The present study theoretically explored the feasibility of the capillary method for measuring near-infrared (NIR) spectra of liquid or solution samples with microlitre volume, which was proposed in our previous studi...The present study theoretically explored the feasibility of the capillary method for measuring near-infrared (NIR) spectra of liquid or solution samples with microlitre volume, which was proposed in our previous studies. Lambert-Beer absorb- ance rule was applied to establish a model for the integral absorbance of capillary, which was then implemented in numerical analyses of the effects of capillary on various spectral features and dynamic range of absorption measurement. The theoretical speculations indicated that the capillary method might be used in NIR spectroscopy, which was further supported by the empirical data collected from our experiments by comparison between capillary NIR spectra of several organic solvents and cuvette cell NIR spectra.展开更多
The numerical simulation model for predicting fast filling process of 70 MPa type Ⅲ(with metal liner) hydrogen vehicle cylinder was presented,which has considered turbulence,real gas effect and solid heat transfer is...The numerical simulation model for predicting fast filling process of 70 MPa type Ⅲ(with metal liner) hydrogen vehicle cylinder was presented,which has considered turbulence,real gas effect and solid heat transfer issues.Through the numerical analysis method,the temperature distributions of the gas within the solid walls were revealed; adiabatic filling was studied to evaluate the heat dissipation during the filling; the influences of various filling conditions on temperature rise were analyzed in detail.Finally,cold filling was proposed to evaluate the effect on temperature rise and SoC(state of charge) within the cylinder.The hydrogen pre-cooling was proved to be an effective solution to reduce maximum temperature and acquire higher SoC during the filling process.展开更多
文摘The present study theoretically explored the feasibility of the capillary method for measuring near-infrared (NIR) spectra of liquid or solution samples with microlitre volume, which was proposed in our previous studies. Lambert-Beer absorb- ance rule was applied to establish a model for the integral absorbance of capillary, which was then implemented in numerical analyses of the effects of capillary on various spectral features and dynamic range of absorption measurement. The theoretical speculations indicated that the capillary method might be used in NIR spectroscopy, which was further supported by the empirical data collected from our experiments by comparison between capillary NIR spectra of several organic solvents and cuvette cell NIR spectra.
基金support of Institute of Beijing Aeronautic and Astronautic Testing Technology in the experiments of hydrogen fast filling process under 70 MPa
文摘The numerical simulation model for predicting fast filling process of 70 MPa type Ⅲ(with metal liner) hydrogen vehicle cylinder was presented,which has considered turbulence,real gas effect and solid heat transfer issues.Through the numerical analysis method,the temperature distributions of the gas within the solid walls were revealed; adiabatic filling was studied to evaluate the heat dissipation during the filling; the influences of various filling conditions on temperature rise were analyzed in detail.Finally,cold filling was proposed to evaluate the effect on temperature rise and SoC(state of charge) within the cylinder.The hydrogen pre-cooling was proved to be an effective solution to reduce maximum temperature and acquire higher SoC during the filling process.
