低纬度磁异常波数域化极方法机理分析与功能定位

基于化极算法误差方程,对三类波数域低纬度化极方法进行机理分析和功能定位。压制型化极法不能用于低纬度磁异常数据的定量解释,但可用于定性解释;反演化极法理论上可用于定量解释,但要求资料窗外的未知数据很好地被模拟(实测资料难以满足),因此不具有实用性;偏移抽样化极法理论上也可以用于定量解释,但该方法要求磁偏角方向上的数据(网格数)不超过64,且数据相对精度不低于0.2%。三类波数域低纬度化极方法的功能定位,可对低纬度磁测资料的解释发挥重要的指导作用。

低磁纬度地区磁异常化极方法及应用

化极作为一种重要的数据处理方法 ,很早就受到地球物理工作者的重视和研究 ,并已取得了不少研究成果。但在低磁纬度地区 ,作大面积化极换算并进行地质解释的工作仍处于探索阶段。采用频率域局部扇形约束函数改造化极因子的化极方法对南沙中部海磁数据的化极处理结果表明 ,该方法具有处理变倾角、低纬度资料的能力 ,数值恢复精度较高 ,在综合解释中 ,显示了良好的地质解释效果。

Theoretical Study on Stereodynamics of Reactions of N（^2D）＋H2→NH＋H and N（^2D）＋D2→ND＋D

The vector correlations between products and reagents for the title reactions have been calculated by the quasi-classical trajectory method at a collision energy of 21.32 kJ/mol on an accurate potential energy surface of Ho et al. （J. Chem. Phys. 119, 3063 （2003））. The peaks of the product angular distribution are found to be in both backward and forward directions for the two title reactions. The product rotational angular momentum is not only aligned, but also oriented along the negative direction of y-axis. These theoretical results are in good agreement with recent experimental findings for the two title reactions. The isotopic effect is also revealed and primarily attributed to the difference of the mass factor in the two title reactions.

Effect of heat treatment on corrosion properties of CuAlNi shape memory alloy

The effect of heat treatment on corrosion properties of CuAlNi shape memory alloy was investigated in 0.9% Na Cl solution at p H 7.4 and 37 ℃ by open circuit potential measurements, polarisation techniques, and electrochemical impedance spectroscopy. Investigations were performed on CuAlNi alloy samples in as-cast state and after heat treatment procedure containing annealing at 850, 885 and 920 ℃ followed by water quenching. Electrochemical impedance measurement results indicate that heat treatment of CuAlNi alloy leads to the increase in charge transfer resistance and surface layer resistance and the decrease in values of capacitance of the double and surface layers, indicating higher corrosion resistance compared with the as-cast CuAlNi alloy. The increase in polarisation resistance and the decrease in corrosion current density of heat-treated CuAlNi alloy also suggest beneficial influence of heat treatment on corrosion resistance of CuAlNi alloy. Optical microscopy, SEM/EDX and XRD analysis of samples surface after polarisation measurements show the occurrence of pitting corrosion on the electrode surfaces, with the existence of CuCl2, AlCl3 and Cu2Cl（OH）3 compounds as the surface corrosion products.

Quasi-Classical Trajectory Study on O＋＋DH（v=0,j=0）→OD＋＋H Reaction at Different Collision Energy

The quasi-classical trajectory calculations O＋＋DH（v=0,j=0）→OD＋＋H reactions on the RODRIGO potential energy surface have been carried out to study the isotope effect on stereo-dynamics at the collision energies of 1.0, 1.5, 2.0, and 2.5 eV. The distributions of dihedral angle P（~r） and the distributions of P（Or） are discussed. Furthermore, the angular distributions of the product rotational vectors in the form of polar plot in θr and φr are calculated. The differential cross section shows interesting phenomenon that the reaction is dominated by the direct reaction mechanism. Reaction probability and reaction cross section are also calculated. The calculations indicate that the stereo-dynamics properties of the title reactions are sensitive to the collision energy.

Interference Alignment in Two-Way Relay Networks via Rank Constraints Rank Minimization

Interference alignment(IA) is one of the promising measures for the multi-user network to manage interference. The rank constraints rank minimization means that interference spans the lowest dimensional subspace and the useful signal spans all available spatial dimensions. In order to improve the performance of two-way relay network, we can use rank constrained rank minimization(RCRM) to solve the IA problem. This paper proposes left reweighted nuclear norm minimization-γalgorithm and selective coupling reweighted nuclear norm minimization algorithm to implement interference alignment in two-way relay networks. The left reweighted nuclear norm minimization-γ algorithm is based on reweighted nuclear norm minimization algorithm and has a novel γ choosing rule. The selective coupling reweighted nuclear norm minimization algorithm weighting methods choose according to singular value of interference matrixes. Simulation results show that the proposed algorithms considerably improve the sum rate performance and achieve the higher average achievable multiplexing gain in two-way relay interference networks.

The Pole Placement of a Singular System with Delay

This paper deals with the pole placement of the singular system Ex=Ax（t）＋Dx（t-τ）＋Bu,y=yx,where x ∈ R^n, u ∈ R^m, and y ∈ R^n are its state, control input and measure output respectively; E, A ∈ R^n×n, B ∈ R^n×m, and C ∈ R^r×n are constant matrices. It is also assumed that rankE 〈 n. The results generalize the results of [1].

Influence of Integral Instability of Kramers-Kronig Transformation on Photoabsorption Cross Sections

The photoabsorption cross sections of condensed atoms and molecules have proven to be dependent not only on the imaginary parts but also on the real parts of the polarizabilities due to the strong interatomie interactions in condensed environment. The real parts of the polarizabilities calculated usually by using the famous Kramers-Kronig transformation （KKT） from the photoabsorption cross sections of the isolated atoms are very sensitive to the accuracy of the implementation method of the infinite integral in the KKT. The influence of the integral instability of the KKT and the real part of the polarizability on the variation of the photoabsorption cross sections with the number density and the structure of the condensed matter has been studied in the present work for the first time. The conclusion is that the integration method with interpolation has given more reasonable results than the direct truncation method if some appropriate interpolation functions have been used. Some notes and conclusions have also been given for the applications of the alternative coupled expressions of photoabsorption cross sections.

Optimization of pulsed current gas tungsten arc welding process parameters to attain maximum tensile strength in AZ31B magnesium alloy

An empirical relationship to predict tensile strength of pulsed current gas tungsten arc welded AZ31B magnesium alloy was developed. Incorporating process parameters such as peak current, base current, pulse frequency and pulse on time were studied. The experiments were conducted based on a four-factor, five-level, central composite design matrix. The developed empirical relationship can be effectively used to predict the tensile strength of pulsed current gas tungsten arc welded AZ31B magnesium alloy joints at 95% confidence level. The results indicate that pulse frequency has the greatest influence on tensile strength, followed by peak current, pulse on time and base current.

Preparation and application of perovskite-type oxides for electrocatalysis in oxygen/air electrodes

Recent advances in the preparation and application of perovskite-type oxides as bifunctional electrocatalysts for oxygen reaction and oxygen evolution reaction in rechargeable metal-air batteries are presented in this review.Various fabrication methods of these oxides are introduced in detail,and their advantages and disadvantages are analyzed.Different preparation methods adopted have great influence on the morphologies and physicochemical properties of perovskite-type oxides.As a bifunctional electrocatalyst,perovskite-type oxides are widely used in rechargeable metal-air batteries.The relationship between the preparation methods and the performances of oxygen/air electrodes are summarized.This work is concentrated on the structural stability,the phase compositions,and catalytic performance of perovskite-type oxides in oxygen/air electrodes.The main problems existing in the practical application of perovskite-type oxides as bifunctional electrocatalysts are pointed out and possible research directions in the future are recommended.

An Informational Approach to The Sinusoidal Law of Photon Polarization

The photon polarization law p(theta) = sin(2)theta is derived from a simple informational consideration by two methods: The first is via an intuitive principle of minimum Fisher information, the second is via a symmetry and invariance argument. The results demonstrate that in photon polarization, Nature has a tendency to hide herself as deep as possible while obeying some regular conditions.

Spin Transport in a Rashba Ring-Quantum Dot System Pumped by Microwave Fields

We report a theoretical study on producing electrically spin-polarized current in the Rashba ring with parallel double dots embedded, which are subject to two time-dependent microwave fields. By means of the Keldysh Green＇s function method, we present an analytic result of the pumped current at adiabatic limit and demonstrate that the interplay between the quantum pumping effect and spin-dependent quantum interference can lead to an arbitrarily controllable spin-polarized current in the device. The magnitude and direction of the charge and spin current can be effectively modulated by system parameters such as the pumping phase difference, Rashba precession phase, and the dynamic phase difference of electron traveling in two arms of ring; moreover, the spin-polarization degree of the charge current can also be tuned in the range [-∞, ＋∞]. Our findings may shed light on the all-electric way to produce the controllable spin-polarized charge current in the field of spintronics.

Aerosol Type Identification Using PARASOL Multichannel Polarized Data

PARASOL(Polarization & Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar) multi-channel and multi-directional polarized data for different aerosol types were compared.The PARASOL polarized radiance data at 490 nm,670 nm,and 865 nm increased with aerosol optical thickness(AOT) for fine-mode aerosols;however,the polarized radiances at 490 nm and 670 nm decreased as AOT increased for coarse dust aerosols.Thus,the variation of the polarized radiance with AOT can be used to identify fine or coarse particle-dominated aerosols.Polarized radiances at three wavelengths for fine-and coarse-mode aerosols were analyzed and fitted by linear regression.The slope of the line for 670 nm and 490 nm wavelength pairs is less than 0.35 for dust aerosols.However,the value for fine-mode aerosols is greater than 0.60.The Support Vector Machine method(SVM) based on 12 vector features was used to discriminate clear sky,coarse dust aerosols,fine-mode aerosols,and cloud.Two cases were given and validated by AErosol RObotic NETwork(AERONET) measurements,MODIS(Moderate Resolution Imaging Spectroradiometer) FMF(Fine Mode Fraction at 550 nm) images,PARASOL RGB(Red Green Blue) images,and CALIOP(Cloud-Aerosol Lidar with Orthogonal Polarization) VFM(Vertical Feature Mask) data.

Electrocatalytic Activity of Tungsten Carbide and Natural Zeolite Composite in Aqueous Solution

Tungsten carbide and zeolite nanocomposite was prepared by combining a mechanochemical approach with a reduction and carbonization approach,using natural zeolite and ammonia metatungstate as precursors.The sample was characterized by X-ray diffraction and scanning electron microscope.The results showed that the crystal phase of the sample is composed of zeolite,monotungsten carbide and bitungsten carbide.The mass percentage and the crystallite diameter of tungsten carbide change along with the reacted time.Its electrocatalytic activity was measured with a microelectrode system with three electrodes.The results show that its electrocatalytic property is related to its crystal phase and the mass percentage of tungsten carbide,and its electrocatalytic activity is connected with the property of electrolyte,in which it is measured.Synergistic effect between tungsten carbide and zeolite is found during electrocatalysis.

Effect of coal slurry on the corrosion of coal-mine equipment

The corrosion of coal mine equipment immersed in coal slurry is addressed. The corrosion of low carbon steel samples immersed in coal slurries of different concentrations （80, 130, and 180g/L） prepared from coals of different rank （long-flame coal, meager lean coal, and anthracite） and different granularity （0.25-0.5 ram, 0.074-0.25 mm, and less than 0.074 mm particle size） was studied by the electrochemical method of polarization curve measurement, controlled potential sweeping, and continuous scanning. The results show that the corrosion rate in an anthracite slurry, where the coal has high coalification, is far greater than corrosion in a long-flame or a meager lean coal slurry. Furthermore the corrosion current, polarization current, and corrosion rate of low carbon steel become larger, and the polarizability becomes smaller, as the coal particle size decreases. The same trend is seen as the concentration of the coal slurry increases.

Laccase biosensor using magnetic multiwalled carbon nanotubes and chitosan/silica hybrid membrane modified magnetic carbon paste electrode

A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were prepared by chemical coprecipitation method. Scanning electron microscope (SEM) and vibrating sample magnetometer (VSM) were used to identify its surfacetopography and magnetization, respectively. Laccase was immobilized on the MMCNT modified magnetic carbon paste electrode by the aid of chitosan/silica (CS) hybrid membrane. Using current-time detection method, the biosensor shows a linear response related to the concentration of catechol in the range from 10-7 to 0.165×10-3 mol/L. The corresponding detection limit is 3.34×10-8 mol/L based on signal-to-noise ratios (S/N) ≥3 under the optimized conditions. In addition, its response current retains 90% of the original after being stored for 45 d. The results indicate that this proposed strategy can be expected to develop other enzyme-based biosensors.

Dechlorination of zinc dross by microwave roasting

Traditional treatments of zinc dross have many disadvantages,such as complicated recovering process and serious environmental pollution.In this work,a new process of chlorine removal from zinc dross by microwave was proposed for solving problem of recycling the zinc dross.With better ability of absorbing the microwave than zinc oxide,the main material in zinc dross,chlorides,can be heated and evaporated rapidly during microwave roasting.Various parameters including roasting temperature,duration time and stirring speed were optimized.The microstructure of roasted materials was characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM).The content of the chloride was analyzed by the method of chlorine ion selective electrode.The experiments indicate that the best duration time is 60 min with a stirring speed of 15 r/min during the microwave roasting process.The dechlorination rate reaches peak value of 88% at 700 ℃.The chlorine is removed as HCl gas when water vapor is used as activating agent,which means that it can be recovered into hydrochloride acid.

Suppression to the cross-channel interference based on the short time Fourier transform

A new cross-channel interference suppression method is proposed to decrease the cross-channel interference in beat signals based on the short time Fourier transform （STY3＂） and the inverse short time Fourier transform （ISTFT） when the dual-orthogonal polarimetric frequency-modulated continu- ous wave （FMCW） radar adopts the opposite-slope linear frequency modulation signal pair in the simultaneous measurement mode. The STFT is applied only on the signals in the cross-interference intervals in the four polarimetric channels to decrease the computation complexity. A mask matrix for suppressing the interference is constructed using the constant false alarm ratio （CFAR） detection on the spectrograms by the STFY. The simulative results show that the cross-channel interference is effi- ciently suppressed by the proposed method. The comparison between the proposed method and the rejection method verifies the improved performance of the proposed method.

A lightweight carbon nanofiber-based 3D structured matrix with high nitrogen-doping level for lithium metal anodes

Lithium metal is considered to be the most promising anode material for the next-generation rechargeable batteries. However, the uniform and dendrite-free deposition of Li metal anode is hard to achieve, hindering its practical applications. Herein, a lightweight, free-standing and nitrogen-doped carbon nanofiber-based 3D structured conductive matrix(NCNF), which is characterized by a robust and interconnected 3D network with high doping level of 9.5 at%, is prepared by electrospinning as the current collector for Li metal anode. Uniform Li nucleation with reduced polarization and dendrite-free Li deposition are achieved because the NCNF with high nitrogen-doping level and high conductivity provide abundant and homogenous metallic Li nucleation and deposition sites. Excellent cycling stability with high coulombic efficiency are realized. The Li plated NCNF was paired with LiFePO4 to assemble the full battery, also showing high cyclic stability.

Localized States of an Excess Electron in an Ionic Cluster

A theory of an electron affinity for an ionic cluster is proposed both in a quasiclassical approach and with quantization of a polarization electric field in a nanopartiele. A critical size of the cluster regarding in formation of an electron＇s autolocalized state, dependencies of energy and radius of a polaron on a cluster＇s size are obtained by a variational method. It has been found that binding energy of the electron in the cluster depends on a eluster＇s radius but a radius of electron＇s auto-localization does not depend on the cluster＇s radius and it equals to the polaron radius in a corresponding infinity crystal. A bound state of the electron in a cluster is possible only if the duster＇s radius is more than the polaron radius.