The experimental study of natural convection in allglass evacuated tube solar collectors is performed through the experimental platform of the solar-assisted fuel cell system.The experimental facility includes solar c...The experimental study of natural convection in allglass evacuated tube solar collectors is performed through the experimental platform of the solar-assisted fuel cell system.The experimental facility includes solar collectors with different length and diameter tubes, different coating materials, and with / without guide plates, respectively. Threedimensional mathematical models on natural and forced convections in the solar collectors are established and the experimental data is validated by field synergy and entransy principles. The results of natural convection show that the water temperature increases and thermal efficiency decreases gradually with the evacuated tube length. The thermal efficiency increases when absorption rates increase from 0. 95 to 1. 0 and emission rates decrease from 0. 16 to 0. 06. The thermal efficiency of solar collectors is increased after being equipped with the guide plate, which is attributed to the disappearance of the mixed flowand the enhancement of the heat transfer at the bottom of the evacuated tube. The results of forced convertion indicate that the Reynolds, Nusselt and entransy increments of the horizontal double collectors are higher than those of the vertical single collector while the entransy dissipation is lower than that of the vertical single collector. It is concluded that the solar collectors with guide plates are suitable for natural convection while the double horizontal collectors are suitable for forced convection in the thermal field of solar-assisted fuel cell systems with lowand medium temperatures.展开更多
This study combines the three-dimensional model of the high-temperature proton exchange membrane fuel cell(HT-PEMFC)with theoretical analysis,by optimizing the structure of the fuel cell,adding a semicircular baffle i...This study combines the three-dimensional model of the high-temperature proton exchange membrane fuel cell(HT-PEMFC)with theoretical analysis,by optimizing the structure of the fuel cell,adding a semicircular baffle in the gas channel and implementing novelly arranged obstacles to improve the PEMFC performance. The effects of velocity distribution,interface reactant concentration and pressure drop on performance are studied. The results show that adding obstacles in the gas channel will produce vertical velocity and can improve output performance,especially in the case of high current density and higher baffle radius. The superiority of the optimized structure in mass transfer capacity is proved,and a mechanism explanation is given for the improvement of performance.展开更多
TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite photoanodes were successfully designed for the first time. The photoelectric conversion efficiency of TiO2-NaYF4:Er^3+/Yb^3+ C3N4 composite cell can result an efficiency of ...TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite photoanodes were successfully designed for the first time. The photoelectric conversion efficiency of TiO2-NaYF4:Er^3+/Yb^3+ C3N4 composite cell can result an efficiency of 7.37%, which is higher than those of pure TiO2 cell and TiO2-C3N4 composite cell. The enhancement of the efficiency can be attributed to the synergetic effect of NaYF4:Er^3+/Yb^3+ and C3N4. Elec- trochemical impedance spectroscopy analysis revealed that the interfacial resistance of the TiO2-dyelI3^-/I^- electrolyte interface of TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composites cell was much smaller than that of pure TiO2 cell. In addition, the TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite cell had longer electron recombination time and shorter electron transport time than that of pure TiO2 cell.展开更多
LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2, LiMn_2O_4 and LiCoO_2 are paired to make the blended materials for the cathode of lithium-ion batteries. The factors impacting on the characteristics of blended materials are studied usi...LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2, LiMn_2O_4 and LiCoO_2 are paired to make the blended materials for the cathode of lithium-ion batteries. The factors impacting on the characteristics of blended materials are studied using constant current charge/discharge measurement and electrochemical impedance spectroscopy. The results show that the three pairs of blended materials exhibit very different synergetic effects in high C-rate discharging. The mechanism of particle synergetic effect has a physical root on the compensating material property of blending components, which fundamentally correlates with their similarity and difference in crystalline and electronic structures. The AC impedance show the obvious changes that alternate the high C-rate performance, due to reduced particle impedance in blended materials. The pairs of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2-LiMn_2O and LiCoO_2-LiMn_2O_4 present obvious increases in high C-rate reversible capacities than does the pair LiCoO_2-LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2.展开更多
基金The National Natural Science Foundation of China(No.51376110,51541604)the Major International(Regional) Joint Research Project of the National Natural Science Foundation of China(No.61320106011)
文摘The experimental study of natural convection in allglass evacuated tube solar collectors is performed through the experimental platform of the solar-assisted fuel cell system.The experimental facility includes solar collectors with different length and diameter tubes, different coating materials, and with / without guide plates, respectively. Threedimensional mathematical models on natural and forced convections in the solar collectors are established and the experimental data is validated by field synergy and entransy principles. The results of natural convection show that the water temperature increases and thermal efficiency decreases gradually with the evacuated tube length. The thermal efficiency increases when absorption rates increase from 0. 95 to 1. 0 and emission rates decrease from 0. 16 to 0. 06. The thermal efficiency of solar collectors is increased after being equipped with the guide plate, which is attributed to the disappearance of the mixed flowand the enhancement of the heat transfer at the bottom of the evacuated tube. The results of forced convertion indicate that the Reynolds, Nusselt and entransy increments of the horizontal double collectors are higher than those of the vertical single collector while the entransy dissipation is lower than that of the vertical single collector. It is concluded that the solar collectors with guide plates are suitable for natural convection while the double horizontal collectors are suitable for forced convection in the thermal field of solar-assisted fuel cell systems with lowand medium temperatures.
基金supported by the De-fense Industrial Technology Development Program (No. JCKY2018605B006)the Aviation Science Fund (No. 201928052002)
文摘This study combines the three-dimensional model of the high-temperature proton exchange membrane fuel cell(HT-PEMFC)with theoretical analysis,by optimizing the structure of the fuel cell,adding a semicircular baffle in the gas channel and implementing novelly arranged obstacles to improve the PEMFC performance. The effects of velocity distribution,interface reactant concentration and pressure drop on performance are studied. The results show that adding obstacles in the gas channel will produce vertical velocity and can improve output performance,especially in the case of high current density and higher baffle radius. The superiority of the optimized structure in mass transfer capacity is proved,and a mechanism explanation is given for the improvement of performance.
基金supported by the National Natural Science Foundation of China (21471050 and 21501052)the China Postdoctoral Science Foundation (2015M570304)+2 种基金the Postdoctoral Science Foundation of Heilongjiang Province (LBH-TZ06019)Heilongjiang Province Natural Science Foundation (ZD201301)the Science Foundation for Excellent Youth of Harbin City of China (2016RQQXJ099)
文摘TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite photoanodes were successfully designed for the first time. The photoelectric conversion efficiency of TiO2-NaYF4:Er^3+/Yb^3+ C3N4 composite cell can result an efficiency of 7.37%, which is higher than those of pure TiO2 cell and TiO2-C3N4 composite cell. The enhancement of the efficiency can be attributed to the synergetic effect of NaYF4:Er^3+/Yb^3+ and C3N4. Elec- trochemical impedance spectroscopy analysis revealed that the interfacial resistance of the TiO2-dyelI3^-/I^- electrolyte interface of TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composites cell was much smaller than that of pure TiO2 cell. In addition, the TiO2-NaYF4:Er^3+/Yb^3+-C3N4 composite cell had longer electron recombination time and shorter electron transport time than that of pure TiO2 cell.
基金supported by the National Research Program of China (Grant No. 2013AA050901)the National Young Scholar Natural Science Foundation of China (Grant No. 201303235)+3 种基金the Public Projects of Zhejiang Province (Grant No. 2015C31122)Zhejiang Natural Science Foundation(Grant No. LY16B030007)Ningbo Natural Science Foundation (Grant No.2015A610240)Zhejiang Province Key Science and Technology InnovationTeam (Grant No. 2013PT16)
文摘LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2, LiMn_2O_4 and LiCoO_2 are paired to make the blended materials for the cathode of lithium-ion batteries. The factors impacting on the characteristics of blended materials are studied using constant current charge/discharge measurement and electrochemical impedance spectroscopy. The results show that the three pairs of blended materials exhibit very different synergetic effects in high C-rate discharging. The mechanism of particle synergetic effect has a physical root on the compensating material property of blending components, which fundamentally correlates with their similarity and difference in crystalline and electronic structures. The AC impedance show the obvious changes that alternate the high C-rate performance, due to reduced particle impedance in blended materials. The pairs of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2-LiMn_2O and LiCoO_2-LiMn_2O_4 present obvious increases in high C-rate reversible capacities than does the pair LiCoO_2-LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2.