This paper presents a new improved term frequency/inverse document frequency (TF-IDF) approach which uses confidence, support and characteristic words to enhance the recall and precision of text classification. Synony...This paper presents a new improved term frequency/inverse document frequency (TF-IDF) approach which uses confidence, support and characteristic words to enhance the recall and precision of text classification. Synonyms defined by a lexicon are processed in the improved TF-IDF approach. We detailedly discuss and analyze the relationship among confidence, recall and precision. The experiments based on science and technology gave promising results that the new TF-IDF approach improves the precision and recall of text classification compared with the conventional TF-IDF approach.展开更多
Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rank...Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.展开更多
Fine particles are difficult to fluidize due to strong interparticle attraction.An attempt has been made to study the bed expansion of silica gel(dp=25μm) powder in presence of an acoustic field.A 135 mm diameter flu...Fine particles are difficult to fluidize due to strong interparticle attraction.An attempt has been made to study the bed expansion of silica gel(dp=25μm) powder in presence of an acoustic field.A 135 mm diameter fluidized bed activated by an acoustic field with sound intensity up to 145 dB and frequency from 90 Hz to 170 Hz was studied.The effects of sound pressure level,sound frequency and particle loading on the bed expansion were investigated.Experimental results showed that,bed expansion was good in presence of acoustic field of particular frequency.In addition,it was observed that in presence of acoustic field the bed collapses slowly.展开更多
In recent years, with the constant change in the global climate, the effect of climate factors on net primary productivity(NPP) has become a hot research topic. However, two opposing views have been presented in this ...In recent years, with the constant change in the global climate, the effect of climate factors on net primary productivity(NPP) has become a hot research topic. However, two opposing views have been presented in this research area: global NPP increases with global warming, and global NPP decreases with global warming. The main reasons for these two opposite results are the tremendous differences among seasonal and annual climate variables, and the growth of plants in accordance with these climate variables. Therefore, it will fail to fully clarify the relation between vegetation growth and climate changes by research that relies solely on annual data. With seasonal climate variables, we may clarify the relation between vegetation growth and climate changes more accurately. Our research examined the arid and semiarid areas in China(ASAC), which account for one quarter of the total area of China. The ecological environment of these areas is fragile and easily affected by human activities. We analyzed the influence of climate changes, especially the changes in seasonal climate variables, on NPP, with Climatic Research Unit(CRU) climatic data and Moderate Resolution Imaging Spectroradiometer(MODIS) satellite remote data, for the years 2000–2010. The results indicate that: for annual climatic data, the percentage of the ASAC in which NPP is positively correlated with temperature is 66.11%, and 91.47% of the ASAC demonstrates a positive correlation between NPP and precipitation. Precipitation is more positively correlated with NPP than temperature in the ASAC. For seasonal climatic data, the correlation between NPP and spring temperature shows significant regional differences. Positive correlation areas are concentrated in the eastern portion of the ASAC, while the western section of the ASAC generally shows a negative correlation. However, in summer, most areas in the ASAC show a negative correlation between NPP and temperature. In autumn, precipitation is less important in the west, as opposed to the east, in which it is critically important. Temperatures in winter are a limiting factor for NPP throughout the region. The findings of this research not only underline the importance of seasonal climate variables for vegetation growth, but also suggest that the effects of seasonal climate variables on NPP should be explored further in related research in the future.展开更多
The complex spatiotemporal vegetation variability in the subtropical mountain-hill region was investigated through a multi-level modeling framework. Three levels - parcel, landscape, and river basin levels- were selec...The complex spatiotemporal vegetation variability in the subtropical mountain-hill region was investigated through a multi-level modeling framework. Three levels - parcel, landscape, and river basin levels- were selected to discover the complex spatiotemporal vegetation variability induced by climatic, geomorphic and anthropogenic processes at different levels. The wavelet transform method was adopted to construct the annual maximum Enhanced Vegetation Index and the amplitude of the annual phenological cycle based on the 16-day time series of a5om Moderate Resolution Imaging Spectroradiometer Enhanced Vegetation Index datasets during 2OOl-2OlO. Results revealed that land use strongly influenced the overall vegetation greenness and magnitude of phenological cycles. Topographic variables also contributed considerably to the models, reflecting the positive influence from altitude and slope. Additionally, climate factors played an important role: precipitation had a considerable positive association with the vegetation greenness, whereas the temperature difference had strong positive influence on the magnitude of vegetation phenology. The multilevel approach leads to a better understanding of the complex interaction of the hierarchical ecosystem, human activities and climate change.展开更多
Based on constructal theory,the constructs of three "volume-point" heat conduction models with three-dimensional cylindrical element and rectangular and triangular elements on microscale and nanoscale are op...Based on constructal theory,the constructs of three "volume-point" heat conduction models with three-dimensional cylindrical element and rectangular and triangular elements on microscale and nanoscale are optimized by taking minimum entransy dissipation rate as optimization objective.The optimal constructs of the three "volume-point" heat conduction models with minimum dimensionless equivalent thermal resistance are obtained.The results show that the optimal constructs of the three-dimensional cylindrical assembly based on the minimizations of dimensionless equivalent thermal resistance and dimensionless maximum thermal resistance are different,which is obviously different from the comparison between those of the corresponding two-dimensional rectangular assembly based on the minimizations of these two objectives.The optimal constructs based on rectangular and triangular elements on microscale and nanoscale when the size effect takes effect are obviously different from those when the size effect does not take effect.Because the thermal current density in the high conductivity channel of the rectangular and triangular second order assemblies are not linear with the length,the optimal constructs of these assemblies based on the minimization of entransy dissipation rate are different from those based on the minimization of maximum temperature difference.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the construct.The studies on "volume-point" heat conduction constructal problems at three-dimensional conditions and microscale and nanoscale by taking minimum entransy dissipation rate as optimization objective extend the application range of the entransy dissipation extremum principle.展开更多
Proton exchange membrane fuel cells(PEMFCs)suffer extreme CO poisoning even at PPM level(<10 ppm),owning to the preferential CO adsorption and the consequential blockage of the catalyst surface.Herein,however,we re...Proton exchange membrane fuel cells(PEMFCs)suffer extreme CO poisoning even at PPM level(<10 ppm),owning to the preferential CO adsorption and the consequential blockage of the catalyst surface.Herein,however,we report that CO itself can become an easily convertible fuel in PEMFC using atomically dispersed Rh catalysts(Rh-N-C).With CO to CO_(2) conversion initiates at 0 V,pure CO powered fuel cell attains unprecedented power density at 236 mW cm^(-2),with maximum CO turnover frequency(64.65 s^(-1),363 K)far exceeding any chemical or electrochemical catalysts reported.Moreover,this feature enables efficient CO selective removal from H_(2) gas stream through the PEMFC technique,with CO concentration reduced by one order of magnitude through running only one single cell,while simultaneously harvesting electricity.We attribute such catalytic behavior to the weak CO adsorption and the co-activation of H_(2)O due to the interplay between two adjacent Rh sites.展开更多
According to the requirements of a solar dish-Brayton system,a centrifugal compressor stage with a minimum total pressure ratio of 5,an adiabatic efficiency above 75% and a surge margin more than 12% needs to be desig...According to the requirements of a solar dish-Brayton system,a centrifugal compressor stage with a minimum total pressure ratio of 5,an adiabatic efficiency above 75% and a surge margin more than 12% needs to be designed.A single stage,which consists of impeller,radial vaned diffuser,90° crossover and two rows of axial stators,was chosen to satisfy this system.To achieve the stage performance,an impeller with a 6:1 total pressure ratio and an adiabatic efficiency of 90% was designed and its preliminary geometry came from an in-house one-dimensional program.Radial vaned diffuser was applied downstream of the impeller.Two rows of axial stators after 90° crossover were added to guide the flow into axial direction.Since jet-wake flow,shockwave and boundary layer separation coexisted in the impeller-diffuser region,optimization on the radius ratio of radial diffuser vane inlet to impeller exit,diffuser vane inlet blade angle and number of diffuser vanes was carried out at design point.Finally,an optimized centrifugal compressor stage fulfilled the high expectations and presented proper performance.Numerical simulation showed that at design point the stage adiabatic efficiency was 79.93% and the total pressure ratio was 5.6.The surge margin was 15%.The performance map including 80%,90% and 100% design speed was also presented.展开更多
A controllable mechanical turbo-compounding(CMTC) system including continuously variable transmission(CVT) and power turbine bypass valve is proposed to recover waste heat from engine exhaust. The combined matching pr...A controllable mechanical turbo-compounding(CMTC) system including continuously variable transmission(CVT) and power turbine bypass valve is proposed to recover waste heat from engine exhaust. The combined matching principle considering swallowing capacity of both charging turbine and power turbine, main gear ratio is investigated at first based on the analysis of individual influence. Then the effects and strategies of CVT and power turbine bypass valve are studied for better performance under off-design conditions. At last, the transient response of intake pressure of engine with CMTC system is researched and the fuel saving potential is tested under driving cycle conditions. The results indicate that the overall fuel efficiency elevates at the off-design conditions if CVT is adopted due to the improvement of power turbine operating efficiency by speed modulation. The diversion of exhaust through power turbine bypass valve under the low load condition is necessary. The back pressure of the charging turbine infuences the transient response of intake pressure for a fixed CMTC configuration. A method featured by the assistance of power turbine bypass valve is tested to improve the transient response of the intake pressure. The fuel consumption reduces by 2% and 3.4% under highway fuel economy test(HWFET) and Tianjin 503(TJ503) driving cycles respectively.展开更多
The inlet attack angle of rotor blade reasonably can be adjusted with the change of the stagger angle of inlet guide vane (IGV); so the efficiency of each condition will be affected. For the purpose to improve the eff...The inlet attack angle of rotor blade reasonably can be adjusted with the change of the stagger angle of inlet guide vane (IGV); so the efficiency of each condition will be affected. For the purpose to improve the efficiency, the DSP (Digital Signal Processor) controller is designed to adjust the stagger angle of IGV automatically in order to optimize the efficiency at any operating condition. The A/D signal collection includes inlet static pressure, outlet static pressure, outlet total pressure, rotor speed and torque signal, the efficiency can be calculated in the DSP, and the angle signal for the stepping motor which control the IGV will be sent out from the D/A. Experimental investigations are performed in a three-stage, low-speed axial compressor with variable inlet guide vanes. It is demonstrated that the DSP designed can well adjust the stagger angle of IGV online, the efficiency under different conditions can be optimized. This establishment of DSP online adjustment scheme may provide a practical solution for improving performance of multi-stage axial flow compressor when its operating condition is varied.展开更多
The charging kinetics of electric double layers (EDLs) is closely related to the performance of a wide variety of nanostructured devices including supercapacitors, electro-actuators, and electrolyte-gated transistor...The charging kinetics of electric double layers (EDLs) is closely related to the performance of a wide variety of nanostructured devices including supercapacitors, electro-actuators, and electrolyte-gated transistors. While room temperature ionic liquids (RTIL) are often used as the charge carrier in these new applications, the theoretical analyses are mostly based on conventional electrokinetic theories suitable for macroscopic electrochemical phenomena in aqueous solutions. In this work, we study the charging behavior of RTIL-EDLs using a coarse-grained molecular model and constant-potential molecular dynamics (MD) simulations. In stark contrast to the predictions of conventional theories, the MD results show oscillatory variations of ionic distributions and electrochemical properties in response to the separation between electrodes. The rate of EDL charging exhibits non-monotonic behavior revealing strong electrostatic correlations in RTIL under confinement.展开更多
A new kind of photoactive electrodes with nanocrystalline TiO2(nano-TiO2)secondary structure is successfully prepared via a simple method of adding a small amount of TiCl4 2-propanol solution in conventional nano-TiO2...A new kind of photoactive electrodes with nanocrystalline TiO2(nano-TiO2)secondary structure is successfully prepared via a simple method of adding a small amount of TiCl4 2-propanol solution in conventional nano-TiO2 paste to form micro-sized nano-TiO2 aggregates.The benefits of this special structure include improved optical absorption,increased light scattering ability,and enhanced electron transport and collection efficiency.Dye-sensitized solar cells(DSCs)based on these photoactive electrodes show improved performance.The power conversion efficiency of the cells can be increased from 5.03%to 7.30%by substituting 6μm conventional nano-TiO2 thin film with the same thickness of as-prepared nano-TiO2 aggregates film in the photoactive electrodes.A higher power conversion efficiency of the cells can be obtained by further increasing the thickness of the nano-TiO2 aggregates film.展开更多
基金Project (No. 60082003) supported by the National Natural Science Foundation of China
文摘This paper presents a new improved term frequency/inverse document frequency (TF-IDF) approach which uses confidence, support and characteristic words to enhance the recall and precision of text classification. Synonyms defined by a lexicon are processed in the improved TF-IDF approach. We detailedly discuss and analyze the relationship among confidence, recall and precision. The experiments based on science and technology gave promising results that the new TF-IDF approach improves the precision and recall of text classification compared with the conventional TF-IDF approach.
基金Project(2009Gk2009)supported by the Science and Technology Department Funds of Hunan Province,ChinaProject(12C0379)supported by the Scientific Research Fund of Hunan Province,ChinaProject(13QDZ04)supported by the Scientific Research Foundation for Doctors of Xiang Tan University,China
文摘Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.
文摘Fine particles are difficult to fluidize due to strong interparticle attraction.An attempt has been made to study the bed expansion of silica gel(dp=25μm) powder in presence of an acoustic field.A 135 mm diameter fluidized bed activated by an acoustic field with sound intensity up to 145 dB and frequency from 90 Hz to 170 Hz was studied.The effects of sound pressure level,sound frequency and particle loading on the bed expansion were investigated.Experimental results showed that,bed expansion was good in presence of acoustic field of particular frequency.In addition,it was observed that in presence of acoustic field the bed collapses slowly.
基金the Strategic Priority Research Program-Climate Change:Carbon Budget and Relevant Issues of Chinese Academy of Sciences(No.XDA05060104)
文摘In recent years, with the constant change in the global climate, the effect of climate factors on net primary productivity(NPP) has become a hot research topic. However, two opposing views have been presented in this research area: global NPP increases with global warming, and global NPP decreases with global warming. The main reasons for these two opposite results are the tremendous differences among seasonal and annual climate variables, and the growth of plants in accordance with these climate variables. Therefore, it will fail to fully clarify the relation between vegetation growth and climate changes by research that relies solely on annual data. With seasonal climate variables, we may clarify the relation between vegetation growth and climate changes more accurately. Our research examined the arid and semiarid areas in China(ASAC), which account for one quarter of the total area of China. The ecological environment of these areas is fragile and easily affected by human activities. We analyzed the influence of climate changes, especially the changes in seasonal climate variables, on NPP, with Climatic Research Unit(CRU) climatic data and Moderate Resolution Imaging Spectroradiometer(MODIS) satellite remote data, for the years 2000–2010. The results indicate that: for annual climatic data, the percentage of the ASAC in which NPP is positively correlated with temperature is 66.11%, and 91.47% of the ASAC demonstrates a positive correlation between NPP and precipitation. Precipitation is more positively correlated with NPP than temperature in the ASAC. For seasonal climatic data, the correlation between NPP and spring temperature shows significant regional differences. Positive correlation areas are concentrated in the eastern portion of the ASAC, while the western section of the ASAC generally shows a negative correlation. However, in summer, most areas in the ASAC show a negative correlation between NPP and temperature. In autumn, precipitation is less important in the west, as opposed to the east, in which it is critically important. Temperatures in winter are a limiting factor for NPP throughout the region. The findings of this research not only underline the importance of seasonal climate variables for vegetation growth, but also suggest that the effects of seasonal climate variables on NPP should be explored further in related research in the future.
基金supported by the National Natural Science Foundation of China (NSFC) (Grant No. 41071267)Scientific Research Foundation for Returned Scholars ([2012]940)Ministry of Education of China, and the Science Foundation of Fujian Province (Grant Nos. 2012I0005, 2012J01167)
文摘The complex spatiotemporal vegetation variability in the subtropical mountain-hill region was investigated through a multi-level modeling framework. Three levels - parcel, landscape, and river basin levels- were selected to discover the complex spatiotemporal vegetation variability induced by climatic, geomorphic and anthropogenic processes at different levels. The wavelet transform method was adopted to construct the annual maximum Enhanced Vegetation Index and the amplitude of the annual phenological cycle based on the 16-day time series of a5om Moderate Resolution Imaging Spectroradiometer Enhanced Vegetation Index datasets during 2OOl-2OlO. Results revealed that land use strongly influenced the overall vegetation greenness and magnitude of phenological cycles. Topographic variables also contributed considerably to the models, reflecting the positive influence from altitude and slope. Additionally, climate factors played an important role: precipitation had a considerable positive association with the vegetation greenness, whereas the temperature difference had strong positive influence on the magnitude of vegetation phenology. The multilevel approach leads to a better understanding of the complex interaction of the hierarchical ecosystem, human activities and climate change.
基金supported by the National Natural Science Foundation of China (Grant No. 51176203)the Natural Science Foundation of Naval University of Engineering (Grant No. HGDYDJJ10011)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ10017)
文摘Based on constructal theory,the constructs of three "volume-point" heat conduction models with three-dimensional cylindrical element and rectangular and triangular elements on microscale and nanoscale are optimized by taking minimum entransy dissipation rate as optimization objective.The optimal constructs of the three "volume-point" heat conduction models with minimum dimensionless equivalent thermal resistance are obtained.The results show that the optimal constructs of the three-dimensional cylindrical assembly based on the minimizations of dimensionless equivalent thermal resistance and dimensionless maximum thermal resistance are different,which is obviously different from the comparison between those of the corresponding two-dimensional rectangular assembly based on the minimizations of these two objectives.The optimal constructs based on rectangular and triangular elements on microscale and nanoscale when the size effect takes effect are obviously different from those when the size effect does not take effect.Because the thermal current density in the high conductivity channel of the rectangular and triangular second order assemblies are not linear with the length,the optimal constructs of these assemblies based on the minimization of entransy dissipation rate are different from those based on the minimization of maximum temperature difference.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the construct.The studies on "volume-point" heat conduction constructal problems at three-dimensional conditions and microscale and nanoscale by taking minimum entransy dissipation rate as optimization objective extend the application range of the entransy dissipation extremum principle.
基金supported by the National Key Research and Development Program of China (2017YFB0102900)the National Natural Science Foundation of China (21875243, 21633008, 21673221, and U1601211)+3 种基金Jilin Provincial Science and Technology Development Program (20200201001JC, 20190201270JC, and 20180101030JC)supported by the High Performance Computing Center of Jilin University and Jilin ProvinceNetwork and Computing Center of Changchun Institute of Applied Chemistry, Chinese Academy of Sciencessupported by Linglu Instruments (Shanghai) Co., Ltd.
文摘Proton exchange membrane fuel cells(PEMFCs)suffer extreme CO poisoning even at PPM level(<10 ppm),owning to the preferential CO adsorption and the consequential blockage of the catalyst surface.Herein,however,we report that CO itself can become an easily convertible fuel in PEMFC using atomically dispersed Rh catalysts(Rh-N-C).With CO to CO_(2) conversion initiates at 0 V,pure CO powered fuel cell attains unprecedented power density at 236 mW cm^(-2),with maximum CO turnover frequency(64.65 s^(-1),363 K)far exceeding any chemical or electrochemical catalysts reported.Moreover,this feature enables efficient CO selective removal from H_(2) gas stream through the PEMFC technique,with CO concentration reduced by one order of magnitude through running only one single cell,while simultaneously harvesting electricity.We attribute such catalytic behavior to the weak CO adsorption and the co-activation of H_(2)O due to the interplay between two adjacent Rh sites.
基金supported by the National Natural Science Foundation of China(Grant No.51010007)China Scholarship Council(CSC)
文摘According to the requirements of a solar dish-Brayton system,a centrifugal compressor stage with a minimum total pressure ratio of 5,an adiabatic efficiency above 75% and a surge margin more than 12% needs to be designed.A single stage,which consists of impeller,radial vaned diffuser,90° crossover and two rows of axial stators,was chosen to satisfy this system.To achieve the stage performance,an impeller with a 6:1 total pressure ratio and an adiabatic efficiency of 90% was designed and its preliminary geometry came from an in-house one-dimensional program.Radial vaned diffuser was applied downstream of the impeller.Two rows of axial stators after 90° crossover were added to guide the flow into axial direction.Since jet-wake flow,shockwave and boundary layer separation coexisted in the impeller-diffuser region,optimization on the radius ratio of radial diffuser vane inlet to impeller exit,diffuser vane inlet blade angle and number of diffuser vanes was carried out at design point.Finally,an optimized centrifugal compressor stage fulfilled the high expectations and presented proper performance.Numerical simulation showed that at design point the stage adiabatic efficiency was 79.93% and the total pressure ratio was 5.6.The surge margin was 15%.The performance map including 80%,90% and 100% design speed was also presented.
基金supported by the National Basic Research Program of China(Grant No.2011CB707206)
文摘A controllable mechanical turbo-compounding(CMTC) system including continuously variable transmission(CVT) and power turbine bypass valve is proposed to recover waste heat from engine exhaust. The combined matching principle considering swallowing capacity of both charging turbine and power turbine, main gear ratio is investigated at first based on the analysis of individual influence. Then the effects and strategies of CVT and power turbine bypass valve are studied for better performance under off-design conditions. At last, the transient response of intake pressure of engine with CMTC system is researched and the fuel saving potential is tested under driving cycle conditions. The results indicate that the overall fuel efficiency elevates at the off-design conditions if CVT is adopted due to the improvement of power turbine operating efficiency by speed modulation. The diversion of exhaust through power turbine bypass valve under the low load condition is necessary. The back pressure of the charging turbine infuences the transient response of intake pressure for a fixed CMTC configuration. A method featured by the assistance of power turbine bypass valve is tested to improve the transient response of the intake pressure. The fuel consumption reduces by 2% and 3.4% under highway fuel economy test(HWFET) and Tianjin 503(TJ503) driving cycles respectively.
基金supported by National Basic Research Program of China 2007CB210104National Natural Science Foundation of China with projects No.51010007.and No.50736007
文摘The inlet attack angle of rotor blade reasonably can be adjusted with the change of the stagger angle of inlet guide vane (IGV); so the efficiency of each condition will be affected. For the purpose to improve the efficiency, the DSP (Digital Signal Processor) controller is designed to adjust the stagger angle of IGV automatically in order to optimize the efficiency at any operating condition. The A/D signal collection includes inlet static pressure, outlet static pressure, outlet total pressure, rotor speed and torque signal, the efficiency can be calculated in the DSP, and the angle signal for the stepping motor which control the IGV will be sent out from the D/A. Experimental investigations are performed in a three-stage, low-speed axial compressor with variable inlet guide vanes. It is demonstrated that the DSP designed can well adjust the stagger angle of IGV online, the efficiency under different conditions can be optimized. This establishment of DSP online adjustment scheme may provide a practical solution for improving performance of multi-stage axial flow compressor when its operating condition is varied.
基金This work was supported as part of the Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center funded by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences. K. X. is grateful to the Chinese Scholarship Council for a visiting fellowship. Additional support was provided by National Natural Science foundation of China (No. 21276138) and Tsinghua University Foundation (No. 2013108930). The numerical calculations were performed at the National Energy Research Sdentific Computing Center (NERSC).
文摘The charging kinetics of electric double layers (EDLs) is closely related to the performance of a wide variety of nanostructured devices including supercapacitors, electro-actuators, and electrolyte-gated transistors. While room temperature ionic liquids (RTIL) are often used as the charge carrier in these new applications, the theoretical analyses are mostly based on conventional electrokinetic theories suitable for macroscopic electrochemical phenomena in aqueous solutions. In this work, we study the charging behavior of RTIL-EDLs using a coarse-grained molecular model and constant-potential molecular dynamics (MD) simulations. In stark contrast to the predictions of conventional theories, the MD results show oscillatory variations of ionic distributions and electrochemical properties in response to the separation between electrodes. The rate of EDL charging exhibits non-monotonic behavior revealing strong electrostatic correlations in RTIL under confinement.
基金supported by the National Natural Science Foundation of China (U1205112,51002053)the Key Project of the Chinese Ministry of Education (212206)+1 种基金the Programs for Prominent Young Talents and New Century Excellent Talents in Fujian Province Universitythe Promotion Program for Yong and Middle-aged Teacher in Science and Technology Research of Huaqiao University (ZQN- YX102)
文摘A new kind of photoactive electrodes with nanocrystalline TiO2(nano-TiO2)secondary structure is successfully prepared via a simple method of adding a small amount of TiCl4 2-propanol solution in conventional nano-TiO2 paste to form micro-sized nano-TiO2 aggregates.The benefits of this special structure include improved optical absorption,increased light scattering ability,and enhanced electron transport and collection efficiency.Dye-sensitized solar cells(DSCs)based on these photoactive electrodes show improved performance.The power conversion efficiency of the cells can be increased from 5.03%to 7.30%by substituting 6μm conventional nano-TiO2 thin film with the same thickness of as-prepared nano-TiO2 aggregates film in the photoactive electrodes.A higher power conversion efficiency of the cells can be obtained by further increasing the thickness of the nano-TiO2 aggregates film.