Mixed halide perovskites(MHPs)are a class of semiconductor materials with great promise for many optoelectronic applications due to their outstanding photophysical properties.Understanding and tailoring the photogener...Mixed halide perovskites(MHPs)are a class of semiconductor materials with great promise for many optoelectronic applications due to their outstanding photophysical properties.Understanding and tailoring the photogenerated carrier dynamics is essential for further improvement of perovskite performance.Herein,we report a study about the carrier transport and interfacial charge transfer dynamics in Br-gradient MAPbI_(3-x)Br_(x) perovskite thin films prepared by surface ion-exchange method.Driven by the bandgap gradient in MAPbI_(3-x)Br_(x) films,the accelerated internal hole transport and enhanced interfacial extraction efficiency were both observed.Meanwhile,the interfacial electron transfer was also found to be evidently facilitated due to the surface modification during post-treatment.Our findings suggest the possibility of simultaneous acceleration of interfacial electron and hole transfer processes in halide perovskite films via surface post-treatment technique,which is of great importance in further improving the power conversion efficiency of perovskite solar cells.展开更多
基金financial support from the Ministry of Science and Technology of China(No.2018YFA0208704 and No.2016YFA0200602)the National Natural Science Foundation of China(No.21725305)financial support from the National Natural Science Foundation of China(No.21773237)。
文摘Mixed halide perovskites(MHPs)are a class of semiconductor materials with great promise for many optoelectronic applications due to their outstanding photophysical properties.Understanding and tailoring the photogenerated carrier dynamics is essential for further improvement of perovskite performance.Herein,we report a study about the carrier transport and interfacial charge transfer dynamics in Br-gradient MAPbI_(3-x)Br_(x) perovskite thin films prepared by surface ion-exchange method.Driven by the bandgap gradient in MAPbI_(3-x)Br_(x) films,the accelerated internal hole transport and enhanced interfacial extraction efficiency were both observed.Meanwhile,the interfacial electron transfer was also found to be evidently facilitated due to the surface modification during post-treatment.Our findings suggest the possibility of simultaneous acceleration of interfacial electron and hole transfer processes in halide perovskite films via surface post-treatment technique,which is of great importance in further improving the power conversion efficiency of perovskite solar cells.
