The formation kinetics and mechanism of tricalcium aluminate hydrate and calcium oxalate in dilute sodium aluminate solution and sodium oxalate solution were studied respectively based on the lime causticization, and ...The formation kinetics and mechanism of tricalcium aluminate hydrate and calcium oxalate in dilute sodium aluminate solution and sodium oxalate solution were studied respectively based on the lime causticization, and the optimal conditions for removing the oxalate in dilute sodium aluminate solution as well as the mechanism were finally obtained.The formation processes of tricalcium aluminate hydrate and calcium oxalate are mainly controlled by the chemical reaction and the inner diffusion respectively,and the corresponding reaction rate equations as well as the apparent activation energy were calculated. The hydrocalumite with a spatially interleaved structure will form in dilute sodium aluminate solution with sodium oxalate, greatly removing the oxalate impurity by absorption. Calcium oxalate can be converted to tricalcium aluminate hydrate with the increasing reaction time. The oxalate causticization efficiency and the alumina loss rate can be over 90% and below 31% respectively when reacted at 50℃ with a stirring rate of 200 r/min.展开更多
Flotation tests, contact angle measurements, infrared spectrum analyses, X-ray analyses and computer simulation were carried out in order to study the activation mechanism of lime-depressed pyrite with oxalic acid. Th...Flotation tests, contact angle measurements, infrared spectrum analyses, X-ray analyses and computer simulation were carried out in order to study the activation mechanism of lime-depressed pyrite with oxalic acid. The results show that the oxalic acid effectively eliminated the hydrophilic calcium film from the surface of pyrite. Therefore, the efficiency of pyrite flotation was also activated. The results indicate that after reacting with hydrophobic insoluble remainders on the surface of pyrite, oxalic acid can pro- duce hydrophilic compounds, such as CaC03, Ca(OH)2 and Fe(OH)3. As a consequence, a flesh pyrite layer was exposed and its flotation activated.展开更多
Shrub-grass vegetation was established on the rocky slope of Longhui-Dongkou Section of Shaohuai Expressway (Shaoyang to Huaihua) by following the below procedures: ① According to regional climatic characteristics, g...Shrub-grass vegetation was established on the rocky slope of Longhui-Dongkou Section of Shaohuai Expressway (Shaoyang to Huaihua) by following the below procedures: ① According to regional climatic characteristics, grasses like Cynodon dactylon, Papalum natatum and Sorghum bicolor (L.) Moench can be applied as pioneering species, local shrubs with drought, cold and infertility resistance like Nerium ndicum Mill., Amorpha fruticosa, Pyracantha fortuneana, and Mycoplasma organism as constructive species, local arbors like Robinia pseudoacacia and Albizia kalkora as accompanying species; ② Slope should be treated first before the establishment of shrub-grass vegetation, then anchored, and covered with nets after the mortar solidified and hardened; after the base materials spraying which includes both substrate spraying and surface spraying, the slope should be promptly covered with non-woven fabrics. The results showed that green coverage ratio of shrub-grass vegetation achieved 90% or above, all quality indexes met the expected standards, which implied that the establishment of shrub-grass vegetation is a rapid and effective way for the vegetation restoration of rocky slopes along expressways, and worth of being promoted in similar climatic zones.展开更多
The first humans (hominids) appeared at about the same geological time in three independent areas: in East Africa, southern Indochina and in the Kazakh steppe. People inhabiting all continents and countries around ...The first humans (hominids) appeared at about the same geological time in three independent areas: in East Africa, southern Indochina and in the Kazakh steppe. People inhabiting all continents and countries around the world descended from hominids that emerged in these three foci then resided elsewhere. The number of people emerged 2-3 million years ago now about 7.0 billion people. They inhabit the planet and the master space. Kazakh steppe, located in the middle of the Eurasian continent, has always had a positive impact on neighboring countries. According to historical geological data obtained in the south near the ridge Karatau, the first people emerged on the territory of Kazakhstan were found about 2 million years ago. Such a conclusion was made on the basis of residual cultural pebble tools of hominids, founded by scientists. As a result of geological survey work carried out in the 1960's there were found some primitive people, starting with the era of"Arystandy culture" and including the Late Paleolithic era in the area of ridges Big and Small Karatau. There had been found the fossil remains of large mammals hunted by hominids around the sites of ancient people. Thanks for these residues the corresponding time of residence of primitive people can be judged from the animal world of the Kazakh steppe.展开更多
基金Project(2018YFC1901903)supported by the National Key R&D Program of ChinaProjects(51774079,51674075)supported by the National Natural Science Foundation of ChinaProject(N182508026)supported by the Fundamental Research Funds for the Central Universities,China
文摘The formation kinetics and mechanism of tricalcium aluminate hydrate and calcium oxalate in dilute sodium aluminate solution and sodium oxalate solution were studied respectively based on the lime causticization, and the optimal conditions for removing the oxalate in dilute sodium aluminate solution as well as the mechanism were finally obtained.The formation processes of tricalcium aluminate hydrate and calcium oxalate are mainly controlled by the chemical reaction and the inner diffusion respectively,and the corresponding reaction rate equations as well as the apparent activation energy were calculated. The hydrocalumite with a spatially interleaved structure will form in dilute sodium aluminate solution with sodium oxalate, greatly removing the oxalate impurity by absorption. Calcium oxalate can be converted to tricalcium aluminate hydrate with the increasing reaction time. The oxalate causticization efficiency and the alumina loss rate can be over 90% and below 31% respectively when reacted at 50℃ with a stirring rate of 200 r/min.
基金the financial support from the Key Projects in the National Science & Technology Pillar Program for the Eleventh Five-Year Plan (No. 2006BAB02A06)
文摘Flotation tests, contact angle measurements, infrared spectrum analyses, X-ray analyses and computer simulation were carried out in order to study the activation mechanism of lime-depressed pyrite with oxalic acid. The results show that the oxalic acid effectively eliminated the hydrophilic calcium film from the surface of pyrite. Therefore, the efficiency of pyrite flotation was also activated. The results indicate that after reacting with hydrophobic insoluble remainders on the surface of pyrite, oxalic acid can pro- duce hydrophilic compounds, such as CaC03, Ca(OH)2 and Fe(OH)3. As a consequence, a flesh pyrite layer was exposed and its flotation activated.
基金Supported by 948 Key Projects of State Forestry Administration (2008-4-32)~~
文摘Shrub-grass vegetation was established on the rocky slope of Longhui-Dongkou Section of Shaohuai Expressway (Shaoyang to Huaihua) by following the below procedures: ① According to regional climatic characteristics, grasses like Cynodon dactylon, Papalum natatum and Sorghum bicolor (L.) Moench can be applied as pioneering species, local shrubs with drought, cold and infertility resistance like Nerium ndicum Mill., Amorpha fruticosa, Pyracantha fortuneana, and Mycoplasma organism as constructive species, local arbors like Robinia pseudoacacia and Albizia kalkora as accompanying species; ② Slope should be treated first before the establishment of shrub-grass vegetation, then anchored, and covered with nets after the mortar solidified and hardened; after the base materials spraying which includes both substrate spraying and surface spraying, the slope should be promptly covered with non-woven fabrics. The results showed that green coverage ratio of shrub-grass vegetation achieved 90% or above, all quality indexes met the expected standards, which implied that the establishment of shrub-grass vegetation is a rapid and effective way for the vegetation restoration of rocky slopes along expressways, and worth of being promoted in similar climatic zones.
文摘The first humans (hominids) appeared at about the same geological time in three independent areas: in East Africa, southern Indochina and in the Kazakh steppe. People inhabiting all continents and countries around the world descended from hominids that emerged in these three foci then resided elsewhere. The number of people emerged 2-3 million years ago now about 7.0 billion people. They inhabit the planet and the master space. Kazakh steppe, located in the middle of the Eurasian continent, has always had a positive impact on neighboring countries. According to historical geological data obtained in the south near the ridge Karatau, the first people emerged on the territory of Kazakhstan were found about 2 million years ago. Such a conclusion was made on the basis of residual cultural pebble tools of hominids, founded by scientists. As a result of geological survey work carried out in the 1960's there were found some primitive people, starting with the era of"Arystandy culture" and including the Late Paleolithic era in the area of ridges Big and Small Karatau. There had been found the fossil remains of large mammals hunted by hominids around the sites of ancient people. Thanks for these residues the corresponding time of residence of primitive people can be judged from the animal world of the Kazakh steppe.