The reactive adsorption desulfurization of model gasoline was carried out on Ni/ZnO-HY adsorbent.The Ni/ZnO-HY adsorbent was characterized by N2adsorption-desorption test(BET),X-ray diffractometry(XRD),and temperature...The reactive adsorption desulfurization of model gasoline was carried out on Ni/ZnO-HY adsorbent.The Ni/ZnO-HY adsorbent was characterized by N2adsorption-desorption test(BET),X-ray diffractometry(XRD),and temperature-programmed reduction(TPR)analysis.The test results have demonstrated that HY-zeolite is a feasible support for Ni/ZnO components used in reactive adsorption desulfurization.The results of XRD and TPR analyses showed that most of nickel element was present as Ni2+species with only a small part existing as Ni3+species,and the Ni2+species had interactions with HY-zeolite.Under the conditions of this study,which specified a 50% ratio of HY-zeolite in the adsorbent,a Zn/Ni molar ratio of 10,and a reduction temperature of 400℃,the Ni/ZnO-HY adsorbent showed the best desulfurization performance.The sulfur capacity of Ni/ZnO-HY adsorbent could be recovered to 92.19% of the fresh one after being subjected to regeneration at 500℃,and could be maintained at 82.17% of the fresh one after 5 regeneration cycles.展开更多
As valuable energy in iron-and steel-making process,by-product gas is widely used in heating and technical processes in steel plant.After being used according to the technical requirements,the surplus by-product gas i...As valuable energy in iron-and steel-making process,by-product gas is widely used in heating and technical processes in steel plant.After being used according to the technical requirements,the surplus by-product gas is usually used for buffer boilers to produce steam.With the rapid development of energy conservation technology and energy consumption level,surplus gas in steel plant continues to get larger.Therefore,it is significant to organize surplus gas among buffer boilers.A dynamic programming model of that issue was established in this work,considering the ramp rate constraint of boilers and the influences of setting gasholders.Then a case study was done.It is shown that dynamic programming dispatch gets more steam generation and less specific gas consumption compared with current proportionate dispatch depending on nominal capacities of boilers.The ignored boiler ramp rate constraint was considered and its contribution to the result validity was pointed out.Finally,the significance of setting gasholders was studied.展开更多
The thermodynamic properties of metamizol monohydrate in pure solvents(methanol,ethanol,n-propanol and isopropanol) and two binary mixed solvent systems including(methanol+ethanol) and(methanol+isopropanol) were measu...The thermodynamic properties of metamizol monohydrate in pure solvents(methanol,ethanol,n-propanol and isopropanol) and two binary mixed solvent systems including(methanol+ethanol) and(methanol+isopropanol) were measured from 283.15 K to 313.15 K by gravimetric method under atmospheric pressure thought as 0.1 MPa.The modi fied Apelblat equation,the CNIBS/R-K equation,the Hybrid model and the NRTL model were used to correlate the solubility of metamizol monohydrate,respectively.The results show that the solubility of metamizol monohydrate in all the tested solvents increases with the rising temperature which means that it has temperature dependence.What's more,the effects of solvent components of the binary solvent mixtures on solubility were discussed,it illustrates that the increasing of the molar fraction of methanol gives the system a greater dissolving power.Furthermore,according to the NRTL model,the enthalpy,the Gibbs energy and the entropy of the mixing process were also obtained and discussed.展开更多
There is no doubt that the UHI (urban heat island) is a mounting problem in built-up environments, due to the energy retention by surface dense building materials, leading to increased temperatures, air pollution, a...There is no doubt that the UHI (urban heat island) is a mounting problem in built-up environments, due to the energy retention by surface dense building materials, leading to increased temperatures, air pollution, and energy consumption. Much of the earlier research on the UHI has used two-dimensional (2-D) information, such as land uses and the distribution of vegetation. In the case of homogeneous land uses, it is possible to predict surface temperatures with reasonable accuracy with 2-D information. However, three-dimensional (3-D) information is necessary to analyze more complex sites, including dense building clusters. In this research, 3-D building geometry information is combined with 2-D urban surface information to examine the relationship between urban characteristics and temperature. The research includes the following stages: (1) estimating urban temperature; (2) developing a 3-D city model; (3) generating geometric parameters; and (4) conducting statistical analyses using both linear and non-linear regression models. The implications of the results are discussed, providing guidelines for policies aiming to reduce the UHI.展开更多
The influences of temperature on the mechanical behavior of saturated clays are discussed first. Based on the concept of true strength and the revised calculation method of the potential failure stress ratio, the equa...The influences of temperature on the mechanical behavior of saturated clays are discussed first. Based on the concept of true strength and the revised calculation method of the potential failure stress ratio, the equation of the critical state stress ratio for saturated clays under different temperatures is deduced. Temperature is introduced as a variable into the UH model (3-dimensional elastoplastic model for overconsolidated clays adopting unified hardening parameter) proposed by Yao et al. and then the UH model considering temperature effects is proposed. By means of the transformed stress method proposed by Yao et al., the proposed model can be applied conveniently to 3-dimensional stress states. The strain-hardening, softening and dilatancy behavior of overconsolidated clays at a given temperature can be described using the proposed model, and the volume change behavior caused by heating can also be predicted. Compared with the modified Cam-clay model, the proposed model requires only one additional parameter to consider the behavior of the decrease of preconsolidation pressure with an increase of temperature. At room temperature, the proposed model can be changed into the original UH model and the modified Cam-clay model for overconsolidated clays and normally consolidated clays, respectively. The considered temperature range here is from the melting point to the boiling point of the pore water (e.g. the experimental temperatures (20℃-95℃) mentioned in this paper are within this range). Comparison with existing test results shows that the model can reasonably describe the basic mechanical behavior of overconsolidated clays under various temperature paths.展开更多
In recent decades,it presents a more obvious temperature rise in urban area along with the global warming.City is generally the center of human society,so the study on urban temperature variation will be helpful to ou...In recent decades,it presents a more obvious temperature rise in urban area along with the global warming.City is generally the center of human society,so the study on urban temperature variation will be helpful to our city development planning that is to reduce urban warming.The study is also helpful to a more comprehensive understanding of the causes of climate warming,which could provide a theoretical support to the government to make more reasonable international energy policies.Local temperature rise has different mechanisms with the global warming:large quantities of artificial heat release from the energy consumption will stay in urban areas for a period of time,which will inevitably influence the short-term trend of the local temperature change.Based on that view,a structural thermodynamic model was established in this paper to investigate the effect of the artificial heat release on the urban local temperatures.In the model,the city environment was divided into Human,Local,Outer three blocks,and then the heat and temperatures of the blocks were analyzed based on the laws of thermodynamics.After that,the effect of artificial heat release in Human block on the local temperatures was clarified.The model shows that the artificial heat release has an approximately linearly promoting effect on the local temperature rise,and the more the heat release is,the stronger the effect is.In addition,a validation of that model was carried out based on some national statistical data.The data of temperatures and artificial heat release of some provincial capitals of China were analyzed with linear regression extrapolation method and Pearson correlation statistical method.The results show that in most capital cities,the temperature variations basically depend on the artificial heat release in a linear relationship,which usually becomes more apparent with the increase of the artificial heat release in both spatial and temporal dimensions.The conclusions of the statistics have good conformity with the model and the rationality of the model is verified.展开更多
Global vegetation photosynthesis and productivity have increased substantially since the 1980s,but this trend is heterogeneous in both time and space.Here,we categorize the secular trend in global vegetation greenness...Global vegetation photosynthesis and productivity have increased substantially since the 1980s,but this trend is heterogeneous in both time and space.Here,we categorize the secular trend in global vegetation greenness into sustained greening,sustained browning and greening-to-browning.We found that by 2016,increased global vegetation greenness had begun to level off,with the area of browning increasing in the last decade,reaching 39.0 million km^(2)(35.9%of the world’s vegetated area).This area is larger than the area with sustained increasing growth(27.8 million km^(2),26.4%);thus,12.0%±3.1%(0.019±0.004 NDVI a^(-1))of the previous earlier increase has been offset since 2010(2010–2016,P<0.05).Global gross primary production also leveled off,following the trend in vegetation greenness in time and space.This leveling off was caused by increasing soil water limitations due to the spatial expansion of drought,whose impact dominated over the impacts of temperature and solar radiation.This response of global gross primary production to soil water limitation was not identified by land submodels within Earth system models.Our results provide empirical evidence that global vegetation greenness and primary production are offset by water stress and suggest that as global warming continues,land submodels may overestimate the world’s capacity to take up carbon with global vegetation greening.展开更多
基金financially supported by the National Natural Science Foundation of China(No.21276086)the Opening Project of State Key Laboratory of Chemical Engineering of East China University of Science and Technology(No.SKL-ChE-11C04)
文摘The reactive adsorption desulfurization of model gasoline was carried out on Ni/ZnO-HY adsorbent.The Ni/ZnO-HY adsorbent was characterized by N2adsorption-desorption test(BET),X-ray diffractometry(XRD),and temperature-programmed reduction(TPR)analysis.The test results have demonstrated that HY-zeolite is a feasible support for Ni/ZnO components used in reactive adsorption desulfurization.The results of XRD and TPR analyses showed that most of nickel element was present as Ni2+species with only a small part existing as Ni3+species,and the Ni2+species had interactions with HY-zeolite.Under the conditions of this study,which specified a 50% ratio of HY-zeolite in the adsorbent,a Zn/Ni molar ratio of 10,and a reduction temperature of 400℃,the Ni/ZnO-HY adsorbent showed the best desulfurization performance.The sulfur capacity of Ni/ZnO-HY adsorbent could be recovered to 92.19% of the fresh one after being subjected to regeneration at 500℃,and could be maintained at 82.17% of the fresh one after 5 regeneration cycles.
基金Project(L2012082)supported by the Science and Technology Research Funds of Liaoning Provincial Education Department,China
文摘As valuable energy in iron-and steel-making process,by-product gas is widely used in heating and technical processes in steel plant.After being used according to the technical requirements,the surplus by-product gas is usually used for buffer boilers to produce steam.With the rapid development of energy conservation technology and energy consumption level,surplus gas in steel plant continues to get larger.Therefore,it is significant to organize surplus gas among buffer boilers.A dynamic programming model of that issue was established in this work,considering the ramp rate constraint of boilers and the influences of setting gasholders.Then a case study was done.It is shown that dynamic programming dispatch gets more steam generation and less specific gas consumption compared with current proportionate dispatch depending on nominal capacities of boilers.The ignored boiler ramp rate constraint was considered and its contribution to the result validity was pointed out.Finally,the significance of setting gasholders was studied.
基金Supported by National Natural Science Foundation of China(21206109)China Ministry of Science and Major National Scientific Instrument Development Project(21527812)
文摘The thermodynamic properties of metamizol monohydrate in pure solvents(methanol,ethanol,n-propanol and isopropanol) and two binary mixed solvent systems including(methanol+ethanol) and(methanol+isopropanol) were measured from 283.15 K to 313.15 K by gravimetric method under atmospheric pressure thought as 0.1 MPa.The modi fied Apelblat equation,the CNIBS/R-K equation,the Hybrid model and the NRTL model were used to correlate the solubility of metamizol monohydrate,respectively.The results show that the solubility of metamizol monohydrate in all the tested solvents increases with the rising temperature which means that it has temperature dependence.What's more,the effects of solvent components of the binary solvent mixtures on solubility were discussed,it illustrates that the increasing of the molar fraction of methanol gives the system a greater dissolving power.Furthermore,according to the NRTL model,the enthalpy,the Gibbs energy and the entropy of the mixing process were also obtained and discussed.
文摘There is no doubt that the UHI (urban heat island) is a mounting problem in built-up environments, due to the energy retention by surface dense building materials, leading to increased temperatures, air pollution, and energy consumption. Much of the earlier research on the UHI has used two-dimensional (2-D) information, such as land uses and the distribution of vegetation. In the case of homogeneous land uses, it is possible to predict surface temperatures with reasonable accuracy with 2-D information. However, three-dimensional (3-D) information is necessary to analyze more complex sites, including dense building clusters. In this research, 3-D building geometry information is combined with 2-D urban surface information to examine the relationship between urban characteristics and temperature. The research includes the following stages: (1) estimating urban temperature; (2) developing a 3-D city model; (3) generating geometric parameters; and (4) conducting statistical analyses using both linear and non-linear regression models. The implications of the results are discussed, providing guidelines for policies aiming to reduce the UHI.
基金supported by the National Natural Science Foundation of China (Grant Nos.50879001,90815024,10872016,11072016)the National Basic Research Program of China ("973" Project) (Grant No.2007CB714103)
文摘The influences of temperature on the mechanical behavior of saturated clays are discussed first. Based on the concept of true strength and the revised calculation method of the potential failure stress ratio, the equation of the critical state stress ratio for saturated clays under different temperatures is deduced. Temperature is introduced as a variable into the UH model (3-dimensional elastoplastic model for overconsolidated clays adopting unified hardening parameter) proposed by Yao et al. and then the UH model considering temperature effects is proposed. By means of the transformed stress method proposed by Yao et al., the proposed model can be applied conveniently to 3-dimensional stress states. The strain-hardening, softening and dilatancy behavior of overconsolidated clays at a given temperature can be described using the proposed model, and the volume change behavior caused by heating can also be predicted. Compared with the modified Cam-clay model, the proposed model requires only one additional parameter to consider the behavior of the decrease of preconsolidation pressure with an increase of temperature. At room temperature, the proposed model can be changed into the original UH model and the modified Cam-clay model for overconsolidated clays and normally consolidated clays, respectively. The considered temperature range here is from the melting point to the boiling point of the pore water (e.g. the experimental temperatures (20℃-95℃) mentioned in this paper are within this range). Comparison with existing test results shows that the model can reasonably describe the basic mechanical behavior of overconsolidated clays under various temperature paths.
基金supported by the Knowledge Innovation Project of The Chinese Academy of Sciences(Grant No. KGCX2-YW-356)
文摘In recent decades,it presents a more obvious temperature rise in urban area along with the global warming.City is generally the center of human society,so the study on urban temperature variation will be helpful to our city development planning that is to reduce urban warming.The study is also helpful to a more comprehensive understanding of the causes of climate warming,which could provide a theoretical support to the government to make more reasonable international energy policies.Local temperature rise has different mechanisms with the global warming:large quantities of artificial heat release from the energy consumption will stay in urban areas for a period of time,which will inevitably influence the short-term trend of the local temperature change.Based on that view,a structural thermodynamic model was established in this paper to investigate the effect of the artificial heat release on the urban local temperatures.In the model,the city environment was divided into Human,Local,Outer three blocks,and then the heat and temperatures of the blocks were analyzed based on the laws of thermodynamics.After that,the effect of artificial heat release in Human block on the local temperatures was clarified.The model shows that the artificial heat release has an approximately linearly promoting effect on the local temperature rise,and the more the heat release is,the stronger the effect is.In addition,a validation of that model was carried out based on some national statistical data.The data of temperatures and artificial heat release of some provincial capitals of China were analyzed with linear regression extrapolation method and Pearson correlation statistical method.The results show that in most capital cities,the temperature variations basically depend on the artificial heat release in a linear relationship,which usually becomes more apparent with the increase of the artificial heat release in both spatial and temporal dimensions.The conclusions of the statistics have good conformity with the model and the rationality of the model is verified.
基金the National Key Research and Development Program of China(2017YFA0604700)the National Natural Science Foundation of China(41722104)+3 种基金the Key Research Project of Chinese Academy of Sciences(QYZDY-SSWDQC025 and 2019DC0027)supported by the European Research Council Synergy(ERC-2013-Sy G-610028 IMBALANCE-P)the Spanish Government(CGL2016-79835)the Catalan Government(SGR 2017-1005)。
文摘Global vegetation photosynthesis and productivity have increased substantially since the 1980s,but this trend is heterogeneous in both time and space.Here,we categorize the secular trend in global vegetation greenness into sustained greening,sustained browning and greening-to-browning.We found that by 2016,increased global vegetation greenness had begun to level off,with the area of browning increasing in the last decade,reaching 39.0 million km^(2)(35.9%of the world’s vegetated area).This area is larger than the area with sustained increasing growth(27.8 million km^(2),26.4%);thus,12.0%±3.1%(0.019±0.004 NDVI a^(-1))of the previous earlier increase has been offset since 2010(2010–2016,P<0.05).Global gross primary production also leveled off,following the trend in vegetation greenness in time and space.This leveling off was caused by increasing soil water limitations due to the spatial expansion of drought,whose impact dominated over the impacts of temperature and solar radiation.This response of global gross primary production to soil water limitation was not identified by land submodels within Earth system models.Our results provide empirical evidence that global vegetation greenness and primary production are offset by water stress and suggest that as global warming continues,land submodels may overestimate the world’s capacity to take up carbon with global vegetation greening.