic polarization,were employed to characterize the corrosion behavior of copper at different temperatures.Stereoscopic microscopy and scanning electron microscopy were used to examine the surface morphology,and X-ray photoelectronspectroscopy analysis was used to identify the composition of the passive film.The experimental results show that corrosionresistance of the passive film does not blindly decrease with the increase of temperature but increases at60°C owing to a compactouter layer;there is a potential for pitting corrosion,which decreases as the temperature increases.The main product of copper in ananaerobic aqueous sulfide solution is Cu2S but the content of CuS increases at higher temperatures.The whole passivation rangeshows p-type semiconductor characteristics and the magnitude of the acceptor density is1023cm-3,which increases with increasingtemperature.展开更多
Twenty-one square concrete columns were constructed and tested. The testing results indicate that bonded carbon fiber reinforced plastics(CFRP) sheets can be used to increase the strength and improve the serviceabilit...Twenty-one square concrete columns were constructed and tested. The testing results indicate that bonded carbon fiber reinforced plastics(CFRP) sheets can be used to increase the strength and improve the serviceability of damaged concrete columns at low temperatures. The failure of the specimens,in most cases,takes place within the middle half of the columns. And the failure of strengthened columns is sudden and explosive. The CFRP sheets increase both the axial load capacity and the ultimate concrete compressive strain of the columns. The ultimate loads of strengthened columns at-10,0 and 10 ℃ increase averagely by 9.09%,6.63% and 17.83%,respectively,as compared with those of the control specimens. The axial compressive strength of strengthened columns is related to the curing temperatures. The improvement of axial compressive strength decreases with reducing temperature,and when the temperature drops to a certain value,the improvement increases with falling temperature.展开更多
β-Sialon based composites were successfully prepared from fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-nitridation process. Effects of heating temperature and raw materials composition...β-Sialon based composites were successfully prepared from fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-nitridation process. Effects of heating temperature and raw materials composition on synthesis process were investigated, and the formation process of the composites was also discussed. The phase composition and microstructure of the composites were characterized by X-ray diffraction and scanning electronic microscopy. The results show that increasing heating temperature or mass ratio of carbon black to fly ash can promote the formation of β-Sialon. The β-Sialon based composites can be synthesized at 1723 K for 6 h while heating the sample with mass ratio of carbon black to fly ash of 0.56. The as-received β-Sialon in the composites exists as granular with an average particle size of 2-3 μm. The preparation process of β-Sialon based composites includes the formation of O′-Sialon, X-Sialon and β-Sialon as well as the conversion processes of O′-Sialon and X-Sialon to β-Sialon.展开更多
The hydrogenation reaction characteristics and the properties of its hydrides for the magnetic regenerative material HoCu_2(CeCu_2-type) of a cryocooler were investigated. The XRD testing reveals that the hydrides of ...The hydrogenation reaction characteristics and the properties of its hydrides for the magnetic regenerative material HoCu_2(CeCu_2-type) of a cryocooler were investigated. The XRD testing reveals that the hydrides of HoCu_2 were a mixture of Cu, unknown hydride Ⅰ, and unknown hydride Ⅱ. Based on the PCT(pressure-concentration-temperature) curves under different reaction temperatures, the relationships among reaction temperature, equilibrium pressure, and maximum hydrogen absorption capacity were analyzed and discussed. The enthalpy change ΔH and entropy change ΔS as a result of the whole hydrogenation process were also calculated from the PCT curves. The magnetization and volumetric specific heat capacity of the hydride were also measured by SQUID magnetometer and PPMS, respectively.展开更多
The cloud-detection procedure developed by McNally and Watts(MW03) was added to the Weather Research and Forecasting Data Assimilation System. To provide some guidelines for setting up cloud-detection schemes, this st...The cloud-detection procedure developed by McNally and Watts(MW03) was added to the Weather Research and Forecasting Data Assimilation System. To provide some guidelines for setting up cloud-detection schemes, this study compares the MW03 scheme to the Multivariate and Minimum Residual(MMR) scheme for both simulated and real Advanced Infrared Sounder(AIRS) radiances. Results show that there is a high level of consistency between the results from simulated and real AIRS data. As expected, both cloud-detection schemes perform well in finding the cloud-contaminated channels based on the channels' peak levels. The clouddetection results from MW03 are sensitive to the prescribed brightness temperature innovation threshold and brightness temperature gradient threshold. When increasing the brightness temperature innovation threshold for MW03 to roughly eight times the default threshold, the two cloud-detection schemes produce consistent data rejection distributions overall for high channels. MMR generally retains more data for long-wave channels. For both cloud-detection schemes, there is a high level of consistency between the cloud-free pixels and the visible/near-IR(Vis/NIR) cloud mask.展开更多
Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechani...Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechanical behaviors at the solid state of the mix. This study focused on the behavior of a new kind of admixture at fresh and solid states. Currently, the concrete material has become a very expensive material because the high price mostly of aggregates, representing the three quarters of the concrete components. By consequence, it costs money and on the other hand, it produces a lot of wastes. The main aspect which guides this study is to make a kind of concrete based mainly on local material and sustainable concrete material (SCM or waste material), which is one very abundant material in quality and quantity, under the current tendency the results obtained in this study summarize up the importance of the temperature during the development of the mechanical characteristics of mortar, mainly on compressive strength at age of 28 days. This is in the case of the addition of limestone crushed additive by percentage of substitution.展开更多
This work shows the comparison between the results of wind and temperature simulation and data weather measurements in low layers near Gualeguaychfi City, Argentine, for 12 h in January 1, 2011. The model ARPS (advan...This work shows the comparison between the results of wind and temperature simulation and data weather measurements in low layers near Gualeguaychfi City, Argentine, for 12 h in January 1, 2011. The model ARPS (advanced regional prediction system) with two options in the boundary conditions is used. In such conditions, wave-radiating open (radiative) with relaxation to the initial state were used while otherwise used absorbing boundary conditions data forced from MBLM (meso-scale boundary layer model) operational forecasters used by the National Weather Office. The results of both simulations are compared with data measured by three weather stations located around of the Uruguay River. As both simulations are initialized using the same data, there is a better agreement between the values obtained by forcing the boundary conditions for which are using "radiative" boundary conditions after 2 h physical time from the start of the simulation.展开更多
Carbon-carbon composite (C/C) materials are prone to severe oxidation and volatilization problems. To address these issues, mullite (3Al2O3.2SiO2)/silicon carbide (SIC) coatings were deposited on C/C composite s...Carbon-carbon composite (C/C) materials are prone to severe oxidation and volatilization problems. To address these issues, mullite (3Al2O3.2SiO2)/silicon carbide (SIC) coatings were deposited on C/C composite substrates characterized into high and low densities. The coatings were applied by a two-step approach: pack cementation and silica sol based slurry coating processes. The relationship between the microstructure of 3Al2O3·2SiO2/SiC coatings and C/C substrates during isothermal oxidation cycle at 1 500 ℃ was investigated using X-ray diffractometer (XRD) and scanning electron microscope (SEM) mounted with energy dispersive spectrometer (EDS). The results indicate that the density of the substrates has a marked effect on the coatings. Dense, thick and well-bonded coatings are obtained in the high density substrate. After 106 h of isothermal oxidation, the high density substrate with 3Al2O3-2SiO2/SiC coating offers effective protection as compared to low density substrate suffering recession.展开更多
The great major applications of thermal isolation are in the strip of drops and averages temperatures (up to 180 ℃), which is used from aggressive materials to the nature, such as glass wool, rock wool, polystyrene...The great major applications of thermal isolation are in the strip of drops and averages temperatures (up to 180 ℃), which is used from aggressive materials to the nature, such as glass wool, rock wool, polystyrene, EPS among others. In spite of the effectiveness in the retention of the flow of heat, such materials possess considerable cost and they are discarded for long years to be decomposed. In that context, to adapt to the world politics about the preservation of the environment, a study began with intention of developing a material composite with thermal properties, originating from insulating industrial residues. In this research, the behavior of this composite was analyzed, when it submitted traction efforts. For this, a term-mechanic was used (DMA), where the composite was differentiated under variation temperatures. It was also certain that the gradient temperature of the composite was the source of heat, the conductivity and thermal diffusion. Consequently, the function of the answers of the system was possible to be observed with the deformation of the composite with the tension and temperature variation, as well as the temperature gradient for each proportion of the composite.展开更多
Dimethyl carbonate is an environmentally benign and biodegradable chemical.Based on integration of reactive distillation and pressure-swing distillation technologies,a novel process for synthesis of dimethyl carbonate...Dimethyl carbonate is an environmentally benign and biodegradable chemical.Based on integration of reactive distillation and pressure-swing distillation technologies,a novel process for synthesis of dimethyl carbonate through transesterification with propylene carbonate and methanol has been developed by Huang et al.In this work,the optimization of this process was performed by minimizing the total TAC.The results show that the optimal design flowsheet can save energy consumption by 18.6% with the propylene carbonate conversion of 99.9%.Then,an effective plant-wide control structure for the process was developed.Dynamic simulation results demonstrate that the temperature/flow rate cascade control plus with simple temperature control can keep not only product purity but also the conversion of the reactant at their desired values in the face of the disturbance in reactant feed flow rate and feed composition.展开更多
Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient relea...Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tgof coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection.展开更多
The materials used in fuel cells are currently the subject of much research, particularly those of the cathode which is a key element for the different functions that it provides. In our work the authors became intere...The materials used in fuel cells are currently the subject of much research, particularly those of the cathode which is a key element for the different functions that it provides. In our work the authors became interested in the different materials used for the cathode, which are usually ceramic, and some of their physical properties between different electrical conductivity (electronic, ionic), the coefficient of thermal expansion and chemical compatibility between different materials used in the stack. Not to mention, however, the various parameters that influence these properties, such as structure, the sintering temperature, dope, and the operating temperature of the battery. The main objective of research in this area is to improve battery performance by researching new materials and new manufacturing technologies that will increase the electrical conductivity while trying to lower the temperature operating the latter as much as possible while keeping it above 650℃, In doing so, the longevity of the battery will be increased which will have a direct impact on manufacturing costs of the battery, and thus greater use thereof.展开更多
Oxidation and burning behaviors were studied for CaO added AM50 Mg composites which were manufactured by conventional melting and casting processes without SF6 protective gas. CaO added AM50 Mg composites show the sta...Oxidation and burning behaviors were studied for CaO added AM50 Mg composites which were manufactured by conventional melting and casting processes without SF6 protective gas. CaO added AM50 Mg composites show the stable oxidation resistance, while AMS0 Mg alloys show the poor oxidation resistance. The effects of CaO addition on the burning resistance under ambient, nitrogen and dry air atmospheres were examined for CaO added AM50 Mg composites. With increasing CaO addition, the burning temperature increases under ambient, nitrogen and dry air atmospheres. The burning temperatures of small test specimen under all conditions greatly increase even by 0.3% CaO (mass fraction) addition into AM50 Mg alloys.展开更多
Organic dust flames deal with a field of science in which many complicated phenomena like pyrolysis or devolatization of solid particles and combustion of volatile particles take place. One-dimensional flame propagati...Organic dust flames deal with a field of science in which many complicated phenomena like pyrolysis or devolatization of solid particles and combustion of volatile particles take place. One-dimensional flame propagation in cloud of fuel mixture is analyzed in which flame structure is divided into three zones. The first zone is preheat zone in which rate of the chemical reaction is small and transfer phenomena play significant role in temperature and mass distributions. In this model, it is assumed that particles pyrolyze first to yield a gaseous fuel mixture. The second zone is reaction zone where convection and vaporization rates of the particles are small. The third zone is convection zone where diffusive terms are negligible in comparison of other terms. Non-zero Biot number is used in order to study effect of particles thermal resistance on flame characteristics. Also, effect of particle size on combustion of micro organic dust is investigated. According to obtained results, it is understood that both flame temperature and burning velocity decrease with rise in the Biot number and particle size.展开更多
The scheduling process of cracking furnace feedstock is important in an ethylene plant. In this paper it is described as a constraint optimization problem. The constraints consist of the cycle of operation, maximum tu...The scheduling process of cracking furnace feedstock is important in an ethylene plant. In this paper it is described as a constraint optimization problem. The constraints consist of the cycle of operation, maximum tube metal temperature, process time of each feedstock, and flow rate. A modified group search optimizer is proposed to deal with the optimization problem. Double fitness values are defined for every group. First, the factor of penalty function should be changed adaptively by the ratio of feasible and general solutions. Second, the "excellent" infeasible solution should be retained to guide the search. Some benchmark functions are used to evaluate the new algorithm. Finally, the proposed algorithm is used to optimize the scheduling process of cracking furnace feedstock. And the optimizing result is obtained.展开更多
In the field of highly integrated printed circuit board (PCB), the heat resistant substrate with low water absorption is very important material. To get the resin composition for the high functional substrate materi...In the field of highly integrated printed circuit board (PCB), the heat resistant substrate with low water absorption is very important material. To get the resin composition for the high functional substrate material with low moisture absorption and high glass transition temperature (Tg) simultaneously, a fluorenyl "Cardo" epoxy was incorporated into novolac cyanate ester resin. As an optimum curing agent for the fiuorenyl epoxy, methyl nadic anhydride (MNA) was selected. Silica powders as fillers were added into the resin composition. The partial replacement of the cyanate ester resin with the fluorenyl epoxy could reduce the moisture absorption with keeping high glass transition temperature over 300 ℃. The laminate, which was fabricated from prepregs made with 40 wt% silica-filled resin composition and glass fabric, showed high Tg of 317 ℃ and low moisture absorption of 0.57%.展开更多
In this study, the bending test is used to investigate the glass transition temperature for epoxy reinforced with three types ot fibers, fiberglass, Kevlar and synthetic wool, these materials have a wide used in many ...In this study, the bending test is used to investigate the glass transition temperature for epoxy reinforced with three types ot fibers, fiberglass, Kevlar and synthetic wool, these materials have a wide used in many application which they are used composite materials. The glass transition temperature can be measured at the point of inflection for "the curve of variation of the deflection and temperature. The results show that, the glass transition temperature is affected by the type of the reinforcement of the composites. On the other hand, the glass transition temperature of the wool composite is higher than the other.展开更多
基金Projects(YKJ201203,CKJB201205)supported by the Nanjing Institute of Technology,China
文摘In order to improve the wear resistance properties of copper substrate, a layer of electroplated nickel was firstly deposited on copper substrate, subsequently these electroplated specimens were treated by slurry pack cementation process with a slurry pack cementation mixture composed of TiO2 as titanizing source, pure Al powder as aluminzing source and also a reducer for titanizing, an activator of NH4Cl and albumen (egg white) as cohesive agent. The Ti-Al coating was fabricated on the surface of electro-deposited nickel layer on copper matrix followed by the slurry pack cementation process. The effects of slurry pack cementation temperature on the microstructures and wear resistance of Ti-Al coating were studied. The results show that the microstructure of the coating changed from NiAl+Ni3(Ti,Al) to NiAl +Ni3(Ti,Al)+Ni4Ti3 to Ni4Ti3+NiAl, and to NiAl+Ni3(Ti,Al)+NiTi with slurry pack cementation temperature ranging from 800 ℃ to 950 ℃ in 12 h. The friction coefficient of Ti-Al coating decreased and the hardness increased with increasing the slurry pack cementation temperature. The minimum friction coefficient was 1/3 and the minimum hardness was 5 times larger than that of pure copper.
基金Projects(51072173,51272221)supported by the National Natural Science Foundation of ChinaProject(20094301110005)supported by Specialized Research Fund for the Doctoral Program of Higher Education,ChinaProject(2013FJ4062)supported by Science and Technology Plan Foundation of Hunan Province,China
文摘The activated nitrogen-enriched novel carbons (NENCs) were prepared by direct carbonization using polyaniline coating activated mesocarbon microbead composites as the precursor. Herein the influences of the carbonization temperature on the structure and morphology of the NENCs samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and N2 adsorption/desorption isotherm at 77 K. The electrochemical properties of the supercapacitors were characterized by cyclic voltammetry, galvanostatic charge/discharge, electrochemical impedance spectroscopy (EIS), cycle life, leakage current and self-discharge measurements in 6 mol/L KOH solution. The results demonstrate that the NENC samples carbonized at 600 °C show the highest specific capacitance of 385 F/g at the current density of 1 A/g and the lowest ESR value (only 0.93?). Furthermore, the capacity retention ratio of the NENCs-600 supercapacitor is 92.8 % over 2500 cycles.
基金Project(FRF-TP-14-011C1) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2014CB643300) supported by the National Basic Research Program of China
文摘The effect of temperature on the corrosion behavior of copper in simulated high-level nuclear waste environment wassystematically studied.Electrochemical methods,including electrochemical impendence spectra,Mott–Schottky technology,cyclicpolarization,and potentiostatic polarization,were employed to characterize the corrosion behavior of copper at different temperatures.Stereoscopic microscopy and scanning electron microscopy were used to examine the surface morphology,and X-ray photoelectronspectroscopy analysis was used to identify the composition of the passive film.The experimental results show that corrosionresistance of the passive film does not blindly decrease with the increase of temperature but increases at60°C owing to a compactouter layer;there is a potential for pitting corrosion,which decreases as the temperature increases.The main product of copper in ananaerobic aqueous sulfide solution is Cu2S but the content of CuS increases at higher temperatures.The whole passivation rangeshows p-type semiconductor characteristics and the magnitude of the acceptor density is1023cm-3,which increases with increasingtemperature.
基金Project(04043076) supported by the Outstanding Youth Foundation for Scientific and Technological Research of Anhui Province, ChinaProject(2007jq1035) supported by the Scientific Research Projects for Young College Teachers of Anhui Province, China
文摘Twenty-one square concrete columns were constructed and tested. The testing results indicate that bonded carbon fiber reinforced plastics(CFRP) sheets can be used to increase the strength and improve the serviceability of damaged concrete columns at low temperatures. The failure of the specimens,in most cases,takes place within the middle half of the columns. And the failure of strengthened columns is sudden and explosive. The CFRP sheets increase both the axial load capacity and the ultimate concrete compressive strain of the columns. The ultimate loads of strengthened columns at-10,0 and 10 ℃ increase averagely by 9.09%,6.63% and 17.83%,respectively,as compared with those of the control specimens. The axial compressive strength of strengthened columns is related to the curing temperatures. The improvement of axial compressive strength decreases with reducing temperature,and when the temperature drops to a certain value,the improvement increases with falling temperature.
基金Project (51074038) supported by the National Natural Science Foundation of ChinaProject (N100302002) supported by the Fundamental Research Funds for the Central Universities, China
文摘β-Sialon based composites were successfully prepared from fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-nitridation process. Effects of heating temperature and raw materials composition on synthesis process were investigated, and the formation process of the composites was also discussed. The phase composition and microstructure of the composites were characterized by X-ray diffraction and scanning electronic microscopy. The results show that increasing heating temperature or mass ratio of carbon black to fly ash can promote the formation of β-Sialon. The β-Sialon based composites can be synthesized at 1723 K for 6 h while heating the sample with mass ratio of carbon black to fly ash of 0.56. The as-received β-Sialon in the composites exists as granular with an average particle size of 2-3 μm. The preparation process of β-Sialon based composites includes the formation of O′-Sialon, X-Sialon and β-Sialon as well as the conversion processes of O′-Sialon and X-Sialon to β-Sialon.
基金Project(51276154)supported by the National Natural Science Foundation of ChinaProject(2012010111014)supported by the University Doctoral Subject Special Foundation of China
文摘The hydrogenation reaction characteristics and the properties of its hydrides for the magnetic regenerative material HoCu_2(CeCu_2-type) of a cryocooler were investigated. The XRD testing reveals that the hydrides of HoCu_2 were a mixture of Cu, unknown hydride Ⅰ, and unknown hydride Ⅱ. Based on the PCT(pressure-concentration-temperature) curves under different reaction temperatures, the relationships among reaction temperature, equilibrium pressure, and maximum hydrogen absorption capacity were analyzed and discussed. The enthalpy change ΔH and entropy change ΔS as a result of the whole hydrogenation process were also calculated from the PCT curves. The magnetization and volumetric specific heat capacity of the hydride were also measured by SQUID magnetometer and PPMS, respectively.
基金sponsored by the National Basic Research Program of China (973 Program, 2013CB430102)the Program of Scientific Innovation Research of College Graduate in Jiangsu Province (Grant Nos. CXZZ12-0490 and CXZZ11-0606)The National Center for Atmospheric Research is sponsored by the National Science Foundation
文摘The cloud-detection procedure developed by McNally and Watts(MW03) was added to the Weather Research and Forecasting Data Assimilation System. To provide some guidelines for setting up cloud-detection schemes, this study compares the MW03 scheme to the Multivariate and Minimum Residual(MMR) scheme for both simulated and real Advanced Infrared Sounder(AIRS) radiances. Results show that there is a high level of consistency between the results from simulated and real AIRS data. As expected, both cloud-detection schemes perform well in finding the cloud-contaminated channels based on the channels' peak levels. The clouddetection results from MW03 are sensitive to the prescribed brightness temperature innovation threshold and brightness temperature gradient threshold. When increasing the brightness temperature innovation threshold for MW03 to roughly eight times the default threshold, the two cloud-detection schemes produce consistent data rejection distributions overall for high channels. MMR generally retains more data for long-wave channels. For both cloud-detection schemes, there is a high level of consistency between the cloud-free pixels and the visible/near-IR(Vis/NIR) cloud mask.
文摘Nowadays, technologies in construction field have offered several kinds of chemical admixtures, which offer different behaviors at the fresh state of the batch and by consequence, it is resulted with different mechanical behaviors at the solid state of the mix. This study focused on the behavior of a new kind of admixture at fresh and solid states. Currently, the concrete material has become a very expensive material because the high price mostly of aggregates, representing the three quarters of the concrete components. By consequence, it costs money and on the other hand, it produces a lot of wastes. The main aspect which guides this study is to make a kind of concrete based mainly on local material and sustainable concrete material (SCM or waste material), which is one very abundant material in quality and quantity, under the current tendency the results obtained in this study summarize up the importance of the temperature during the development of the mechanical characteristics of mortar, mainly on compressive strength at age of 28 days. This is in the case of the addition of limestone crushed additive by percentage of substitution.
文摘This work shows the comparison between the results of wind and temperature simulation and data weather measurements in low layers near Gualeguaychfi City, Argentine, for 12 h in January 1, 2011. The model ARPS (advanced regional prediction system) with two options in the boundary conditions is used. In such conditions, wave-radiating open (radiative) with relaxation to the initial state were used while otherwise used absorbing boundary conditions data forced from MBLM (meso-scale boundary layer model) operational forecasters used by the National Weather Office. The results of both simulations are compared with data measured by three weather stations located around of the Uruguay River. As both simulations are initialized using the same data, there is a better agreement between the values obtained by forcing the boundary conditions for which are using "radiative" boundary conditions after 2 h physical time from the start of the simulation.
基金Project(2011CB605805) supported by the National Basic Research Program of ChinaProject(51021063) supported by the Creative Research Group of National Natural Science Foundation of China
文摘Carbon-carbon composite (C/C) materials are prone to severe oxidation and volatilization problems. To address these issues, mullite (3Al2O3.2SiO2)/silicon carbide (SIC) coatings were deposited on C/C composite substrates characterized into high and low densities. The coatings were applied by a two-step approach: pack cementation and silica sol based slurry coating processes. The relationship between the microstructure of 3Al2O3·2SiO2/SiC coatings and C/C substrates during isothermal oxidation cycle at 1 500 ℃ was investigated using X-ray diffractometer (XRD) and scanning electron microscope (SEM) mounted with energy dispersive spectrometer (EDS). The results indicate that the density of the substrates has a marked effect on the coatings. Dense, thick and well-bonded coatings are obtained in the high density substrate. After 106 h of isothermal oxidation, the high density substrate with 3Al2O3-2SiO2/SiC coating offers effective protection as compared to low density substrate suffering recession.
文摘The great major applications of thermal isolation are in the strip of drops and averages temperatures (up to 180 ℃), which is used from aggressive materials to the nature, such as glass wool, rock wool, polystyrene, EPS among others. In spite of the effectiveness in the retention of the flow of heat, such materials possess considerable cost and they are discarded for long years to be decomposed. In that context, to adapt to the world politics about the preservation of the environment, a study began with intention of developing a material composite with thermal properties, originating from insulating industrial residues. In this research, the behavior of this composite was analyzed, when it submitted traction efforts. For this, a term-mechanic was used (DMA), where the composite was differentiated under variation temperatures. It was also certain that the gradient temperature of the composite was the source of heat, the conductivity and thermal diffusion. Consequently, the function of the answers of the system was possible to be observed with the deformation of the composite with the tension and temperature variation, as well as the temperature gradient for each proportion of the composite.
基金Supported by the National Natural Science Foundation of China(21306025,21576053)the International Science&Technology Cooperation Program of China(2013DFR90540)
文摘Dimethyl carbonate is an environmentally benign and biodegradable chemical.Based on integration of reactive distillation and pressure-swing distillation technologies,a novel process for synthesis of dimethyl carbonate through transesterification with propylene carbonate and methanol has been developed by Huang et al.In this work,the optimization of this process was performed by minimizing the total TAC.The results show that the optimal design flowsheet can save energy consumption by 18.6% with the propylene carbonate conversion of 99.9%.Then,an effective plant-wide control structure for the process was developed.Dynamic simulation results demonstrate that the temperature/flow rate cascade control plus with simple temperature control can keep not only product purity but also the conversion of the reactant at their desired values in the face of the disturbance in reactant feed flow rate and feed composition.
基金Supported by the National 12th Five-Year Science and Technology Supporting Program(2011BAD11B01)the Research & Development Projects Cooperation Project of Chinese Academy of Sciences(YDJDBNJ-2012-023)
文摘Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tgof coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection.
文摘The materials used in fuel cells are currently the subject of much research, particularly those of the cathode which is a key element for the different functions that it provides. In our work the authors became interested in the different materials used for the cathode, which are usually ceramic, and some of their physical properties between different electrical conductivity (electronic, ionic), the coefficient of thermal expansion and chemical compatibility between different materials used in the stack. Not to mention, however, the various parameters that influence these properties, such as structure, the sintering temperature, dope, and the operating temperature of the battery. The main objective of research in this area is to improve battery performance by researching new materials and new manufacturing technologies that will increase the electrical conductivity while trying to lower the temperature operating the latter as much as possible while keeping it above 650℃, In doing so, the longevity of the battery will be increased which will have a direct impact on manufacturing costs of the battery, and thus greater use thereof.
文摘Oxidation and burning behaviors were studied for CaO added AM50 Mg composites which were manufactured by conventional melting and casting processes without SF6 protective gas. CaO added AM50 Mg composites show the stable oxidation resistance, while AMS0 Mg alloys show the poor oxidation resistance. The effects of CaO addition on the burning resistance under ambient, nitrogen and dry air atmospheres were examined for CaO added AM50 Mg composites. With increasing CaO addition, the burning temperature increases under ambient, nitrogen and dry air atmospheres. The burning temperatures of small test specimen under all conditions greatly increase even by 0.3% CaO (mass fraction) addition into AM50 Mg alloys.
文摘Organic dust flames deal with a field of science in which many complicated phenomena like pyrolysis or devolatization of solid particles and combustion of volatile particles take place. One-dimensional flame propagation in cloud of fuel mixture is analyzed in which flame structure is divided into three zones. The first zone is preheat zone in which rate of the chemical reaction is small and transfer phenomena play significant role in temperature and mass distributions. In this model, it is assumed that particles pyrolyze first to yield a gaseous fuel mixture. The second zone is reaction zone where convection and vaporization rates of the particles are small. The third zone is convection zone where diffusive terms are negligible in comparison of other terms. Non-zero Biot number is used in order to study effect of particles thermal resistance on flame characteristics. Also, effect of particle size on combustion of micro organic dust is investigated. According to obtained results, it is understood that both flame temperature and burning velocity decrease with rise in the Biot number and particle size.
基金Supported by the Major State Basic Research Development Program of China(2012CB720500)the National Natural Science Foundation of China(Key Program:U1162202),the National Natural Science Foundation of China(61174118)+2 种基金the National High-Tech Research and Development Program of China(2012AA040307)Shanghai Key Technologies R&D program(12dz1125100)Shanghai Leading Academic Discipline Project(B504)
文摘The scheduling process of cracking furnace feedstock is important in an ethylene plant. In this paper it is described as a constraint optimization problem. The constraints consist of the cycle of operation, maximum tube metal temperature, process time of each feedstock, and flow rate. A modified group search optimizer is proposed to deal with the optimization problem. Double fitness values are defined for every group. First, the factor of penalty function should be changed adaptively by the ratio of feasible and general solutions. Second, the "excellent" infeasible solution should be retained to guide the search. Some benchmark functions are used to evaluate the new algorithm. Finally, the proposed algorithm is used to optimize the scheduling process of cracking furnace feedstock. And the optimizing result is obtained.
文摘In the field of highly integrated printed circuit board (PCB), the heat resistant substrate with low water absorption is very important material. To get the resin composition for the high functional substrate material with low moisture absorption and high glass transition temperature (Tg) simultaneously, a fluorenyl "Cardo" epoxy was incorporated into novolac cyanate ester resin. As an optimum curing agent for the fiuorenyl epoxy, methyl nadic anhydride (MNA) was selected. Silica powders as fillers were added into the resin composition. The partial replacement of the cyanate ester resin with the fluorenyl epoxy could reduce the moisture absorption with keeping high glass transition temperature over 300 ℃. The laminate, which was fabricated from prepregs made with 40 wt% silica-filled resin composition and glass fabric, showed high Tg of 317 ℃ and low moisture absorption of 0.57%.
文摘In this study, the bending test is used to investigate the glass transition temperature for epoxy reinforced with three types ot fibers, fiberglass, Kevlar and synthetic wool, these materials have a wide used in many application which they are used composite materials. The glass transition temperature can be measured at the point of inflection for "the curve of variation of the deflection and temperature. The results show that, the glass transition temperature is affected by the type of the reinforcement of the composites. On the other hand, the glass transition temperature of the wool composite is higher than the other.