From the perspective of biomechanics and forming technology,Ti−Fe−Zr−Sn−Y eutectic alloy was designed using a“cluster-plus-glue-atom”model,and then the alloy was prepared by laser additive manufacturing(LAM)on pure ...From the perspective of biomechanics and forming technology,Ti−Fe−Zr−Sn−Y eutectic alloy was designed using a“cluster-plus-glue-atom”model,and then the alloy was prepared by laser additive manufacturing(LAM)on pure titanium substrate.The mechanical properties of the alloy were evaluated using micro-hardness and compression tester,and the elastic modulus was measured by nanoindenter.The results show that the alloy exhibits a high hardness of HV(788±10),a high strength of 2229 MPa,a failure strain of 14%,and a low elastic modulus of 87.5 GPa.The alloy also has good tribological,chemical,forming,and biological properties.The comprehensive performances of the Ti64.51Fe26.40Zr5.86Sn2.93Y0.30 alloy are superior to those of the Ti70.5Fe29.5 eutectic alloy and commercial Ti−6Al−4V alloy.All the above-mentioned qualities make the alloy a promising candidate as LAM biomaterial.展开更多
The influence of thermo-mechanical processing (TMP) on the microstructure and the electrochemical behavior of new metastableβ alloy Ti?20.6Nb?13.6Zr?0.5V (TNZV) was investigated. The TMP included hot working in below...The influence of thermo-mechanical processing (TMP) on the microstructure and the electrochemical behavior of new metastableβ alloy Ti?20.6Nb?13.6Zr?0.5V (TNZV) was investigated. The TMP included hot working in belowβ transus, solution heat treatments at the same temperature and different cooling rates in addition to aging. Depending upon the TMP conditions, a wide range of microstructures with varying spatial distributions and morphologies of equiaxed/elongatedα andβ phases were attained, allowing for a wide range of electrochemical properties to be achieved. The corrosion behavior of the studied alloy was evaluated in a Ringer’s solution at 37 °C via open circuit potential?time and potentiodynamic polarization measurements.展开更多
Porous Ti-23%Nb(mole fraction)shape memory alloys(SMAs)were prepared successfully by microwave sintering with excellent outer finishing(without space holder).The effects of microwave-sintering on the microstructure,ph...Porous Ti-23%Nb(mole fraction)shape memory alloys(SMAs)were prepared successfully by microwave sintering with excellent outer finishing(without space holder).The effects of microwave-sintering on the microstructure,phase composition,phase-transformation temperature,mechanical properties and shape-memory effect were investigated.The results show that the density and size of porosity vary based on the sintering time and temperature,in which the smallest size and the most uniform pore shape are exhibited with Ti-23%Nb SMA after being sintered at 900°C for 30 min.The microstructure of porous Ti-Nb SMA consists of predominantα',α,andβphases in needle-like and plate-like morphologies,and their volume fractions vary based on the sintering time and temperature.Theβphase represents the largest phase due to the higher content ofβstabilizer element with little intensities ofαandα'phases.The highest ultimate strength and its strain are indicated for the sample sintered at 900°C for 30 min,while the best superelasticity is for the sample sintered at 1200°C for 30 min.The low-elastic modulus enables these alloys to avoid the problem of“stress shielding”.Therefore,microwave heating can be employed to sinter Ti-alloys for biomedical applications and improve the mechanical properties of these alloys.展开更多
基金Project(51371041)supported by the National Natural Science Foundation of China。
文摘From the perspective of biomechanics and forming technology,Ti−Fe−Zr−Sn−Y eutectic alloy was designed using a“cluster-plus-glue-atom”model,and then the alloy was prepared by laser additive manufacturing(LAM)on pure titanium substrate.The mechanical properties of the alloy were evaluated using micro-hardness and compression tester,and the elastic modulus was measured by nanoindenter.The results show that the alloy exhibits a high hardness of HV(788±10),a high strength of 2229 MPa,a failure strain of 14%,and a low elastic modulus of 87.5 GPa.The alloy also has good tribological,chemical,forming,and biological properties.The comprehensive performances of the Ti64.51Fe26.40Zr5.86Sn2.93Y0.30 alloy are superior to those of the Ti70.5Fe29.5 eutectic alloy and commercial Ti−6Al−4V alloy.All the above-mentioned qualities make the alloy a promising candidate as LAM biomaterial.
基金the financial assistance provided by Ministry of High Education and Scientific Research, the Government of Iraq
文摘The influence of thermo-mechanical processing (TMP) on the microstructure and the electrochemical behavior of new metastableβ alloy Ti?20.6Nb?13.6Zr?0.5V (TNZV) was investigated. The TMP included hot working in belowβ transus, solution heat treatments at the same temperature and different cooling rates in addition to aging. Depending upon the TMP conditions, a wide range of microstructures with varying spatial distributions and morphologies of equiaxed/elongatedα andβ phases were attained, allowing for a wide range of electrochemical properties to be achieved. The corrosion behavior of the studied alloy was evaluated in a Ringer’s solution at 37 °C via open circuit potential?time and potentiodynamic polarization measurements.
基金the financial support under the University Research Grant No. Q.J130000.3024. 00M57
文摘Porous Ti-23%Nb(mole fraction)shape memory alloys(SMAs)were prepared successfully by microwave sintering with excellent outer finishing(without space holder).The effects of microwave-sintering on the microstructure,phase composition,phase-transformation temperature,mechanical properties and shape-memory effect were investigated.The results show that the density and size of porosity vary based on the sintering time and temperature,in which the smallest size and the most uniform pore shape are exhibited with Ti-23%Nb SMA after being sintered at 900°C for 30 min.The microstructure of porous Ti-Nb SMA consists of predominantα',α,andβphases in needle-like and plate-like morphologies,and their volume fractions vary based on the sintering time and temperature.Theβphase represents the largest phase due to the higher content ofβstabilizer element with little intensities ofαandα'phases.The highest ultimate strength and its strain are indicated for the sample sintered at 900°C for 30 min,while the best superelasticity is for the sample sintered at 1200°C for 30 min.The low-elastic modulus enables these alloys to avoid the problem of“stress shielding”.Therefore,microwave heating can be employed to sinter Ti-alloys for biomedical applications and improve the mechanical properties of these alloys.