Metal halide perovskite(MHP)has become one of the most promising materials for photocatalytic CO_(2) reduction owing to the wide light absorption range,negative conduction band position and high reduction ability.Howe...Metal halide perovskite(MHP)has become one of the most promising materials for photocatalytic CO_(2) reduction owing to the wide light absorption range,negative conduction band position and high reduction ability.However,photoreduction of CO_(2) by MHP remains a challenge because of the slow charge separation and transfer.Herein,a cobalt single-atom modified nitrogen-doped graphene(Co-NG)cocatalyst is prepared for enhanced photocatalytic CO_(2) reduction of bismuth-based MHP Cs_(3)Bi_(2)Br_(9).The optimal Cs_(3)Bi_(2)Br_(9)/Co-NG composite exhibits the CO production rate of 123.16μmol g^(-1)h^(-1),which is 17.3 times higher than that of Cs_(3)Bi_(2)Br_(9).Moreover,the Cs_(3)Bi_(2)Br_(9)/Co-NG composite photocatalyst exhibits nearly 100% CO selectivity as well as impressive long-term stability.Charge carrier dynamic characterizations such as Kelvin probe force microscopy(KPFM),single-particle PL microscope and transient absorption(TA)spectroscopy demonstrate the vital role of Co-NG cocatalyst in accelerating the transfer and separation of photogenerated charges and improving photocatalytic performance.The reaction mechanism has been demonstrated by in situ diffuse reflectance infrared Fourier-transform spectroscopy measurement.In addition,in situ X-ray photoelectron spectroscopy test and theoretical calculation reveal the reaction reactive sites and reaction energy barriers,demonstrating that the introduction of Co-NG promotes the formation of ^(*)COOH intermediate,providing sufficient evidence for the highly selective generation of CO.This work provides an effective single-atom-based cocatalyst modification strategy for photocatalytic CO_(2) reduction and is expected to shed light on other photocatalytic applications.展开更多
A modified algorithm of combined GPS/GLONASS precise point positioning （GG-PPP） was developed by decreasing the number of unknowns to be estimated so that accurate position solutions can be achieved in the case of l...A modified algorithm of combined GPS/GLONASS precise point positioning （GG-PPP） was developed by decreasing the number of unknowns to be estimated so that accurate position solutions can be achieved in the case of less number of visible satellites. The system time difference between GPS and GLONASS （STDGG） and zenith tropospheric delay （ZTD） values were firstly estimated in an open sky condition using the traditional GG-PPP algorithm. Then, they were used as a priori known values in the modified algorithm instead of estimating them as unknowns. The proposed algorithm was tested using observations collected at BJFS station in a simulated open-pit mine environment. The results show that the position filter converges much faster to a stable value in all three coordinate components using the modified algorithm than using the traditional algorithm. The modified algorithm achieves higher positioning accuracy as well. The accuracy improvement in the horizontal direction and vertical direction reaches 69% and 95% at a satellite elevation mask angle of 50°, respectively.展开更多
Hydration grossular and hematite monominerals were synthesized. The effects of dissolved organic compounds(including sodium formate, sodium acetate, sodium oxalate, sodium salicylate or disodium phthalate) on the sett...Hydration grossular and hematite monominerals were synthesized. The effects of dissolved organic compounds(including sodium formate, sodium acetate, sodium oxalate, sodium salicylate or disodium phthalate) on the settling performance of hydration grossular or hematite slurries were studied. The settling of the slurries was also investigated with the addition of sodium polyacrylate(PAAS) or hydroxamated polyacrylamide flocculant(HCPAM). The adsorption mechanism of organic compounds on monominerals surfaces was studied by FT-IR and XPS, respectively. A deterioration in settling is observed in order of disodium phthalate>sodium salicylate>sodium oxalate>sodium formate(or sodium acetate). Moreover, PAAS can efficiently eliminate the negative effects of organic compounds on the settling performance of the hydration grossular slurry. HCPAM can efficiently eliminate the negative effects of sodium formate, sodium acetate and sodium oxalate on the settling performance of the hematite slurry, but it only partially improves the settling performance of hematite slurry containing sodium salicylate or disodium phthalate. FT-IR and XPS results show that organic compounds are physically adsorbed on hydration grossular surface, and chemisorptions of organic compounds occur on hematite surface with a bidentate chelating complex.展开更多
Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe...Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe 3d, while that of hexagonal pyrrhotite is from Fe 3d, Fe 3p and S 3s. The hexagonal pyrrhotite is more reactive than monoclinic pyrrhotite because of large density of states near the Fermi level. The hexagonal pyrrhotite shows antiferromagnetism. S—Fe bonds mainly exist in monoclinic pyrrhotite as the covalent bonds, while hexagonal pyrrhotite has no covalency. The main contributions of higest occupied molecular orbital(HOMO) and lowest unoccupied molecular obital(LUMO) for monoclinic pyrrhotite come from S and Fe. The main contribution of HOMO for hexagonal pyrrhotite comes from Fe, while that of LUMO comes from S. The coefficient of Fe atom is much larger than that of S atom of HOMO for hexagonal pyrrhotite, which contributes to the adsorption of Ca OH+ on the surface of hexagonal pyrrhotite when there is lime. As a result, lime has the inhibitory effect on the floatation of hexagonal pyrrhotite and the coefficient of Fe is very close to that of S for monoclinic pyrrhotite. Therefore, the existence of S prevents the adsorption of Ca OH+on the surface of monoclinic pyrrhotite, which leads to less inhibitory effect on the flotation of monoclinic pyrrhotite.展开更多
Effects of multivalent metallic cations, such as Ca2+ and Fe3+, on the flotation of spodumene and beryl were studied. The results show that Fe3+ and Ca2+ exhibit efficient activation on the flotation of spodumene and ...Effects of multivalent metallic cations, such as Ca2+ and Fe3+, on the flotation of spodumene and beryl were studied. The results show that Fe3+ and Ca2+ exhibit efficient activation on the flotation of spodumene and beryl. The ac- tivation of Fe3+ happens quite well within a pH range of 6-9 while the concentration of Fe3+ is 35 mg/L. Efficient acti- vation of Ca2+ takes place over at a pH over 11.6 at a concentration of 140 mg/L. The zeta potential of beryl and spo- dumene shifts slightly to positive values when activated by Ca2+, but markedly by Fe3+. New stretching frequencies of 1594.24 cm-1 and 1587.13 cm-1 have been found in the FTIR spectra of the two minerals after their interaction with Fe3+ and the collector. These new stretching frequencies are the asymmetric stretching frequencies of COO-(carboxyl anion), so thecollector may be chemically absorbed on the surface of Fe3+-activated beryl and spodumene.展开更多
With the increase of mining depth,the effect of rock burst on coal mining is becoming more and more obvious and the rock burst mechanism becomes more and more complicated.Scholars from many countries had put forward d...With the increase of mining depth,the effect of rock burst on coal mining is becoming more and more obvious and the rock burst mechanism becomes more and more complicated.Scholars from many countries had put forward different mechanisms,but no one gave a reasonable explanation to the mechanism of rock burst.In this paper,based on the energy theories,we studied the energy limit equilibrium（ELE） of coal mine rock burst The coal seam with rock burst is divided into energy limit equilibrium zone（ELEZ）（A） and elastic zone（B）;we also determined the position where the rock burst occurs,including the roof and floor of coal seams;in addition,we derived the limit width of ELEZ and the mathematic relationship between the limit width and occurrence mechanism of rock burst：the energy difference function（EDF）,w（x） = w_j - w_p,because first-order derivative w＇（x）,is less than 0.So EDF is a monotonically decreasing function.The graph of the energy difference function was also determined, through which we analysed the occurrence mechanism of rock burst.展开更多
The sulfide passivation film produced on the surface seriously prevents further reaction in the process of using monoclinic pyrrhotite(MPr)to treat heavy metal ions in wastewater.Ultrasonic technology was introduced t...The sulfide passivation film produced on the surface seriously prevents further reaction in the process of using monoclinic pyrrhotite(MPr)to treat heavy metal ions in wastewater.Ultrasonic technology was introduced to assist MPr to recover the copper ions.XPS result proves that CuS products exist on the surface of MPr.XRD and SEM results show that the CuS on the particles’surface is stripped under ultrasonic condition.The kinetics results indicate that the reaction under both conventional and ultrasonic conditions conform to the Avrami model.The reaction process changes from diffusion control to chemical reaction control under the ultrasonic condition as the solid layer is stripped off.The presence of ultrasonic significantly reduces the acidity and temperature required for the reaction and enhances the utilization efficiency of MPr;by controlling the amount of MPr,the removal rates of copper and arsenic in copper smelting dust leachate exceed 99%and 95%,respectively.展开更多
The calculating methods for path number and path matrix of ventilation net- works without unidirectional circuits were introduced,and the inapplicability problem of the matrix algorithm to determine paths in a ventila...The calculating methods for path number and path matrix of ventilation net- works without unidirectional circuits were introduced,and the inapplicability problem of the matrix algorithm to determine paths in a ventilation network with unidirectional circuit was brought forward,and a depth-first search method based algorithm to determine path ma- trix by means of modifying search strategies was discussed.The method is suitable for ventilation networks with unidirectional circuits and ventilation networks without unidirec- tional circuits,moreover the complexity is less than the complexities of matrix based algo- rithms.A series of methods and means to avoid and to reduce the negative effects of un- idirectional circuits such as the optimum of the positions of fan stations,the increase or de-crease of fan station numbers,the optimum regulation of network and the analysis of diagonal structures were put forward.展开更多
Two design axioms and axiomatic approach were discussed. As an example of application, design process of a new style single prop was illustrated in term of axi- oms.
Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-depen...Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-dependent optoelectronic properties and the nanocrystal assembling process,but its detection is still a bit challenging.In this study,we demonstrate that femtosecond sum frequency generation(SFG)vibrational spectroscopy can provide a highly sensitive tool for probing the molecular structures of nanocrystals with a size comparable to the Bohr diameter(∼10 nm)at the single-nanocrystal level.The SFG signals are monitored using the spectral features of the phenyl group in(RMBA)PbBr_(3) and(R-MBA)_(2)PbI_(4) nanocrystals(MBA:methyl-benzyl-ammonium).It is found that the SFG spectra exhibit a strong resonant peak at 3067±3 cm^(−1)(ν2 mode)and a weak shoulder peak at 3045±4 cm^(−1)(ν_(7a) mode)at the ensemble level,whereas a peak of theν2 mode and a peak at 3025±3 cm^(−1)(ν20b mode)at the single-nanocrystal level.The nanocrystals at the single-nanocrystal level tend to lie down on the surface,but stand up as the ensemble number and the averaged sizes increase.This finding may provide valuable information on the structural origins for size-dependent photo-physical properties and photoluminescence blinking dynamics in nanocrystals.展开更多
The occurrence of local circulating ventilation can be caused by many factors, such as the airflow reversion during mine fire,the improper arrangement of local fan or underground fan station and the man-made error inp...The occurrence of local circulating ventilation can be caused by many factors, such as the airflow reversion during mine fire,the improper arrangement of local fan or underground fan station and the man-made error input of raw data before network solving. Once circulating ventilations occur,the corresponding branches in the ventilation network corresponding to the relevant airways in ventilation system form circuits,and all the direc- tions of the branches in the circuits are identical,which is the unidirectional problem in ventilation network.Based on the properties of node adjacent matrix,a serial of mathe- matical computation to node adjacent matrix were performed,and a mathematical model for determining unidirectional circuits based on node adjacent matrix was put forward.展开更多
The phosphate solubilizing characteristics of a strain YC, which was isolated from phosphate mines (Hubei, China), were studied in National Botanical Research Institute’s phosphate (NBRIP) growth medium containing tr...The phosphate solubilizing characteristics of a strain YC, which was isolated from phosphate mines (Hubei, China), were studied in National Botanical Research Institute’s phosphate (NBRIP) growth medium containing tricalcium phosphate (TCP) as sole phosphorus (P) source. The strain YC is identified as Stenotrophomonas maltophilia (S. maltophilia) based upon the results of morphologic, physiological and biochemical characteristics and 16S rRNA sequences analysis. The results show that the strain S. maltophilia YC can solubilize TCP and release soluble P in NBRIP growth medium. A positive correlation between concentration of soluble P and population of the isolate and a negative correlation between concentration of soluble P and pH in the culture medium are observed from statistical analysis results. Moreover, gluconic acid is detected in the culture medium by HPLC analysis. It indicates that the isolate can release gluconic acid during the solubilizing experiment, which causes acidification of the culture medium and then TCP solubilization. S. maltophilia YC has a maximal TCP solubilizing capability when using maltose as carbon source and ammonium nitrate as nitrogen source, respectively, in NBRIP growth medium.展开更多
文摘Metal halide perovskite(MHP)has become one of the most promising materials for photocatalytic CO_(2) reduction owing to the wide light absorption range,negative conduction band position and high reduction ability.However,photoreduction of CO_(2) by MHP remains a challenge because of the slow charge separation and transfer.Herein,a cobalt single-atom modified nitrogen-doped graphene(Co-NG)cocatalyst is prepared for enhanced photocatalytic CO_(2) reduction of bismuth-based MHP Cs_(3)Bi_(2)Br_(9).The optimal Cs_(3)Bi_(2)Br_(9)/Co-NG composite exhibits the CO production rate of 123.16μmol g^(-1)h^(-1),which is 17.3 times higher than that of Cs_(3)Bi_(2)Br_(9).Moreover,the Cs_(3)Bi_(2)Br_(9)/Co-NG composite photocatalyst exhibits nearly 100% CO selectivity as well as impressive long-term stability.Charge carrier dynamic characterizations such as Kelvin probe force microscopy(KPFM),single-particle PL microscope and transient absorption(TA)spectroscopy demonstrate the vital role of Co-NG cocatalyst in accelerating the transfer and separation of photogenerated charges and improving photocatalytic performance.The reaction mechanism has been demonstrated by in situ diffuse reflectance infrared Fourier-transform spectroscopy measurement.In addition,in situ X-ray photoelectron spectroscopy test and theoretical calculation reveal the reaction reactive sites and reaction energy barriers,demonstrating that the introduction of Co-NG promotes the formation of ^(*)COOH intermediate,providing sufficient evidence for the highly selective generation of CO.This work provides an effective single-atom-based cocatalyst modification strategy for photocatalytic CO_(2) reduction and is expected to shed light on other photocatalytic applications.
基金Project(41004011)supported by the National Natural Science Foundation of ChinaProject(2014M550425)supported by the China Postdoctoral Science Foundation
文摘A modified algorithm of combined GPS/GLONASS precise point positioning （GG-PPP） was developed by decreasing the number of unknowns to be estimated so that accurate position solutions can be achieved in the case of less number of visible satellites. The system time difference between GPS and GLONASS （STDGG） and zenith tropospheric delay （ZTD） values were firstly estimated in an open sky condition using the traditional GG-PPP algorithm. Then, they were used as a priori known values in the modified algorithm instead of estimating them as unknowns. The proposed algorithm was tested using observations collected at BJFS station in a simulated open-pit mine environment. The results show that the position filter converges much faster to a stable value in all three coordinate components using the modified algorithm than using the traditional algorithm. The modified algorithm achieves higher positioning accuracy as well. The accuracy improvement in the horizontal direction and vertical direction reaches 69% and 95% at a satellite elevation mask angle of 50°, respectively.
基金Project(51174231)supported by the National Natural Science Foundation of China
文摘Hydration grossular and hematite monominerals were synthesized. The effects of dissolved organic compounds(including sodium formate, sodium acetate, sodium oxalate, sodium salicylate or disodium phthalate) on the settling performance of hydration grossular or hematite slurries were studied. The settling of the slurries was also investigated with the addition of sodium polyacrylate(PAAS) or hydroxamated polyacrylamide flocculant(HCPAM). The adsorption mechanism of organic compounds on monominerals surfaces was studied by FT-IR and XPS, respectively. A deterioration in settling is observed in order of disodium phthalate>sodium salicylate>sodium oxalate>sodium formate(or sodium acetate). Moreover, PAAS can efficiently eliminate the negative effects of organic compounds on the settling performance of the hydration grossular slurry. HCPAM can efficiently eliminate the negative effects of sodium formate, sodium acetate and sodium oxalate on the settling performance of the hematite slurry, but it only partially improves the settling performance of hematite slurry containing sodium salicylate or disodium phthalate. FT-IR and XPS results show that organic compounds are physically adsorbed on hydration grossular surface, and chemisorptions of organic compounds occur on hematite surface with a bidentate chelating complex.
基金Project supported by the Open Foundation of Guangxi Key Laboratory for Advanced Materials and Manufacturing Technology,China
文摘Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe 3d, while that of hexagonal pyrrhotite is from Fe 3d, Fe 3p and S 3s. The hexagonal pyrrhotite is more reactive than monoclinic pyrrhotite because of large density of states near the Fermi level. The hexagonal pyrrhotite shows antiferromagnetism. S—Fe bonds mainly exist in monoclinic pyrrhotite as the covalent bonds, while hexagonal pyrrhotite has no covalency. The main contributions of higest occupied molecular orbital(HOMO) and lowest unoccupied molecular obital(LUMO) for monoclinic pyrrhotite come from S and Fe. The main contribution of HOMO for hexagonal pyrrhotite comes from Fe, while that of LUMO comes from S. The coefficient of Fe atom is much larger than that of S atom of HOMO for hexagonal pyrrhotite, which contributes to the adsorption of Ca OH+ on the surface of hexagonal pyrrhotite when there is lime. As a result, lime has the inhibitory effect on the floatation of hexagonal pyrrhotite and the coefficient of Fe is very close to that of S for monoclinic pyrrhotite. Therefore, the existence of S prevents the adsorption of Ca OH+on the surface of monoclinic pyrrhotite, which leads to less inhibitory effect on the flotation of monoclinic pyrrhotite.
基金Project 2005CB623701 supported by the National Key Basic Research & Development Program (973) of China
文摘Effects of multivalent metallic cations, such as Ca2+ and Fe3+, on the flotation of spodumene and beryl were studied. The results show that Fe3+ and Ca2+ exhibit efficient activation on the flotation of spodumene and beryl. The ac- tivation of Fe3+ happens quite well within a pH range of 6-9 while the concentration of Fe3+ is 35 mg/L. Efficient acti- vation of Ca2+ takes place over at a pH over 11.6 at a concentration of 140 mg/L. The zeta potential of beryl and spo- dumene shifts slightly to positive values when activated by Ca2+, but markedly by Fe3+. New stretching frequencies of 1594.24 cm-1 and 1587.13 cm-1 have been found in the FTIR spectra of the two minerals after their interaction with Fe3+ and the collector. These new stretching frequencies are the asymmetric stretching frequencies of COO-(carboxyl anion), so thecollector may be chemically absorbed on the surface of Fe3+-activated beryl and spodumene.
基金Financial support for this project,provided by the Key Basic Research Program of China(No.2006CB202200)the National Major Project of Ministry of Education(No.304005)the Program for Changjiang Scholars and Innovative Research Team in University of China(No.IRT0656)
文摘With the increase of mining depth,the effect of rock burst on coal mining is becoming more and more obvious and the rock burst mechanism becomes more and more complicated.Scholars from many countries had put forward different mechanisms,but no one gave a reasonable explanation to the mechanism of rock burst.In this paper,based on the energy theories,we studied the energy limit equilibrium（ELE） of coal mine rock burst The coal seam with rock burst is divided into energy limit equilibrium zone（ELEZ）（A） and elastic zone（B）;we also determined the position where the rock burst occurs,including the roof and floor of coal seams;in addition,we derived the limit width of ELEZ and the mathematic relationship between the limit width and occurrence mechanism of rock burst：the energy difference function（EDF）,w（x） = w_j - w_p,because first-order derivative w＇（x）,is less than 0.So EDF is a monotonically decreasing function.The graph of the energy difference function was also determined, through which we analysed the occurrence mechanism of rock burst.
基金the National Key Scientific Research Project,China(Nos.2018YFC1901601,2018YFC1901602)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2021zzts0307)+2 种基金the National Natural Science Foundation of China(No.51804340)the Innovation-driven Plan of Central South University,China(No.2018CX036)the Collaborative Innovation Center for Clean and Efficient Utilization of Strategic Metal Mineral Resources,China,and Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-containing Mineral Resources,China(No.2018TP1002).
文摘The sulfide passivation film produced on the surface seriously prevents further reaction in the process of using monoclinic pyrrhotite(MPr)to treat heavy metal ions in wastewater.Ultrasonic technology was introduced to assist MPr to recover the copper ions.XPS result proves that CuS products exist on the surface of MPr.XRD and SEM results show that the CuS on the particles’surface is stripped under ultrasonic condition.The kinetics results indicate that the reaction under both conventional and ultrasonic conditions conform to the Avrami model.The reaction process changes from diffusion control to chemical reaction control under the ultrasonic condition as the solid layer is stripped off.The presence of ultrasonic significantly reduces the acidity and temperature required for the reaction and enhances the utilization efficiency of MPr;by controlling the amount of MPr,the removal rates of copper and arsenic in copper smelting dust leachate exceed 99%and 95%,respectively.
文摘The calculating methods for path number and path matrix of ventilation net- works without unidirectional circuits were introduced,and the inapplicability problem of the matrix algorithm to determine paths in a ventilation network with unidirectional circuit was brought forward,and a depth-first search method based algorithm to determine path ma- trix by means of modifying search strategies was discussed.The method is suitable for ventilation networks with unidirectional circuits and ventilation networks without unidirec- tional circuits,moreover the complexity is less than the complexities of matrix based algo- rithms.A series of methods and means to avoid and to reduce the negative effects of un- idirectional circuits such as the optimum of the positions of fan stations,the increase or de-crease of fan station numbers,the optimum regulation of network and the analysis of diagonal structures were put forward.
文摘Two design axioms and axiomatic approach were discussed. As an example of application, design process of a new style single prop was illustrated in term of axi- oms.
基金supported by the National Key Research and Development Program of China(No.2017YFA0303500,No.2018YFA0208702)the National Natural Science Foundation of China(No.21925302,No.21873090,and No.21633007)Anhui Initiative in Quantum Information Technologies(No.AHY090000)。
文摘Determination of molecular structures of organicinorganic hybrid perovskite(OIHP)nanocrystals at the single-nanocrystal and ensemble levels is essential to understanding the mechanisms responsible for their size-dependent optoelectronic properties and the nanocrystal assembling process,but its detection is still a bit challenging.In this study,we demonstrate that femtosecond sum frequency generation(SFG)vibrational spectroscopy can provide a highly sensitive tool for probing the molecular structures of nanocrystals with a size comparable to the Bohr diameter(∼10 nm)at the single-nanocrystal level.The SFG signals are monitored using the spectral features of the phenyl group in(RMBA)PbBr_(3) and(R-MBA)_(2)PbI_(4) nanocrystals(MBA:methyl-benzyl-ammonium).It is found that the SFG spectra exhibit a strong resonant peak at 3067±3 cm^(−1)(ν2 mode)and a weak shoulder peak at 3045±4 cm^(−1)(ν_(7a) mode)at the ensemble level,whereas a peak of theν2 mode and a peak at 3025±3 cm^(−1)(ν20b mode)at the single-nanocrystal level.The nanocrystals at the single-nanocrystal level tend to lie down on the surface,but stand up as the ensemble number and the averaged sizes increase.This finding may provide valuable information on the structural origins for size-dependent photo-physical properties and photoluminescence blinking dynamics in nanocrystals.
基金National Nature Science Foundation of China(50704019)Nature Science Foundation of Liaoning Province(20062204)
文摘The occurrence of local circulating ventilation can be caused by many factors, such as the airflow reversion during mine fire,the improper arrangement of local fan or underground fan station and the man-made error input of raw data before network solving. Once circulating ventilations occur,the corresponding branches in the ventilation network corresponding to the relevant airways in ventilation system form circuits,and all the direc- tions of the branches in the circuits are identical,which is the unidirectional problem in ventilation network.Based on the properties of node adjacent matrix,a serial of mathe- matical computation to node adjacent matrix were performed,and a mathematical model for determining unidirectional circuits based on node adjacent matrix was put forward.
基金Project(2004CB619201) supported by the Major State Basic Research and Development Program of ChinaProject(Z200515002) supported by the Key Project Foundation of the Education Department of Hubei Province, China+1 种基金Project(GCP200801) supported by the Open Research Fund of Key Laboratory for Green Chemical Process of Ministry of Education, ChinaProject(Q200811) supported by the Youths Science Foundation of Wuhan Institute of Technology, China
文摘The phosphate solubilizing characteristics of a strain YC, which was isolated from phosphate mines (Hubei, China), were studied in National Botanical Research Institute’s phosphate (NBRIP) growth medium containing tricalcium phosphate (TCP) as sole phosphorus (P) source. The strain YC is identified as Stenotrophomonas maltophilia (S. maltophilia) based upon the results of morphologic, physiological and biochemical characteristics and 16S rRNA sequences analysis. The results show that the strain S. maltophilia YC can solubilize TCP and release soluble P in NBRIP growth medium. A positive correlation between concentration of soluble P and population of the isolate and a negative correlation between concentration of soluble P and pH in the culture medium are observed from statistical analysis results. Moreover, gluconic acid is detected in the culture medium by HPLC analysis. It indicates that the isolate can release gluconic acid during the solubilizing experiment, which causes acidification of the culture medium and then TCP solubilization. S. maltophilia YC has a maximal TCP solubilizing capability when using maltose as carbon source and ammonium nitrate as nitrogen source, respectively, in NBRIP growth medium.
