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D-π-A型三联吡啶衍生物的合成、结构和光学特性 被引量:2
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作者 高远浩 田玉鹏 +3 位作者 杨家祥 杨风岭 李静 郑直 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2011年第8期1755-1760,共6页
以2,2'∶6',2″-三联吡啶为电子受体(Acceptor,A)基元,通过Wittig成烯反应引入N-己基-3-甲酰基咔唑电子给体(Donor,D)基元,合成了一种D-π-A型三联吡啶衍生物,对其进行了质谱、核磁共振波谱、红外光谱及X射线单晶结构分析.光学... 以2,2'∶6',2″-三联吡啶为电子受体(Acceptor,A)基元,通过Wittig成烯反应引入N-己基-3-甲酰基咔唑电子给体(Donor,D)基元,合成了一种D-π-A型三联吡啶衍生物,对其进行了质谱、核磁共振波谱、红外光谱及X射线单晶结构分析.光学性质研究结果表明,目标产物具有单、双光子吸收和荧光特性,荧光量子产率(Ф)高达0.46,最大双光子吸收截面(δ)为120 GM. 展开更多
关键词 三联吡啶衍生物 单晶结构 单光子特性 光子特性
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Spatial modulation characteristics of single-photon frequency up-conversion systems pumped by Gaussian laser beam
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作者 马建辉 李雄杰 +3 位作者 吴文杰 黄坤 潘海峰 武愕 《Optoelectronics Letters》 EI 2015年第6期477-480,共4页
In a Gaussian laser beam pumped single-photon frequency up-conversion system, the spatial distribution of the con- version efficiency is calculated, which strongly depends on the intensity distribution of the pump bea... In a Gaussian laser beam pumped single-photon frequency up-conversion system, the spatial distribution of the con- version efficiency is calculated, which strongly depends on the intensity distribution of the pump beam and leads to a spatial modulation of the output single photons. As a result, by simply varying the Gauss/an pump beam intensity and the beam size, the converted photons could be modulated spatially and exhibit a programmable distribution. This will be meaningful for the researches on quantum communication and quantum manipulation based on frequency up-conversion svstem. 展开更多
关键词 高斯激光束 转换系统 空间分布 泵浦光束 调制特性 单光子 频率 SER
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Design of large-core single-mode Yb^(3+)-doped photonic crystal fiber
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作者 赵兴涛 郑义 +3 位作者 刘晓旭 周桂耀 刘兆伦 侯蓝田 《Optoelectronics Letters》 EI 2012年第3期212-215,共4页
The effective index of the cladding fundamental space-filling mode in photonic crystal fiber (PCF) is simulated by the effective index method. The variation of the effective index with the structure parameters of the ... The effective index of the cladding fundamental space-filling mode in photonic crystal fiber (PCF) is simulated by the effective index method. The variation of the effective index with the structure parameters of the fiber is achieved. For the first time, the relations of the V parameter of Yb3+-doped PCF with the refractive index of core and the structure parameters of the fiber are provided. the single-mode characteristics of large-core Yb3+-doped photonic crystal fibers with 7 and 19 missing air holes in the core are analyzed. The large-core single-mode Yb3+-doped photonic crystal fibers with core diameters of 50 μm, 100 μm and 150 μm are designed. The results provide theory instruction for the design and fabrication of fiber. 展开更多
关键词 Nonlinear optics Optical fiber fabrication Optical waveguides Photonic crystal fibers Refractive index YTTERBIUM
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Theoretical study of the electronic ground states and low-lying singlet excited states of thiophene-based spirofluorenes 被引量:1
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作者 CHEN RunFeng MA Cong +2 位作者 PAN JingFang ZHENG Chao HUANG Wei 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第5期884-889,共6页
The electronic structures and optical properties of oligothiophene substituted spirofluorenes are investigated theoretically with semi-empirical quantum chemical calculations. A theoretical investigation of the intera... The electronic structures and optical properties of oligothiophene substituted spirofluorenes are investigated theoretically with semi-empirical quantum chemical calculations. A theoretical investigation of the interaction between two perpendicular π-systems of various oligothiophene substituted spirofluorenes is conducted. The results demonstrate that the interaction be- tween two perpendicular branches is reduced by oligothiophene substitutions. Photoexcitation induced relaxation is mainly located on one of the equivalent branches or the branch with longer conjugation length. In addition to these benefits brought by 9,9-spirobifluorene center, the specific oligothiophene moieties linked to the spirt center also have properties of significant merit, such as the ability to tune energy levels and emission colors by controlling the conjugation length. 展开更多
关键词 spirofluorene OLEDS AM1 THIOPHENE
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Single Photon Scattering Properties in Coupled-Resonator Waveguide Coupling with a Nanocavity Interacting with an External Mirror 被引量:1
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作者 程木田 纵卫卫 +3 位作者 叶根龙 马小三 章家岩 王兵 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第6期767-771,共5页
We investigate theoretically single photon transport properties in coupled-resonator waveguide coupling with a nanocavity interacting with an external mirror. By using the discrete coordinates approach, transmission a... We investigate theoretically single photon transport properties in coupled-resonator waveguide coupling with a nanocavity interacting with an external mirror. By using the discrete coordinates approach, transmission and reflection amplitudes of the propagating single photon in the waveguide are obtained. The influence of the coupling strength between the nanocavity and the external mirror on the single photon scattering spectra is discussed. We also extend the results to the waveguide with linear and quadratic form dispersion relations. 展开更多
关键词 coupled-resonator waveguide single photon scattering
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