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Zn0.83Mn0.17Se和ZnSe/Zn0.84Mn0.16Se超晶格材料中Mn^2+的压力光谱研究
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作者 王文杰 邓加军 丁琨 《高压物理学报》 EI CAS CSCD 北大核心 2011年第5期385-389,共5页
采用压力光谱技术在低温下观测到了Mn2+离子的4 T1→6 A1跃迁,该谱线在Zn0.83Mn0.17Se和ZnSe/Zn0.84Mn0.16Se超晶格样品中有不同的压力行为,体材料中其压力系数为-42.4peV/Pa,超晶格中为-29.5peV/Pa。用晶体场理论计算得到体材料Zn0.83M... 采用压力光谱技术在低温下观测到了Mn2+离子的4 T1→6 A1跃迁,该谱线在Zn0.83Mn0.17Se和ZnSe/Zn0.84Mn0.16Se超晶格样品中有不同的压力行为,体材料中其压力系数为-42.4peV/Pa,超晶格中为-29.5peV/Pa。用晶体场理论计算得到体材料Zn0.83Mn0.17Se中Mn2+离子4 T1→6 A1谱线的压力系数为-38.3peV/Pa,与实验结果基本一致。结合材料中发光峰积分强度随压力的变化关系进行分析,证实Mn2+离子的发光性质主要与其近邻的晶体场环境有关。 展开更多
关键词 ZnSe/Zn0.84Mn0.16Se 压力光谱 Mn2+的发光性质
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红宝石R'、B线及U、Y带压力移位的理论计算
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作者 黄小益 《发光学报》 EI CAS CSCD 北大核心 1995年第3期228-231,共4页
基于电子径向波函数在加压下扩展的概念,把B、C、Dq、ξ等参量表示成线性压缩k\的函数,并进一步考虑三角场作用,理论计算了红宝石R'、B线及U、Y带的光谱压力移位,结果与实验数据符合很好。
关键词 晶场 光谱压力移位 红宝石
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静压下半导体微腔内激子与光子行为的研究
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作者 章继东 陈京好 +5 位作者 邓元明 安龙 章昊 杨富华 李国华 郑厚植 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2003年第2期223-225,共3页
由于腔模与激子对压力的依赖关系不同,所以可以选择不同的压力使激子和光场处于不同的耦合状态,从而实现对耦合的调谐。利用这种办法,我们观测到了代表激子与光场强耦合作用的Rabi分裂。由于在我们现有样品结构中压力对激子本征行为的... 由于腔模与激子对压力的依赖关系不同,所以可以选择不同的压力使激子和光场处于不同的耦合状态,从而实现对耦合的调谐。利用这种办法,我们观测到了代表激子与光场强耦合作用的Rabi分裂。由于在我们现有样品结构中压力对激子本征行为的影响很小,与以前报道的温度、电场等调谐方式相比,这种调谐方法不仅可以有效地调谐半导体微腔内激子与腔模的耦合程度,而且能够保持激子的本征性质在整个调谐过程中基本不变。这有助于研究在强耦合过程中激子极化激元的本征性质。将实验结果与压力下激子与腔模耦合理论进行拟合,得出了正确的Rabi分裂值。 展开更多
关键词 半导体微腔 压力光谱 Rabi分裂 量子电动力学效应
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SiC/Al_2O_3纳米复合材料压痕残余应力压谱法测量研究 被引量:1
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作者 陶杰 崔益华 李杨 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2005年第2期270-273,共4页
利用压力荧光光谱法研究了5%SiC/Al2O3纳米复合材料压痕周围残余应力的大小及其分布规律。结果发现在压痕区及压痕周围10μm的应力区范围中,荧光R线明显增宽,而且压应力与离压痕中心距显著相关。通过获得的R双峰(R1和R2荧光光谱)频率变... 利用压力荧光光谱法研究了5%SiC/Al2O3纳米复合材料压痕周围残余应力的大小及其分布规律。结果发现在压痕区及压痕周围10μm的应力区范围中,荧光R线明显增宽,而且压应力与离压痕中心距显著相关。通过获得的R双峰(R1和R2荧光光谱)频率变化,计算了压痕区及其周围复杂应力场中的等静压力。结果表明沿着压痕区主对角线方向和边界垂直平分线方向,其应力分布存在十分相似的变化规律。同时发现在压痕周围存在着对称残余应力区。 展开更多
关键词 纳米复合材料 残余应力 压力荧光光谱 压痕
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PIEZOSPECTROSCOPIC STUDY OF RESIDUAL STRESSES AROUND INDENTATIONS IN SiC/Al_O_3 NANOCOMPOSITE
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作者 陶杰 崔益华 杨斌鹏 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2003年第1期85-90,共6页
A new experimental measurement of residual stresses around Vickers′ indentations on the surface of the SiC/Al 2O 3 nanocomposites is proposed with the aid of a Raman microprobe. Results s how that the shifts of R... A new experimental measurement of residual stresses around Vickers′ indentations on the surface of the SiC/Al 2O 3 nanocomposites is proposed with the aid of a Raman microprobe. Results s how that the shifts of R lines in the fluorescence spectra va ry with the distance from the centre of indentation. The magnitude of load appli ed on the surface of the materials through the indenter influences the shifts of R lines to great extent. The luminescence of R lines of the materials before indenting is used to determine the residual stresses around the indentation in the materials, assuming that the stress tensor is transversely isotropic. Final ly, the term of hydrostatic stress is adopted to explain and compare different residual stresses around indentations with the increase of the indenting load an d the distance from the centre of indentations. < 展开更多
关键词 residual stress NANOCOMPOSITE piezospec troscopi c method INDENTATION SiC/Al 2O 3
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Spectroscopic Diagnostic of Spark Discharge Plasma at Atmospheric Pressure 被引量:1
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作者 Laslov Geza Shuaibov Alexander +1 位作者 Szegedi Szendor Laszlo Elemer 《Journal of Chemistry and Chemical Engineering》 2014年第3期302-305,共4页
The emission of CuInSe2-based spark discharge plasma at atmospheric pressure in air has been investigated by optical emission spectroscopy method. The plasma was formed by action of the high voltage pulse generator (... The emission of CuInSe2-based spark discharge plasma at atmospheric pressure in air has been investigated by optical emission spectroscopy method. The plasma was formed by action of the high voltage pulse generator (with nanosecond pulse) on the corresponding electrodes (CulnSe2 compound). The emission characteristics have been obtained for the spark discharge plasma at 3 mm interelectrode distance. It was established that the spark discharge plasma radiation was determined by decay products of the compound from which electrodes were made. The most suitable spectral lines for plasma diagnostics is atomic copper lines in the visible spectrum and atomic indium lines in UV (ultraviolet) and visible spectrum. 展开更多
关键词 Spark discharge optical emission spectroscopy emission characteristic excited states CulnSe_ compound.
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CO2 Pressure Shift and Broadening of Water Lines Near 790 nm
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作者 陆燕 李新飞 +1 位作者 刘安雯 胡水明 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第1期1-4,I0003,共5页
Carbon dioxide pressure-broadened ro-vibrational transitions belonging to thev^2+3v^3 band of H2160 have been measured with a sensitive cavity ring-down spectrometer. Water vapor of relatively low pressures (〈0.5 T... Carbon dioxide pressure-broadened ro-vibrational transitions belonging to thev^2+3v^3 band of H2160 have been measured with a sensitive cavity ring-down spectrometer. Water vapor of relatively low pressures (〈0.5 Torr) was used to limit the self-collisions among water molecules. After the calibration using the precise atomic transitions of Rb and a thermo- stabilized Fabry-Perot interferometer, 10^-5 cm^-1 frequency accuracy has been achieved. Line parameters are derived from least-squares fitting of the spectra using the "soft" collision model. The retrieved line parameters can be applied in the study of water absorption in the CO2-rich atmospheres of planets like Venus and Mars. 展开更多
关键词 WATER Carbon Dioxide Pressure-induced half width Pressure-induced line shift Cavity ring-down spectroscopy
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The Optical Emission Spectroscopy Experiment of Open Air Plasmas
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作者 S. Mijovic M. Vuceljic M. Scepanovic 《Journal of Chemistry and Chemical Engineering》 2013年第7期671-673,共3页
A plasma spectroscopy experiment is described and its performances are given, ways oI excltauon u^ttc~,t tc~,,,,,~ ,,, free-burning plasma at atmospheric pressure is analyzed in detail. The fixed-grating spectrograph ... A plasma spectroscopy experiment is described and its performances are given, ways oI excltauon u^ttc~,t tc~,,,,,~ ,,, free-burning plasma at atmospheric pressure is analyzed in detail. The fixed-grating spectrograph PGS-2 Carl Zeiss Jena is actually a variation on the very first spectrometer design, where photo-plate was replaced with a detector array of PIXIS-Roper Scientific camera. Abilities of the system are analyzed and its limitations are determined. 展开更多
关键词 Plasma physic SPECTROSCOPY open air plasma.
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激光工作物质
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《中国光学》 EI CAS 1996年第4期25-27,共3页
TN244 96042275红宝石R’B线及U、Y带压力移位的理论计算=Theoretical calculations of pressure-inducedshifts of the R’ and B lines and the U and Y broad bands of the spectral for ruby[刊,中]/黄小益(郴州师范高等专科学校物... TN244 96042275红宝石R’B线及U、Y带压力移位的理论计算=Theoretical calculations of pressure-inducedshifts of the R’ and B lines and the U and Y broad bands of the spectral for ruby[刊,中]/黄小益(郴州师范高等专科学校物理系.湖南,郴州(423000))∥发光学报.—1995,16(3).—228—231基于电子径向波函数在加压下扩展的概念。 展开更多
关键词 激光工作物质 理论计算 光谱特性 径向波函数 红宝石 光谱压力移位 师范高等专科学校 激光谐振腔 可调谐 物理系
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蔬菜、水果中总砷的测定
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作者 毛全阳 赵妍 《绿色科技》 2019年第22期222-223,共2页
对GB 5009.11-2014《食品安全国家标准食品中总砷及无机砷的测定》中总砷的测定第一篇第二法进行了改进,采用压力消解罐消解样品的方法,进行了消解条件、标准曲线、精密度、准确度、方法检出限等实验。结果表明:改进后方法的检出限为0.0... 对GB 5009.11-2014《食品安全国家标准食品中总砷及无机砷的测定》中总砷的测定第一篇第二法进行了改进,采用压力消解罐消解样品的方法,进行了消解条件、标准曲线、精密度、准确度、方法检出限等实验。结果表明:改进后方法的检出限为0.01 mg/kg,相关系数r=0.9997,相对标准偏差为1.4%,样品加标回收率为90%~105%之间。该方法解决了电热板湿法消解耗时长,样品容易受外部环境污染导致结果平行性较差等问题,适用于蔬菜、水果中总砷的测定。 展开更多
关键词 蔬菜、水果中总砷 压力消解罐消解、氢化物发生原子荧光光谱
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