The drying kinetics of Roselle (Hibiscus sabdariffa L) of variety Terengganu (UMKL-1) and the quality attribution of Roselle were studied. The experiments were conducted using four different drying methods, includ...The drying kinetics of Roselle (Hibiscus sabdariffa L) of variety Terengganu (UMKL-1) and the quality attribution of Roselle were studied. The experiments were conducted using four different drying methods, including solar greenhouse drying (SD), solar greenhouse with intermittent heat pump drying (SIHP), hot air drying (HA) and heat pump drying (HP). Among the four drying methods, HP achieved the highest drying rate at a range from 0.054 g H20-(g DM)-1. rain-1 to 0.212 g H20-(g DM)-1. rain 1 while SD had the lowest drying rate, measured at 0.042 g H2O. (g DM) 1.min- 1. The analysis on colour kinetics revealed that there is no significant colour loss (p 〉 0.05) observed from HP's dried Roselle. Greater amount of flavonoid compounds i.e. protocatechuic acid was found in SD and SIHP dried finished product whereas HP's dried Roselle contains higher percentage of catechin as compared to other drying methods.展开更多
The current work is focused on the study of the bio-sorption of hexavalent chromium from aqueous solution using sisal natural fiber(Agave sisalana) treated by various chelating agents(ligands) such as urea(UR),thiocar...The current work is focused on the study of the bio-sorption of hexavalent chromium from aqueous solution using sisal natural fiber(Agave sisalana) treated by various chelating agents(ligands) such as urea(UR),thiocarbamide(TC), ethylenediaminetetraacetic acid(EDTA), and diphenyl carbazide(DCZ). The fiber treatments were investigated using Fourier Transform Infrared Spectroscopy(FTIR) and Scanning electron microscope(SEM). The kinetics of chromium bio-sorption was studied in batch presses under the effect of some physicochemical factors such as the nature of chelating agent(F@UR, F@TC, F@DCZ, and F@EDTA),adsorbent dose(2–10 g·L^(-1)), chromium initial concentration(100–500 mg·L^(-1)), solution pH(1–6), and batch temperature(20 ℃–50 ℃). This study resulted in an optimum adsorption at a chromium initial concentration of 100 mg·L^(-1), at pH 2, and at 20 ℃. The obtained results showed clearly that the treatment with chelating agent boosts the adsorptive capacity of A. sisalana fibers Cr(VI) 10.9 mg·g^(-1) to 58.6 mg·g^(-1). The modeling study showed that the adsorption kinetics obey the pseudo-second-order model, with an R2 in the range of 0.991 and 0.999. The bio-sorption isotherms followed the Langmuir model; the maximum uptake capacity of(F@N, F@UR,F@TC, F@DCZ, and F@EDTA) was found to be respectively, 12.3 mg·g^(-1), 25.33 mg·g^(-1), 28.73 mg·g^(-1),42.54 mg·g^(-1), and 61.45 mg·g^(-1). The determined adsorption thermodynamics parameters such as enthalpy,free energy, and entropy showed that the adsorption process is exothermic, spontaneous, and has a stable configuration.展开更多
Modulation in the aggregation behavior of bio-surfactants (bile salts), sodium cholate (NaC) and sodium deoxycholate (NaDC) in aqueous solutions of carbohydrates (galactose and lactose) have been investigated ...Modulation in the aggregation behavior of bio-surfactants (bile salts), sodium cholate (NaC) and sodium deoxycholate (NaDC) in aqueous solutions of carbohydrates (galactose and lactose) have been investigated by measuring the density (ρ), speed of sound (u) and viscosity (η) of the mixtures at different temperatures 293.15, 298.15, 303.15, 308.15 and 313.15 K. The density and speed of sound data have been used to calculate various volumetric and compressibility parameters such as apparent molar volume (Vφ), isentropic compressibil- ity (κs), apparent molar adiabatic compression (κs,φ) to get a better insight into the micellization mechanism of bile salts. Further, the viscosity data have been studied in the light of relative viscosity (ηr) and viscous relaxation time (τ). Some derived parameters such as free volume (νf), internal pressure (πi) and molar cohesive energy (MCE) of NaC and NaDC in aqueous solution of saccharides have also been calculated from viscosity data in con- junction with density and speed of sound values. All the calculated and derived parameters provide qualitative information regarding the nature of interactions i.e. solute-solute, solute-solvent and solvent-solvent in the solution.展开更多
Time has multiple aspects and is difficult to define as one unique entity, which therefore led to multiple interpretations in physics and philosophy. However, if the perception of time is considered as a composite tim...Time has multiple aspects and is difficult to define as one unique entity, which therefore led to multiple interpretations in physics and philosophy. However, if the perception of time is considered as a composite time concept, it can be decomposed into basic invariable components for the perception of progressive and support-fixed time and into secondary components with possible association to unit-defined time or tense. Progressive time corresponds to Bergson's definition of duration without boundaries, which cannot be divided for measurements. Time periods are already lying in the past and fixed on different kinds of support. The human memory is the first automatic support, but any other support suitable for time registration can also be considered. The true reproduction of original time from any support requires conditions identical to the initial conditions, if not time reproduction becomes artificially modified as can be seen with a film. Time reproduction can be artificially accelerated, slowed down, extended or diminished, and also inverted from the present to the past, which only depends on the manipulation of the support, to which time is firmly linked. Tense associated to progressive and support fixed time is a psychological property directly dependent on an observer, who judges his present as immediate, his past as finished and his future as uncertain. Events can be secondarily associated to the tenses of an observer. Unit-defined time is essential for physics and normal live and is obtained by comparison of support-fixed time to systems with regular motions, like clocks. The association of time perception to time units can also be broken. Einstein's time units became relative, in quantum mechanics, some physicist eliminated time units, others maintained them. Nevertheless, even the complete elimination of time units is not identical to timelessness, since the psychological perception of progressive and support-fixed time still remains and cannot be ignored. It is not seizable by physical methods, but experienced by everybody in everyday life. Contemporary physics can only abandon the association of time units or tenses to the basic components in perceived time.展开更多
The method for pyrolysis of biomass to manufacture hydrocarbon-rich fuel remains challenging in terms of conversion of multifunctional biomass with high oxygen content and low thermal stability into a high-quality com...The method for pyrolysis of biomass to manufacture hydrocarbon-rich fuel remains challenging in terms of conversion of multifunctional biomass with high oxygen content and low thermal stability into a high-quality compound, featuring high content of hydrocarbons, low oxygen content, few functional groups, and high thermal stability. This study offers a promising prospect to derive hydrocarbon-rich oil through microwave-assisted fast catalytic pyrolysis by improving the effective hydrogen to carbon ratio(H/Ceff) of the raw materials. The proposed technique can promote the production of high-quality bio-oil through the molecular sieve catalyzed reduction of oxygenated compounds and mutagenic polyaromatic hydrocarbons. This work aims to review and summarize the research progress on microwave copyrolysis and microwave catalytic copyrolysis to demonstrate their benefits on enhancement of bio-oils derived from the biomass. This review focuses on the potential of optimizing the H/Ceff ratio, the microwave absorbent, and the HZSM-5 catalyst during the microwave copyrolysis to produce the valuable liquid fuel. This paper also proposes future directions for the use of this technique to obtain high yields of bio-oils.展开更多
The objective of this study was to isolate Bacillus subtilis produced Bacteriocin from Khmer traditional fermented soybean to control the growth of pathogenic bacteria from 120 SIENG samples from 9 different loca...The objective of this study was to isolate Bacillus subtilis produced Bacteriocin from Khmer traditional fermented soybean to control the growth of pathogenic bacteria from 120 SIENG samples from 9 different local open markets in Phnom Penh, 1 local open market and 2 local producers in Kandal province in Cambodia. 119 out of 120 samples were positive with Bacillus subtilis strains. Fifteen of these isolated strains exhibited antimicrobial activity to Lactobacillus plantarum by agar well diffusion assay and one of them (CeM6-7 strain) exhibited strongest antimicrobial activity. The filtered supernatant of this strain also suppressed the growth of several Gram-positive pathogens (such as Staphylococcus aureus) or lactic acid bacteria in broth. The filtrate could also suppress the growth of L. plantarum inoculated into soymilk. Antimicrobial B. subtilis strain CeM6-7 is thought to be applicable for making a starter culture to produce much safe fermented soybean foods by suppressing the growth of naturally contaminated B. cereus or S. aureus during production. In addition, the use of this starter culture may contribute to prevent spoilage or quality loss of soybean products caused by the over growth lactic acid bacteria or other Gram-positive bacteria.展开更多
Quantum mechanics has some weird aspects, which we simply have to accept, according to Tegmark. However, approaching this issue from a bio-psychological perspective allows for an alternative interpretation that avoids...Quantum mechanics has some weird aspects, which we simply have to accept, according to Tegmark. However, approaching this issue from a bio-psychological perspective allows for an alternative interpretation that avoids this supposedly inherent weirdness. Physical laws are established based on repeated observations or measurements, which involve sense organs. Our capacity for memorization and abstract reflection allows us to draw conclusions on physical reality, which can thus be represented with mathematical formalism. Therefore, physical laws are dependent on pure bio-psychological functions. If quantum mechanics is seen in the bio-psychological context, normal mental functions might explain phenomena such as the collapse of the wave function. If events of interest occurred regularly, similar to classical physics, the same pattern of regular events would be anticipated in the future. Conversely, if events that occurred in the past were irregular, like in quantum mechanics, they would also evolve in an irregular manner in the future. Prediction of irregular behavior requires the ability to imagine multiple possibilities in a kind of mental superposition. Only when one of the imagined possibilities is realized, the mental superposition of the future will collapse to one observable behavior occurring in the present. However, in mental representation, similar to classical physical formalism, some aspects of reality can be lost. When time and space coordinates are replaced by calculated time intervals and spatial distances, time periods and spatial lengths become independent of their initial reference frames. Consequently, the concepts of past, present, and future become irrelevant for time intervals. In quantum mechanics, as well as in mental imagination of potentiality, the notions of the unity of one space for one time and the time arrow are also eliminated. This analogy suggests that physical formalism does not correspond to independent physical reality, but rather to mental functions, which allow establishing a mathematical model of extra-mental reality. If quantum mechanics is conceived as mental potentiality for modeling physical reality, the weird aspect of the collapse of superposition disappears and becomes a simple transition from imagined potentiality in mental representation to observed reality, which could explain the measurement problem.展开更多
Objective: The aim of the research was to investigate efficacy of dried bio-floc supplemented with immuno-stimulants as beta-glucan and nucleotide on mortality rate and relative percent survival (RPS) of tilapia in...Objective: The aim of the research was to investigate efficacy of dried bio-floc supplemented with immuno-stimulants as beta-glucan and nucleotide on mortality rate and relative percent survival (RPS) of tilapia infected with Flavobacterium columnare, VETSV01. Materials and Methods: A research was performed in 1-inch long tilapia stimulated its immunity by infection with Flavobacterium columnare, VETSV01. Pathogenesis of 0.2 mL Flavobacterium columnare, VETSV01 in the range of 10^2-10^8 mL-1 fish^-1 was injected into its intraperitoneal injection and intramuscular injection and suitable concentrations were screened to obtain for further experiment in a late restage. Based on data of minimal concentration, 50% mortality rate was caused and it was found the concentration of 108 mL^-1 fish^-1 caused 100% mortality rate and no lethal rate was found in other concentrations. Afterwards, efficacy of bio-floc sediment on survival rate of Tilapia infected with Flavobacterium columnare, VETSV01 was examined. Completely randomized design was employed and experiments were divided into 4 treatment: (1) contxol-commercial feed only, (2) commercial feed attached with dried bio-floc, (3) commercial feed attached with bio-floc and beta-glucan and (4) commercial feed attached with bio-floc and nucleotide. Experiment design was performed as 3 replicates with 10 fishes/replicates in 24 inch glass aquarium. Analysis of difference was performed and determination of mean differences of mortality rate mad relative percent survival was done through Duncan's Multiple Range Test (p 〈 0.05). Results and Discussions: It was demonstrated feeding tilapia with commercial feed in combination with dried bio-floc with or without supplementation of 2 immuno-stimulants could lead to 100% survival rate and 100% relative percent survival rate and it was statistically significant different (p 〈 0.05) compared to control group. Bio-floc product supplemented with beta glucan or nucleotide could effectively stimulate immunity against Flavobacterium columnare, VETSV01 and such high effective performance is viewed as a promising potential product to be further developed and practically employed for sake of aquaculture industry in the near future.展开更多
The development of bio-based liquid fuel is important for the substitution of transport fuels.Fast pyrolysis can efficiently convert solid biomass wastes into bio-oil.However,its poor properties limit its high-quality...The development of bio-based liquid fuel is important for the substitution of transport fuels.Fast pyrolysis can efficiently convert solid biomass wastes into bio-oil.However,its poor properties limit its high-quality utilization and therefore upgrading is required.Because of the complicated composition,upgrading bio-oil by a single technique faces many problems,such as low conversion efficiency and severe catalyst deactivation.These problems can be largely overcome by graded upgrading based on separation,in which bio-oil is first separated into several fractions and then these fractions are upgraded by different techniques.This paper is a review of the current states in the upgrading of bio-oil fractions obtained from water extraction and vacuum or molecular distillation.The corresponding upgrading techniques include esterification,steam reforming,catalytic cracking,and hydrodeoxygenation. For each upgrading technique,the corresponding conversion behaviors and mechanisms of typical model compounds in bio-oil fractions are first outlined,and then the applications of this technique in actual bio-oil fraction upgrading are introduced.The graded upgrading of bio-oil based on separation will have more potential and become more economical if various separation techniques,upgrading methods,and the extraction of valuable chemicals can be combined.展开更多
Bio-based elastomer poly(diethyl itaconate-co-isoprene)(PDEII) was designed and synthesized by redox-initiated emulsion polymerization from diethyl itaconate and isoprene with mass ratio of 20:80, 40:60, 60:40 and 80:...Bio-based elastomer poly(diethyl itaconate-co-isoprene)(PDEII) was designed and synthesized by redox-initiated emulsion polymerization from diethyl itaconate and isoprene with mass ratio of 20:80, 40:60, 60:40 and 80:20. The number-average molecular weights of PDEII exceeded 140000 with relatively high yields. The physical properties of PDEII, such as glass transition temperatures and thermostability, were comparable with conventional synthetic elastomers and can be readily tuned by varying the ratio of diethyl itaconate to isoprene. The interaction between silica and PDEII macromolecules was effectively enhanced with the increase of diethyl itaconate content by endowing high polarity. The oil-resistance relevant properties of silica/PDEII80(80% diethyl itaconate, 20% isoprene) such as retention of tensile strength, retention of elongation at break and change in volume even surpass those of silica/NBR 240 S after soaked in ASTM 3# oil at different temperatures.展开更多
Knowledge on the interactions between engineered nanomaterials(ENMs) and biological systems is critical both for the assessment of biological effects of ENMs and for the rational design of ENM-based products. However,...Knowledge on the interactions between engineered nanomaterials(ENMs) and biological systems is critical both for the assessment of biological effects of ENMs and for the rational design of ENM-based products. However, probing the events that occur at the nano-bio interface remains extremely challenging due to their complex and dynamic nature. So far, the understanding of mechanisms underlying nano-bio interactions has been mainly limited by the lack of proper analytical techniques with sufficient sensitivity, selectivity and resolution for characterization of nano-bio interface events. Moreover, many classic bioanalytical methods are not suitable for direct measurement of nano-bio interface interactions. These have made establishing analytical methodologies for systematic and comprehensive study of nano-bio interface one of the most focused areas in nanobiology. In this review we have discussed some representative developments regarding analytical techniques for nano-bio interface characterization, including the improvements of traditional methods and the emergence of powerful new technologies. These developments have allowed ultrasensitive, real-time analysis of interactions between ENMs and biomolecules, transformations of ENMs in biological environment, and impacts of ENMs on living systems on molecular or cellular level.展开更多
In this study, hybrid computational frameworks are developed for active noise control(ANC) systems using an evolutionary computing technique based on genetic algorithms(GAs) and interior-point method(IPM), follo...In this study, hybrid computational frameworks are developed for active noise control(ANC) systems using an evolutionary computing technique based on genetic algorithms(GAs) and interior-point method(IPM), following an integrated approach, GA-IPM. Standard ANC systems are usually implemented with the filtered extended least mean square algorithm for optimization of coefficients for the linear finite-impulse response filter, but are likely to become trapped in local minima(LM). This issue is addressed with the proposed GA-IPM computing approach which is considerably less prone to the LM problem. Also, there is no requirement to identify a secondary path for the ANC system used in the scheme. The design method is evaluated using an ANC model of a headset with sinusoidal, random, and complex random noise interferences under several scenarios based on linear and nonlinear primary and secondary paths. The accuracy and convergence of the proposed scheme are validated based on the results of statistical analysis of a large number of independent runs of the algorithm.展开更多
In this work, biologically-inspired computing framework is developed for HIV infection of CD4+ T-cell model using feed-forward artificial neural networks (ANNs), genetic algorithms (GAs), sequential quadratic pro...In this work, biologically-inspired computing framework is developed for HIV infection of CD4+ T-cell model using feed-forward artificial neural networks (ANNs), genetic algorithms (GAs), sequential quadratic programming (SQP) and hybrid approach based on GA-SQP. The mathematical model for HIV infection of CD4+ T-cells is represented with the help of initial value problems (IVPs) based on the system of ordinary differential equations (ODEs). The ANN model for the system is constructed by exploiting its strength of universal approximation. An objective function is developed for the system through unsupervised error using ANNs in the mean square sense. Training with weights of ANNs is carried out with GAs for effective global search supported with SQP for efficient local search. The proposed scheme is evaluated on a number of scenarios for the HIV infection model by taking the different levels for infected cells, natural substitution rates of uninfected cells, and virus particles. Comparisons of the approximate solutions are made with results of Adams numerical solver to establish the correctness of the proposed scheme. Accuracy and convergence of the approach are validated through the results of statistical analysis based on the sufficient large number of independent runs.展开更多
We provide some sharp criteria for studying the ergodicity and asymptotic stability of general Feller semigroups on Polish metric spaces. As an application, the 2D Navier-Stokes equations with degenerate stochastic fo...We provide some sharp criteria for studying the ergodicity and asymptotic stability of general Feller semigroups on Polish metric spaces. As an application, the 2D Navier-Stokes equations with degenerate stochastic forcing will be simply revisited.展开更多
基金Supported by the Ministry of Agriculture and Agro-Based Industry(MOA),Malaysia(NER30001)
文摘The drying kinetics of Roselle (Hibiscus sabdariffa L) of variety Terengganu (UMKL-1) and the quality attribution of Roselle were studied. The experiments were conducted using four different drying methods, including solar greenhouse drying (SD), solar greenhouse with intermittent heat pump drying (SIHP), hot air drying (HA) and heat pump drying (HP). Among the four drying methods, HP achieved the highest drying rate at a range from 0.054 g H20-(g DM)-1. rain-1 to 0.212 g H20-(g DM)-1. rain 1 while SD had the lowest drying rate, measured at 0.042 g H2O. (g DM) 1.min- 1. The analysis on colour kinetics revealed that there is no significant colour loss (p 〉 0.05) observed from HP's dried Roselle. Greater amount of flavonoid compounds i.e. protocatechuic acid was found in SD and SIHP dried finished product whereas HP's dried Roselle contains higher percentage of catechin as compared to other drying methods.
文摘The current work is focused on the study of the bio-sorption of hexavalent chromium from aqueous solution using sisal natural fiber(Agave sisalana) treated by various chelating agents(ligands) such as urea(UR),thiocarbamide(TC), ethylenediaminetetraacetic acid(EDTA), and diphenyl carbazide(DCZ). The fiber treatments were investigated using Fourier Transform Infrared Spectroscopy(FTIR) and Scanning electron microscope(SEM). The kinetics of chromium bio-sorption was studied in batch presses under the effect of some physicochemical factors such as the nature of chelating agent(F@UR, F@TC, F@DCZ, and F@EDTA),adsorbent dose(2–10 g·L^(-1)), chromium initial concentration(100–500 mg·L^(-1)), solution pH(1–6), and batch temperature(20 ℃–50 ℃). This study resulted in an optimum adsorption at a chromium initial concentration of 100 mg·L^(-1), at pH 2, and at 20 ℃. The obtained results showed clearly that the treatment with chelating agent boosts the adsorptive capacity of A. sisalana fibers Cr(VI) 10.9 mg·g^(-1) to 58.6 mg·g^(-1). The modeling study showed that the adsorption kinetics obey the pseudo-second-order model, with an R2 in the range of 0.991 and 0.999. The bio-sorption isotherms followed the Langmuir model; the maximum uptake capacity of(F@N, F@UR,F@TC, F@DCZ, and F@EDTA) was found to be respectively, 12.3 mg·g^(-1), 25.33 mg·g^(-1), 28.73 mg·g^(-1),42.54 mg·g^(-1), and 61.45 mg·g^(-1). The determined adsorption thermodynamics parameters such as enthalpy,free energy, and entropy showed that the adsorption process is exothermic, spontaneous, and has a stable configuration.
基金S.Chauhan and Maninder Kaur thank UGC,New Delhi for financial assistance under the project(F.No.42-249/2013/SR)award of Senior Research Fellowship(No.F.17-40/2008(SA-1)dated 31.07.2014)+1 种基金Himachal Pradesh University for Senior Research Fellowship(F.No.1-3/2013-HPU(DS)5111)Financial support from UGC-SAP(DRS-I)(No.F.540/3/DRS/2010(SAP-1))to Department of Chemistry,HPU
文摘Modulation in the aggregation behavior of bio-surfactants (bile salts), sodium cholate (NaC) and sodium deoxycholate (NaDC) in aqueous solutions of carbohydrates (galactose and lactose) have been investigated by measuring the density (ρ), speed of sound (u) and viscosity (η) of the mixtures at different temperatures 293.15, 298.15, 303.15, 308.15 and 313.15 K. The density and speed of sound data have been used to calculate various volumetric and compressibility parameters such as apparent molar volume (Vφ), isentropic compressibil- ity (κs), apparent molar adiabatic compression (κs,φ) to get a better insight into the micellization mechanism of bile salts. Further, the viscosity data have been studied in the light of relative viscosity (ηr) and viscous relaxation time (τ). Some derived parameters such as free volume (νf), internal pressure (πi) and molar cohesive energy (MCE) of NaC and NaDC in aqueous solution of saccharides have also been calculated from viscosity data in con- junction with density and speed of sound values. All the calculated and derived parameters provide qualitative information regarding the nature of interactions i.e. solute-solute, solute-solvent and solvent-solvent in the solution.
文摘Time has multiple aspects and is difficult to define as one unique entity, which therefore led to multiple interpretations in physics and philosophy. However, if the perception of time is considered as a composite time concept, it can be decomposed into basic invariable components for the perception of progressive and support-fixed time and into secondary components with possible association to unit-defined time or tense. Progressive time corresponds to Bergson's definition of duration without boundaries, which cannot be divided for measurements. Time periods are already lying in the past and fixed on different kinds of support. The human memory is the first automatic support, but any other support suitable for time registration can also be considered. The true reproduction of original time from any support requires conditions identical to the initial conditions, if not time reproduction becomes artificially modified as can be seen with a film. Time reproduction can be artificially accelerated, slowed down, extended or diminished, and also inverted from the present to the past, which only depends on the manipulation of the support, to which time is firmly linked. Tense associated to progressive and support fixed time is a psychological property directly dependent on an observer, who judges his present as immediate, his past as finished and his future as uncertain. Events can be secondarily associated to the tenses of an observer. Unit-defined time is essential for physics and normal live and is obtained by comparison of support-fixed time to systems with regular motions, like clocks. The association of time perception to time units can also be broken. Einstein's time units became relative, in quantum mechanics, some physicist eliminated time units, others maintained them. Nevertheless, even the complete elimination of time units is not identical to timelessness, since the psychological perception of progressive and support-fixed time still remains and cannot be ignored. It is not seizable by physical methods, but experienced by everybody in everyday life. Contemporary physics can only abandon the association of time units or tenses to the basic components in perceived time.
基金the financial support from the National Natural Science Foundation of China (No. 21766019, 21466022)the Key Research and Development Program of Jiangxi Province(20171BBF60023)+2 种基金the International Science&Technology Cooperation Project of China(2015DFA60170-4)the Science and Technology Research Project of Jiangxi Province Education Department(No.GJJ150213)the Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development Program (No. Y707sb1001)”
文摘The method for pyrolysis of biomass to manufacture hydrocarbon-rich fuel remains challenging in terms of conversion of multifunctional biomass with high oxygen content and low thermal stability into a high-quality compound, featuring high content of hydrocarbons, low oxygen content, few functional groups, and high thermal stability. This study offers a promising prospect to derive hydrocarbon-rich oil through microwave-assisted fast catalytic pyrolysis by improving the effective hydrogen to carbon ratio(H/Ceff) of the raw materials. The proposed technique can promote the production of high-quality bio-oil through the molecular sieve catalyzed reduction of oxygenated compounds and mutagenic polyaromatic hydrocarbons. This work aims to review and summarize the research progress on microwave copyrolysis and microwave catalytic copyrolysis to demonstrate their benefits on enhancement of bio-oils derived from the biomass. This review focuses on the potential of optimizing the H/Ceff ratio, the microwave absorbent, and the HZSM-5 catalyst during the microwave copyrolysis to produce the valuable liquid fuel. This paper also proposes future directions for the use of this technique to obtain high yields of bio-oils.
文摘The objective of this study was to isolate Bacillus subtilis produced Bacteriocin from Khmer traditional fermented soybean to control the growth of pathogenic bacteria from 120 SIENG samples from 9 different local open markets in Phnom Penh, 1 local open market and 2 local producers in Kandal province in Cambodia. 119 out of 120 samples were positive with Bacillus subtilis strains. Fifteen of these isolated strains exhibited antimicrobial activity to Lactobacillus plantarum by agar well diffusion assay and one of them (CeM6-7 strain) exhibited strongest antimicrobial activity. The filtered supernatant of this strain also suppressed the growth of several Gram-positive pathogens (such as Staphylococcus aureus) or lactic acid bacteria in broth. The filtrate could also suppress the growth of L. plantarum inoculated into soymilk. Antimicrobial B. subtilis strain CeM6-7 is thought to be applicable for making a starter culture to produce much safe fermented soybean foods by suppressing the growth of naturally contaminated B. cereus or S. aureus during production. In addition, the use of this starter culture may contribute to prevent spoilage or quality loss of soybean products caused by the over growth lactic acid bacteria or other Gram-positive bacteria.
文摘Quantum mechanics has some weird aspects, which we simply have to accept, according to Tegmark. However, approaching this issue from a bio-psychological perspective allows for an alternative interpretation that avoids this supposedly inherent weirdness. Physical laws are established based on repeated observations or measurements, which involve sense organs. Our capacity for memorization and abstract reflection allows us to draw conclusions on physical reality, which can thus be represented with mathematical formalism. Therefore, physical laws are dependent on pure bio-psychological functions. If quantum mechanics is seen in the bio-psychological context, normal mental functions might explain phenomena such as the collapse of the wave function. If events of interest occurred regularly, similar to classical physics, the same pattern of regular events would be anticipated in the future. Conversely, if events that occurred in the past were irregular, like in quantum mechanics, they would also evolve in an irregular manner in the future. Prediction of irregular behavior requires the ability to imagine multiple possibilities in a kind of mental superposition. Only when one of the imagined possibilities is realized, the mental superposition of the future will collapse to one observable behavior occurring in the present. However, in mental representation, similar to classical physical formalism, some aspects of reality can be lost. When time and space coordinates are replaced by calculated time intervals and spatial distances, time periods and spatial lengths become independent of their initial reference frames. Consequently, the concepts of past, present, and future become irrelevant for time intervals. In quantum mechanics, as well as in mental imagination of potentiality, the notions of the unity of one space for one time and the time arrow are also eliminated. This analogy suggests that physical formalism does not correspond to independent physical reality, but rather to mental functions, which allow establishing a mathematical model of extra-mental reality. If quantum mechanics is conceived as mental potentiality for modeling physical reality, the weird aspect of the collapse of superposition disappears and becomes a simple transition from imagined potentiality in mental representation to observed reality, which could explain the measurement problem.
文摘Objective: The aim of the research was to investigate efficacy of dried bio-floc supplemented with immuno-stimulants as beta-glucan and nucleotide on mortality rate and relative percent survival (RPS) of tilapia infected with Flavobacterium columnare, VETSV01. Materials and Methods: A research was performed in 1-inch long tilapia stimulated its immunity by infection with Flavobacterium columnare, VETSV01. Pathogenesis of 0.2 mL Flavobacterium columnare, VETSV01 in the range of 10^2-10^8 mL-1 fish^-1 was injected into its intraperitoneal injection and intramuscular injection and suitable concentrations were screened to obtain for further experiment in a late restage. Based on data of minimal concentration, 50% mortality rate was caused and it was found the concentration of 108 mL^-1 fish^-1 caused 100% mortality rate and no lethal rate was found in other concentrations. Afterwards, efficacy of bio-floc sediment on survival rate of Tilapia infected with Flavobacterium columnare, VETSV01 was examined. Completely randomized design was employed and experiments were divided into 4 treatment: (1) contxol-commercial feed only, (2) commercial feed attached with dried bio-floc, (3) commercial feed attached with bio-floc and beta-glucan and (4) commercial feed attached with bio-floc and nucleotide. Experiment design was performed as 3 replicates with 10 fishes/replicates in 24 inch glass aquarium. Analysis of difference was performed and determination of mean differences of mortality rate mad relative percent survival was done through Duncan's Multiple Range Test (p 〈 0.05). Results and Discussions: It was demonstrated feeding tilapia with commercial feed in combination with dried bio-floc with or without supplementation of 2 immuno-stimulants could lead to 100% survival rate and 100% relative percent survival rate and it was statistically significant different (p 〈 0.05) compared to control group. Bio-floc product supplemented with beta glucan or nucleotide could effectively stimulate immunity against Flavobacterium columnare, VETSV01 and such high effective performance is viewed as a promising potential product to be further developed and practically employed for sake of aquaculture industry in the near future.
基金financial support from the National Natural Science Foundation of China(Grant Nos.50676085,51276166,50476057,50176046 and 51476142)
文摘The development of bio-based liquid fuel is important for the substitution of transport fuels.Fast pyrolysis can efficiently convert solid biomass wastes into bio-oil.However,its poor properties limit its high-quality utilization and therefore upgrading is required.Because of the complicated composition,upgrading bio-oil by a single technique faces many problems,such as low conversion efficiency and severe catalyst deactivation.These problems can be largely overcome by graded upgrading based on separation,in which bio-oil is first separated into several fractions and then these fractions are upgraded by different techniques.This paper is a review of the current states in the upgrading of bio-oil fractions obtained from water extraction and vacuum or molecular distillation.The corresponding upgrading techniques include esterification,steam reforming,catalytic cracking,and hydrodeoxygenation. For each upgrading technique,the corresponding conversion behaviors and mechanisms of typical model compounds in bio-oil fractions are first outlined,and then the applications of this technique in actual bio-oil fraction upgrading are introduced.The graded upgrading of bio-oil based on separation will have more potential and become more economical if various separation techniques,upgrading methods,and the extraction of valuable chemicals can be combined.
基金supported by the National Basic Research Program of China (2015CB654700)the National Natural Science Foundation of China (50933001)+2 种基金the State Key Program of National Natural Science of China (51333004)the Innovative Research Groups of the Natural Science Foundation of China (51221002)the Goodyear Tire & Rubber Company
文摘Bio-based elastomer poly(diethyl itaconate-co-isoprene)(PDEII) was designed and synthesized by redox-initiated emulsion polymerization from diethyl itaconate and isoprene with mass ratio of 20:80, 40:60, 60:40 and 80:20. The number-average molecular weights of PDEII exceeded 140000 with relatively high yields. The physical properties of PDEII, such as glass transition temperatures and thermostability, were comparable with conventional synthetic elastomers and can be readily tuned by varying the ratio of diethyl itaconate to isoprene. The interaction between silica and PDEII macromolecules was effectively enhanced with the increase of diethyl itaconate content by endowing high polarity. The oil-resistance relevant properties of silica/PDEII80(80% diethyl itaconate, 20% isoprene) such as retention of tensile strength, retention of elongation at break and change in volume even surpass those of silica/NBR 240 S after soaked in ASTM 3# oil at different temperatures.
基金supported by the National Natural Science Foundation of China (21320102003, 31200752, 31661130152, 11435002)the National Distinguished Young Scientists Program (31325010)
文摘Knowledge on the interactions between engineered nanomaterials(ENMs) and biological systems is critical both for the assessment of biological effects of ENMs and for the rational design of ENM-based products. However, probing the events that occur at the nano-bio interface remains extremely challenging due to their complex and dynamic nature. So far, the understanding of mechanisms underlying nano-bio interactions has been mainly limited by the lack of proper analytical techniques with sufficient sensitivity, selectivity and resolution for characterization of nano-bio interface events. Moreover, many classic bioanalytical methods are not suitable for direct measurement of nano-bio interface interactions. These have made establishing analytical methodologies for systematic and comprehensive study of nano-bio interface one of the most focused areas in nanobiology. In this review we have discussed some representative developments regarding analytical techniques for nano-bio interface characterization, including the improvements of traditional methods and the emergence of powerful new technologies. These developments have allowed ultrasensitive, real-time analysis of interactions between ENMs and biomolecules, transformations of ENMs in biological environment, and impacts of ENMs on living systems on molecular or cellular level.
文摘In this study, hybrid computational frameworks are developed for active noise control(ANC) systems using an evolutionary computing technique based on genetic algorithms(GAs) and interior-point method(IPM), following an integrated approach, GA-IPM. Standard ANC systems are usually implemented with the filtered extended least mean square algorithm for optimization of coefficients for the linear finite-impulse response filter, but are likely to become trapped in local minima(LM). This issue is addressed with the proposed GA-IPM computing approach which is considerably less prone to the LM problem. Also, there is no requirement to identify a secondary path for the ANC system used in the scheme. The design method is evaluated using an ANC model of a headset with sinusoidal, random, and complex random noise interferences under several scenarios based on linear and nonlinear primary and secondary paths. The accuracy and convergence of the proposed scheme are validated based on the results of statistical analysis of a large number of independent runs of the algorithm.
文摘In this work, biologically-inspired computing framework is developed for HIV infection of CD4+ T-cell model using feed-forward artificial neural networks (ANNs), genetic algorithms (GAs), sequential quadratic programming (SQP) and hybrid approach based on GA-SQP. The mathematical model for HIV infection of CD4+ T-cells is represented with the help of initial value problems (IVPs) based on the system of ordinary differential equations (ODEs). The ANN model for the system is constructed by exploiting its strength of universal approximation. An objective function is developed for the system through unsupervised error using ANNs in the mean square sense. Training with weights of ANNs is carried out with GAs for effective global search supported with SQP for efficient local search. The proposed scheme is evaluated on a number of scenarios for the HIV infection model by taking the different levels for infected cells, natural substitution rates of uninfected cells, and virus particles. Comparisons of the approximate solutions are made with results of Adams numerical solver to establish the correctness of the proposed scheme. Accuracy and convergence of the approach are validated through the results of statistical analysis based on the sufficient large number of independent runs.
基金supported by the Financial Support from Key Laboratory of Random Complex Structures and Data Science,Academy of Mathematics and Systems Science,Chinese Academy of Sciences(Grant Nos.2008DP173182 and Y129161ZZ1)National Natural Science Foundation of China(Grant Nos.11021161 and 11201456)National Program on Key Basic Research Project of China(973 Program)(Grant No.2011CB808000)
文摘We provide some sharp criteria for studying the ergodicity and asymptotic stability of general Feller semigroups on Polish metric spaces. As an application, the 2D Navier-Stokes equations with degenerate stochastic forcing will be simply revisited.