A numerical investigation on the co-pyrolysis of 1,3-butadiene and propyne is performed to explore the synergistic effect between fuel components on aromatic hydrocarbon formation. A detailed kinetic model of 1,3-buta...A numerical investigation on the co-pyrolysis of 1,3-butadiene and propyne is performed to explore the synergistic effect between fuel components on aromatic hydrocarbon formation. A detailed kinetic model of 1,3-butadiene/propyne co-pyrolysis with the sub-mechanism of aromatic hydrocarbon formation is developed and validated on previous 1,3-butadiene and propyne pyrolysis experiments. The model is able to reproduce both the single component pyrolysis and the co-pyrolysis experiments, as well as the synergistic effect between 1,3- butadiene and propyne on the formation of a series of aromatic hydrocarbons. Based on the rate of production and sensitivity analyses, key reaction pathways in the fuel decomposition and aromatic hydrocarbon formation processes are revealed and insight into the synergistic effect on aromatic hydrocarbon formation is also achieved. The synergistic effect results from the interaction between 1,3-butadiene and propyne. The easily happened chain initiation in the 1,3-butadiene decomposition provides an abundant radical pool for propyne to undergo the H-atom abstraction and produce propargyl radical which plays key roles in the formation of aromatic hydrocarbons. Besides, the 1,3-butadiene/propyne co-pyrolysis includes high concentration levels of C3 and C4 precursors simultaneously, which stimulates the formation of key aromatic hydrocarbons such as toluene and naphthalene.展开更多
It is extensively approved that Channel State Information(CSI) plays an important role for synergetic transmission and interference management. However, pilot overhead to obtain CSI with enough precision is a signific...It is extensively approved that Channel State Information(CSI) plays an important role for synergetic transmission and interference management. However, pilot overhead to obtain CSI with enough precision is a significant issue for wireless communication networks with massive antennas and ultra-dense cell. This paper proposes a learning- based channel model, which can estimate, refine, and manage CSI for a synergetic transmission system. It decomposes the channel impulse response into multiple paths, and uses a learning-based algorithm to estimate paths' parameters without notable degradation caused by sparse pilots. Both indoor measurement and outdoor measurement are conducted to verify the feasibility of the proposed channel model preliminarily.展开更多
This paper substantiates the idea that particular science reflects only a certain angle of a complex model of the world. Guidance as to ＂adding＂ particular science data in order to achieve a holistic picture of the ...This paper substantiates the idea that particular science reflects only a certain angle of a complex model of the world. Guidance as to ＂adding＂ particular science data in order to achieve a holistic picture of the world is a philosophical outlook. The meaning of each relatively closed system is revealed only in the context of a more capacious system. According to the author, as the material world itself, its epistemic models as well are built according to the principle of ＂matryoshka dolls.＂ The rational and irrational are discussed in the paper as equal moments of scientific knowledge. Contrary to the importance given to randomness in synergy, the author considers if it is possible to find out the causes of all events. In order to do this, other viewpoints and structure levels should be considered. There is a hidden order in every chaos, and that is revealed only in a certain situation. The main issue is taking into account the counter action of the system with the environment.展开更多
Based on a membrane-bulk coupling cell model proposed by Gomez-Marin et al. [ Phys. Rev. Lett. 98 （2007） 168303], the cooperative effects of noise and coupling on the stochastic dynamical behavior are investigated. ...Based on a membrane-bulk coupling cell model proposed by Gomez-Marin et al. [ Phys. Rev. Lett. 98 （2007） 168303], the cooperative effects of noise and coupling on the stochastic dynamical behavior are investigated. For parameters in a certain region, the oscillation can be induced by the cooperative effect of noise and coupling. Whether considering the coupling or not, corresponding coherence resonance phenomena are observed. Furthermore, the effects of two coupling parameters, cell size L and coupling intensity k, on the noise-induced oscillation of membranes are studied. Contrary effects of noise are found in and out of the deterministic oscillatory regions.展开更多
基金This work is supported by the National Natural Science Foundation of China （No.51476155, No.51622605, No.91541201）, the National Key Sci- entific Instruments and Equipment Development Program of China （No.2012YQ22011305）, the National Postdoctoral Program for Innovative Talents （No.BX201600100）, and China Postdoctoral Science Foundation （No.2016M600312）.
文摘A numerical investigation on the co-pyrolysis of 1,3-butadiene and propyne is performed to explore the synergistic effect between fuel components on aromatic hydrocarbon formation. A detailed kinetic model of 1,3-butadiene/propyne co-pyrolysis with the sub-mechanism of aromatic hydrocarbon formation is developed and validated on previous 1,3-butadiene and propyne pyrolysis experiments. The model is able to reproduce both the single component pyrolysis and the co-pyrolysis experiments, as well as the synergistic effect between 1,3- butadiene and propyne on the formation of a series of aromatic hydrocarbons. Based on the rate of production and sensitivity analyses, key reaction pathways in the fuel decomposition and aromatic hydrocarbon formation processes are revealed and insight into the synergistic effect on aromatic hydrocarbon formation is also achieved. The synergistic effect results from the interaction between 1,3-butadiene and propyne. The easily happened chain initiation in the 1,3-butadiene decomposition provides an abundant radical pool for propyne to undergo the H-atom abstraction and produce propargyl radical which plays key roles in the formation of aromatic hydrocarbons. Besides, the 1,3-butadiene/propyne co-pyrolysis includes high concentration levels of C3 and C4 precursors simultaneously, which stimulates the formation of key aromatic hydrocarbons such as toluene and naphthalene.
基金supported by National Basic Research Program of China (NO 2012CB316002)China’s 863 Project (NO 2014AA01A703)+2 种基金National Major Projec (NO. 2014ZX03003002-002)Program for New Century Excellent Talents in University (NCET-13-0321)Tsinghua University Initiative Scientific Research Program (2011THZ02-2)
文摘It is extensively approved that Channel State Information(CSI) plays an important role for synergetic transmission and interference management. However, pilot overhead to obtain CSI with enough precision is a significant issue for wireless communication networks with massive antennas and ultra-dense cell. This paper proposes a learning- based channel model, which can estimate, refine, and manage CSI for a synergetic transmission system. It decomposes the channel impulse response into multiple paths, and uses a learning-based algorithm to estimate paths' parameters without notable degradation caused by sparse pilots. Both indoor measurement and outdoor measurement are conducted to verify the feasibility of the proposed channel model preliminarily.
文摘This paper substantiates the idea that particular science reflects only a certain angle of a complex model of the world. Guidance as to ＂adding＂ particular science data in order to achieve a holistic picture of the world is a philosophical outlook. The meaning of each relatively closed system is revealed only in the context of a more capacious system. According to the author, as the material world itself, its epistemic models as well are built according to the principle of ＂matryoshka dolls.＂ The rational and irrational are discussed in the paper as equal moments of scientific knowledge. Contrary to the importance given to randomness in synergy, the author considers if it is possible to find out the causes of all events. In order to do this, other viewpoints and structure levels should be considered. There is a hidden order in every chaos, and that is revealed only in a certain situation. The main issue is taking into account the counter action of the system with the environment.
基金supported by the National Natural Science Foundation of China under Grant No.10575041
文摘Based on a membrane-bulk coupling cell model proposed by Gomez-Marin et al. [ Phys. Rev. Lett. 98 （2007） 168303], the cooperative effects of noise and coupling on the stochastic dynamical behavior are investigated. For parameters in a certain region, the oscillation can be induced by the cooperative effect of noise and coupling. Whether considering the coupling or not, corresponding coherence resonance phenomena are observed. Furthermore, the effects of two coupling parameters, cell size L and coupling intensity k, on the noise-induced oscillation of membranes are studied. Contrary effects of noise are found in and out of the deterministic oscillatory regions.
