A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical met...A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical method was used to investigate the corrosion behavior of steel wires with different surface treatments of a corrosive acid solution.The results show that anode activation of steel wire mainly occurs during pre-corrosion,where the anode activation process of bare steel wires is the fastest as is their corresponding corrosion speed,while the anode activation process of oil coated steel wires and their corresponding corrosion speed are the lowest.During the intermediate and late immersion periods, a passive film is generated on the surface of steel wires,which are gradually damaged with the passage of time.Local pitting corrosion occurs easily on the surface of steel wires with a high-polarization potential. Suitable equivalent circuits were chosen to fit the electrochemical impedance spectroscopy（EIS）of steel wires over various corrosive times and different surface treatments,which indicate good fitting results. The double electrical layer charge-transfer resistance increases in the sequence：bare steel wire, untreated steel wire and oil coated steel wire and their corrosion resistance decreases in turn,which is consistent with their polarization curves.The oil layer provides a certain protective effect on untreated steel wires,but its effect is not entirely clear.展开更多
The influences of temperature on the mechanical behavior of saturated clays are discussed first. Based on the concept of true strength and the revised calculation method of the potential failure stress ratio, the equa...The influences of temperature on the mechanical behavior of saturated clays are discussed first. Based on the concept of true strength and the revised calculation method of the potential failure stress ratio, the equation of the critical state stress ratio for saturated clays under different temperatures is deduced. Temperature is introduced as a variable into the UH model （3-dimensional elastoplastic model for overconsolidated clays adopting unified hardening parameter） proposed by Yao et al. and then the UH model considering temperature effects is proposed. By means of the transformed stress method proposed by Yao et al., the proposed model can be applied conveniently to 3-dimensional stress states. The strain-hardening, softening and dilatancy behavior of overconsolidated clays at a given temperature can be described using the proposed model, and the volume change behavior caused by heating can also be predicted. Compared with the modified Cam-clay model, the proposed model requires only one additional parameter to consider the behavior of the decrease of preconsolidation pressure with an increase of temperature. At room temperature, the proposed model can be changed into the original UH model and the modified Cam-clay model for overconsolidated clays and normally consolidated clays, respectively. The considered temperature range here is from the melting point to the boiling point of the pore water （e.g. the experimental temperatures （20℃-95℃） mentioned in this paper are within this range）. Comparison with existing test results shows that the model can reasonably describe the basic mechanical behavior of overconsolidated clays under various temperature paths.展开更多
基金supported by the National Natural Science Foundation of China(No.50875252)the Program for New Century Excellent Talents in University(No.NCET-06-0479).
文摘A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical method was used to investigate the corrosion behavior of steel wires with different surface treatments of a corrosive acid solution.The results show that anode activation of steel wire mainly occurs during pre-corrosion,where the anode activation process of bare steel wires is the fastest as is their corresponding corrosion speed,while the anode activation process of oil coated steel wires and their corresponding corrosion speed are the lowest.During the intermediate and late immersion periods, a passive film is generated on the surface of steel wires,which are gradually damaged with the passage of time.Local pitting corrosion occurs easily on the surface of steel wires with a high-polarization potential. Suitable equivalent circuits were chosen to fit the electrochemical impedance spectroscopy（EIS）of steel wires over various corrosive times and different surface treatments,which indicate good fitting results. The double electrical layer charge-transfer resistance increases in the sequence：bare steel wire, untreated steel wire and oil coated steel wire and their corrosion resistance decreases in turn,which is consistent with their polarization curves.The oil layer provides a certain protective effect on untreated steel wires,but its effect is not entirely clear.
基金supported by the National Natural Science Foundation of China (Grant Nos.50879001,90815024,10872016,11072016)the National Basic Research Program of China ("973" Project) (Grant No.2007CB714103)
文摘The influences of temperature on the mechanical behavior of saturated clays are discussed first. Based on the concept of true strength and the revised calculation method of the potential failure stress ratio, the equation of the critical state stress ratio for saturated clays under different temperatures is deduced. Temperature is introduced as a variable into the UH model （3-dimensional elastoplastic model for overconsolidated clays adopting unified hardening parameter） proposed by Yao et al. and then the UH model considering temperature effects is proposed. By means of the transformed stress method proposed by Yao et al., the proposed model can be applied conveniently to 3-dimensional stress states. The strain-hardening, softening and dilatancy behavior of overconsolidated clays at a given temperature can be described using the proposed model, and the volume change behavior caused by heating can also be predicted. Compared with the modified Cam-clay model, the proposed model requires only one additional parameter to consider the behavior of the decrease of preconsolidation pressure with an increase of temperature. At room temperature, the proposed model can be changed into the original UH model and the modified Cam-clay model for overconsolidated clays and normally consolidated clays, respectively. The considered temperature range here is from the melting point to the boiling point of the pore water （e.g. the experimental temperatures （20℃-95℃） mentioned in this paper are within this range）. Comparison with existing test results shows that the model can reasonably describe the basic mechanical behavior of overconsolidated clays under various temperature paths.
