Monodisperse and size-tunable magnetic iron oxide nanoparticles （NPs） have been synthesized by thermal decomposition of an iron oleate complex at 310 ℃ in the presence of oleylamine and oleic acid. The diameters of...Monodisperse and size-tunable magnetic iron oxide nanoparticles （NPs） have been synthesized by thermal decomposition of an iron oleate complex at 310 ℃ in the presence of oleylamine and oleic acid. The diameters of the as-synthesized iron oxide NPs decrease with increasing concentrations of iron oleate complex and oleic acid/oleylamine. In addition, the size-dependent crystallinity and magnetic properties of iron oxide NPs are presented. It is found that larger iron oxide NPs have a higher degree of crystallinity and saturation magnetization. More importantly, various M-iron oxide heterostructures （M = Au, Ag, Pt, Pd） have been successfully fabricated by using the same synthesis procedure. The iron oxide NPs are grown over the pre-made metal seeds through a seed-mediated growth process. The physicochemical properties of Au-Fe3O4 heterostructures have been characterized by X-ray diffraction （XRD）, superconducting quantum interference device （SQUID） magnetometry and UV-vis spectroscopy. The as-synthesized Au-Fe3O4 heterostructures show a red-shift in surface plasmon resonance peak compared with Au NPs and similar magnetic properties to Fe3O4 NPs. The heterojunction effects present in such nanostructures offer the opportunity to tune the irphysicochemical properties. Therefore, this synthesis process can be regarded as an efficient way to fabricate a series of heterostructures for a variety of applications.展开更多
We report a facile method to synthesize dispersed Fe304@C nanoparticles （NPs）. Fe304 NPs were firstly prepared via the high temperature diol thermal decomposition method. Fe304@C NPs were fabricated using glucose as...We report a facile method to synthesize dispersed Fe304@C nanoparticles （NPs）. Fe304 NPs were firstly prepared via the high temperature diol thermal decomposition method. Fe304@C NPs were fabricated using glucose as a carbon source by hydro- thermal process. The obtained products were characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, vibrating sample magnetometer （VSM） and Raman spectra. The results indicate that the original shapes and magnetic property of Fe304 NPs can be well preserved. The magnetic particles are well dispersed in the carbon matrix. This strategy would provide an efficient approach for existing applications in Li-ion batteries and drug delivery. Meanwhile, it offers the raw materials to assemble future functional nanometer and micrometer superstructures.展开更多
基金supported by the National Natural Science Foundation of China(21229301,21403126)Research Foundation of Education Bureau of Hubei Province,China(D20131302)~~
文摘Monodisperse and size-tunable magnetic iron oxide nanoparticles （NPs） have been synthesized by thermal decomposition of an iron oleate complex at 310 ℃ in the presence of oleylamine and oleic acid. The diameters of the as-synthesized iron oxide NPs decrease with increasing concentrations of iron oleate complex and oleic acid/oleylamine. In addition, the size-dependent crystallinity and magnetic properties of iron oxide NPs are presented. It is found that larger iron oxide NPs have a higher degree of crystallinity and saturation magnetization. More importantly, various M-iron oxide heterostructures （M = Au, Ag, Pt, Pd） have been successfully fabricated by using the same synthesis procedure. The iron oxide NPs are grown over the pre-made metal seeds through a seed-mediated growth process. The physicochemical properties of Au-Fe3O4 heterostructures have been characterized by X-ray diffraction （XRD）, superconducting quantum interference device （SQUID） magnetometry and UV-vis spectroscopy. The as-synthesized Au-Fe3O4 heterostructures show a red-shift in surface plasmon resonance peak compared with Au NPs and similar magnetic properties to Fe3O4 NPs. The heterojunction effects present in such nanostructures offer the opportunity to tune the irphysicochemical properties. Therefore, this synthesis process can be regarded as an efficient way to fabricate a series of heterostructures for a variety of applications.
基金supported by the National Natural Science Foundation of China(11274033,61227902,11474015)the Research Fund for the Doctoral Program of Higher Education of China(20131102130005)+2 种基金the Fundamental Research Funds for the Central Universities(YWF-14-RSC-119,YWF-15-WLXY-012)China Scholarship Council(201506025052)Beijing Key Discipline Foundation of Condensed Matter Physics
文摘We report a facile method to synthesize dispersed Fe304@C nanoparticles （NPs）. Fe304 NPs were firstly prepared via the high temperature diol thermal decomposition method. Fe304@C NPs were fabricated using glucose as a carbon source by hydro- thermal process. The obtained products were characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, vibrating sample magnetometer （VSM） and Raman spectra. The results indicate that the original shapes and magnetic property of Fe304 NPs can be well preserved. The magnetic particles are well dispersed in the carbon matrix. This strategy would provide an efficient approach for existing applications in Li-ion batteries and drug delivery. Meanwhile, it offers the raw materials to assemble future functional nanometer and micrometer superstructures.
