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TC21合金在不同温度下进行连续多步置氢处理时的显微组织及室温力学性能
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作者 袁宝国 钱德国 +2 位作者 张小雪 陈强 汤爱闯 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第5期1520-1532,共13页
利用OM、XRD、TEM以及压缩试验等方法研究TC21钛合金经不同温度连续多步置氢处理后的显微组织及室温力学性能。结果表明:当氢处理温度超过1073 K时,α相的尺寸明显降低,β相成为主要相。随着氢处理温度的升高,δ氢化物的含量呈先增加后... 利用OM、XRD、TEM以及压缩试验等方法研究TC21钛合金经不同温度连续多步置氢处理后的显微组织及室温力学性能。结果表明:当氢处理温度超过1073 K时,α相的尺寸明显降低,β相成为主要相。随着氢处理温度的升高,δ氢化物的含量呈先增加后逐渐降低的趋势。当氢处理温度超过1073 K时,TC21钛合金在室温压缩变形过程中出现应变软化现象,且该现象随氢处理温度的升高而越来越显著。随着氢处理温度的升高,TC21钛合金的极限变形率呈先降低后增加的趋势。当氢处理温度为1123 K时,TC21钛合金的极限变形率比原始合金增加67.51%。 展开更多
关键词 TC21合金 连续多步置氢处理 室温力学性能 压力-组成等温线
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La_(0.7)Mg_(0.3)(Ni_(1-x)Co_x)_(3.5)(0≤x≤0.5)储氢合金电化学性能 被引量:5
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作者 张海昌 墨伟 +3 位作者 申元 杨化滨 周作祥 周杏弟 《中国稀土学报》 CAS CSCD 北大核心 2004年第5期712-714,共3页
The effects of Ni/Co ratios on A2B7-type La0.7Mg0.3 (Ni1-xCox)3.5 (0≤x≤0.5) alloys were investigated. The results showed that the discharge capacity of the alloys first increased from 245 to 392 mAh·g-1, then... The effects of Ni/Co ratios on A2B7-type La0.7Mg0.3 (Ni1-xCox)3.5 (0≤x≤0.5) alloys were investigated. The results showed that the discharge capacity of the alloys first increased from 245 to 392 mAh·g-1, then decreased to 316 mAh·g-1, corresponding to x=0, 0.2 and 0.5, respectively. While the electrochemical impedance spectra indicated that the reaction resistance had the opposite tendency. When x is equal to 0.2, the reaction resistance has the lowest value. The electrochemical P-C-T results are consistent with the discharge ones of the alloys. When x is equal to 0.2, the dehydriding capacity is 1.34wt.%. 展开更多
关键词 La2Ni7型储氢合金 电化学性能 循环寿命 交流阻抗 电化学压力组成等温线 稀土
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甲醇-正丁醇二元等温汽液平衡体系的研究
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作者 刘廷岳 聂素双 耿肖粉 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2009年第5期69-73,共5页
用经Ellis汽液平衡釜验证的自制汽液平衡装置测定了甲醇-正丁醇二元液系在不同温度处恒温时的压力与组成的汽液平衡数据,计算了体系的热力学函数,并进行了热力学一致性检验。这不仅为二元混合液系的压力组成测定提供了研究装置,同时充... 用经Ellis汽液平衡釜验证的自制汽液平衡装置测定了甲醇-正丁醇二元液系在不同温度处恒温时的压力与组成的汽液平衡数据,计算了体系的热力学函数,并进行了热力学一致性检验。这不仅为二元混合液系的压力组成测定提供了研究装置,同时充实了压力组成实验数据,还丰富了二元液系的热力学理论。 展开更多
关键词 研究装置 甲醇-正丁醇系统 压力组成 汽液平衡 活度系数 热力学函数
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TiCrMo三元储氢合金的结构和性能 被引量:6
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作者 黄太仲 吴铸 徐乃欣 《中国有色金属学报》 EI CAS CSCD 北大核心 2006年第11期1855-1860,共6页
采用XRD、SEM和PCT法研究Mo取代TiCr1.8合金中的部分Cr对其结构和储氢性能的影响。XRD测试结果表明,随着合金中Mo取代Cr的量的增加,合金的相组成首先转变为MoCr体心立方(BCC)相与Laves相共存,Laves相的含量逐渐降低;当Mo含量超过一定量... 采用XRD、SEM和PCT法研究Mo取代TiCr1.8合金中的部分Cr对其结构和储氢性能的影响。XRD测试结果表明,随着合金中Mo取代Cr的量的增加,合金的相组成首先转变为MoCr体心立方(BCC)相与Laves相共存,Laves相的含量逐渐降低;当Mo含量超过一定量时,合金的相组成转变为MoCrBCC相与微量的α-Ti相共存;MoCrBCC相的晶胞参数随合金中Mo含量的增加而增大。合金的压力组分温度(PCT)测试结果表明,合金的吸氢量随合金中Mo含量的增加而减少。 展开更多
关键词 TiCr基储氢合金 压力-温度-组成测试 储氢性能
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Effect of extrusion process on microstructure and mechanical properties of Ni_3Al-B-Cr alloy during self-propagation high-temperature synthesis 被引量:3
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作者 盛立远 奚廷斐 +2 位作者 赖琛 郭建亭 郑玉峰 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第3期489-495,共7页
The well-densified Ni3Al-0.5B-5Cr alloy was fabricated by self-propagation high-temperature synthesis and extrusion technique. Microstructure examination shows that the synthesized alloy has fine microstructure and co... The well-densified Ni3Al-0.5B-5Cr alloy was fabricated by self-propagation high-temperature synthesis and extrusion technique. Microstructure examination shows that the synthesized alloy has fine microstructure and contains Ni3Al, Al2O3, Ni3B and Cr3Ni2 phases. Moreover, the self-propagation high-temperature synthesis and extrusion lead to great deformation and recrystallization in the alloy, which helps to refine the microstructure and weaken the misorientation. In addition, the subsequent extrusion procedure redistributes the Al2O3 particles and eliminates the γ-Ni phase. Compared with the alloy synthesized without extrusion, the Ni3Al-0.5B-5Cr alloy fabricated by self-propagation high-temperature synthesis and extrusion has better room temperature mechanical properties, which should be ascribed to the microstructure evolution. 展开更多
关键词 Ni3Al intermetallic compound self-propagation high-temperature synthesis EXTRUSION MICROSTRUCTURE mechanical properties
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LaMg_(8.40)Ni_(2.34)合金的相结构和储氢性能(英文) 被引量:4
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作者 李金华 刘宝忠 +3 位作者 韩树民 扈琳 朱惜林 王明智 《物理化学学报》 SCIE CAS CSCD 北大核心 2011年第2期403-407,共5页
利用真空感应熔炼和退火方法制备了LaMg8.40Ni2.34合金.采用X射线衍射(XRD)分析、扫描电镜(SEM)和压力-组成-温度(PCT)测试仪测试了合金的相组成、微观形貌和储氢性能.LaMg8.40Ni2.34合金由La2Mg17、LaMg2Ni和Mg2Ni组成,且在第一次吸放... 利用真空感应熔炼和退火方法制备了LaMg8.40Ni2.34合金.采用X射线衍射(XRD)分析、扫描电镜(SEM)和压力-组成-温度(PCT)测试仪测试了合金的相组成、微观形貌和储氢性能.LaMg8.40Ni2.34合金由La2Mg17、LaMg2Ni和Mg2Ni组成,且在第一次吸放氢循环中就可以完全活化.在558K下的可逆储氢量为3.01%(质量分数),合金的PCT曲线表现出双吸氢平台,分别对应着形成的MgH2和Mg2NiH4.但是放氢曲线却只有一个平台出现,这是由MgH2和Mg2NiH4之间的协同脱氢作用产生的.LaMg8.40Ni2.34合金在吸放氢时的活化能分别为(52.4±0.4)和(59.2±0.1)kJ·mol-1,均低于Mg2Ni合金.与纯Mg和Mg2Ni合金相比,LaMg8.40Ni2.34合金具有良好的活化性能、较高的储氢性能和优良的动力学性能. 展开更多
关键词 储氢材料 La-Mg-Ni合金 压力-组成-温度曲线 多相结构
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Influence of Pore Size,Salinity and Gas Composition upon the Hydrate Formation Conditions 被引量:17
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作者 杨明军 宋永臣 +2 位作者 刘瑜 陈拥军 李清平 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第2期292-296,共5页
An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that t... An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature. 展开更多
关键词 HYDRATE EQUILIBRIUM pore size SALINITY gas composition
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Analysis of Properties of Thrust Bearing in Ship Propulsion System 被引量:3
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作者 吴铸新 刘正林 《Journal of Marine Science and Application》 2010年第2期220-222,共3页
Thrust bearing is a key component of the propulsion system of a ship. It transfers the propulsive forces from the propeller to the ship's hull, allowing the propeller to push the ship ahead. The performance of a thru... Thrust bearing is a key component of the propulsion system of a ship. It transfers the propulsive forces from the propeller to the ship's hull, allowing the propeller to push the ship ahead. The performance of a thrust bearing pad is critical. When the thrust bearing becomes damaged, it can cause the ship to lose power and can also affect its operational safety. For this paper, the distribution of the pressure field of a thrust pad was calculated with numerical method, applying Reynolds equation. Thrust bearing properties for loads were analyzed, given variations in outlet thickness of the pad and variations between the load and the slope of the pad. It was noticed that the distribution of pressure was uneven. As a result, increases of both the outlet thickness and the slope coefficient of the pad were able to improve load beating capability. 展开更多
关键词 thrust bearing thrust pad lubrication properties ship propulsion shaft eometrical factors.
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Variation in Grain Size Distribution in Debris Flow 被引量:3
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作者 LI Yong WANG Bao-liang +1 位作者 ZHOU Xiao-jun GOU Wan-chun 《Journal of Mountain Science》 SCIE CSCD 2015年第3期682-688,共7页
Grain composition of debris flow varies considerably from fluid to deposit, making it uncertain to estimate flow properties (e.g., density, velocity and discharge) using deposit as done in practice. Tracing the vari... Grain composition of debris flow varies considerably from fluid to deposit, making it uncertain to estimate flow properties (e.g., density, velocity and discharge) using deposit as done in practice. Tracing the variation of grain composition is thus more important than estimating some certain properties of flow because every debris flow event consists of a series of surges that are distinct in properties and flow regimes. We find that the materials of debris flows, both the fluid and the source soils, satisfy a universal grain size distribution (GSD) in a form of P (D) = CD-zexp(-D/Dc), where the parameters C, p and De are determined by fitting the function to the grain size frequency. A small At implies a small porosity and possible high excess pore pressure in flow; and a large D~ means a wide range of grain composition and hence a high sediment concentration. Flow density increases as 11 decreases or Dc increases, in a power law form. A debris flow always achieves a state of certain mobility and density that can be well described by the coupling of p and Dc, which imposes a constraint on the fluctuations of flow surges. The GSD also describes the changes in grain composition in that it is always satisfied during the course of debris flow developing. Numerical simulation using the GSD can well illustrate the variation ofμ and Dc from source soils to deposits. 展开更多
关键词 Debris flow Grain size distribution Flow fluctuation Power-law constraints
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Influence of Saline Stress on Ionic Balance of Wheat (Triticum Aestivum) and Its Wild Congeners
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作者 Nina Terletskaya Batyrbek Sarsenbayev Yerlan Kirshibayev 《Journal of Life Sciences》 2011年第8期618-624,共7页
Purpose of this work was to study changes in the ion balance under salt stress in roots and leaves of seedlings of T. aestivum L. and its wild congeners with different genomic composition. Laboratory assessment of sal... Purpose of this work was to study changes in the ion balance under salt stress in roots and leaves of seedlings of T. aestivum L. and its wild congeners with different genomic composition. Laboratory assessment of salt tolerance in seedlings was carried out and contents of ions K^+, Na^+ and Ca^2+ in roots and leaves were defined. Considerable change of ionic balance in roots and leaves of studied forms of wheat against salt stress is shown. It is noticed that the parity K^+/Na^+ decreases in process of strengthening of salt stress. Authentic negative correlation between a relative gain of a biomass of leaves and roots in the stress conditions and accumulation of ions Na^+ and between a relative gain of a biomass of leaves in the stress conditions and a parity in them of ions K^+/Na^+ is revealed. The research results also show that the stability characteristics of indicators of changes in ionic composition or balance in the leaves of young plants are more informative than in the roots and allow to reveal the form, characterized by relatively high of K^+/Na^+ ratio and the relatively low accumulation of Ca2^+ as the most resistant to salt stress. 展开更多
关键词 Saline stress response PLANTLETS ions T. aestivum L. wild congeners.
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A constitutive model for granular soils 被引量:9
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作者 YAO YangPing LIU Lin LUO Ting 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2018年第10期1546-1555,共10页
A simple constitutive model is presented to describe the mechanical behaviors of granular soils in a large stress range. A novel normal compression line(NCL) is first expressed by introducing a limit void ratio(e_L) i... A simple constitutive model is presented to describe the mechanical behaviors of granular soils in a large stress range. A novel normal compression line(NCL) is first expressed by introducing a limit void ratio(e_L) in the double logarithmic scale.Subsequently, a state parameter(ξ) is defined to quantify the current state of granular soils, and a unified hardening parameter(H)that is a function of the state parameter(ξ) is developed to govern the hardening process of the drop-shaped yield surface.Combining with flow rule, a constitutive model for granular soils is proposed. Finally, the comparison between the predictions and the test results of Cambria sand and Coarse-grained material indicates that the model is able to describe the mechanical behaviors of granular soils in a large stress range. 展开更多
关键词 granular soils constitutive model particle crushing
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Elements and Element Components of the Rural Landscape in Linpan of Western Sichuan in Relation to Perception,Preference and Stress Recovery 被引量:4
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作者 LUO Hao DENG Li +8 位作者 JIANG Songlin FU Erkang MA Jun SUN Lingxia JIANG Mingyan CAI Shizhen JIA Yin CAI Jun LI Xi 《Journal of Resources and Ecology》 CSCD 2021年第3期384-396,共13页
Natural environments contribute to people’s perception,preference and health restoration.Many researchers have focused either on the positive effects of overall rural environments on stress recovery or concentrated o... Natural environments contribute to people’s perception,preference and health restoration.Many researchers have focused either on the positive effects of overall rural environments on stress recovery or concentrated on the perception and preference aspects of the rural landscape,but few have integrated perception,preference and stress recovery simultaneously.This paper developed a framework which includes 11 elements and 38 element components related to Linpan,China,and distributed it online as part of a survey.As a result,a total of 324 valid questionnaires were collected.The questionnaire included demographic details,perception and preference degree for Linpan,as well as self-estimations of stress recovery.Stepwise multiple linear regression was employed,and revealed 16 significant predictors for the perception,preference and stress recovery in rural environments.In terms of elements,atmosphere and imagery were the two elements that could be best perceived,while woodland,farmland,water,residence and road were the five most important elements for the preference.Moreover,seven elements were also identified as significant predictors for stress recovery.Among the element components,tranquility as well as road and water proximity were the two significant predictors for perception,while wide visibility as well as woodland and residence blending contributed significantly to stress recovery.The five element components of woodland interior,vegetable field,stream,courtyard space and branch road each had a significantly predictive ability for preference and stress recovery.These findings extend the understanding of the perception,preference and restorative properties of rural environments through the combination of elements and element components in Linpan of Western Sichuan,helping to improve the quality and characteristics of rural external and internal environments and create health-promoting environments. 展开更多
关键词 landscape element element components PERCEPTION PREFERENCE stress recovery
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Experimental simulation of gas hydrate decomposition in porous sediment
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作者 YU XiChong LI Gang +4 位作者 LI QingPing LI XiaoSen ZHANG Yu PANG WeiXin BAI YuHu 《Science China Earth Sciences》 SCIE EI CAS 2013年第4期588-593,共6页
Gas hydrate decomposition in sediments involves complicated multiphase flow and heat and mass transfer processes because of heat absorption by solid hydrates. Factors affecting gas hydrate decomposition in sediments i... Gas hydrate decomposition in sediments involves complicated multiphase flow and heat and mass transfer processes because of heat absorption by solid hydrates. Factors affecting gas hydrate decomposition in sediments include sediment type, mineral composition, pore size distribution, particle size, pore water composition, hydrate saturation distribution, initial formation pressure and temperature and cement characteristics. In this paper, experimental simulations of gas hydrate decomposition are carried out on an artificial core to investigate the effects of initial pressure and temperature, particle size and pore size. The experiments show that the characteristics of gas hydrate decomposition in sediments differ completely from those in a pure water system. The decomposition rate of hydrate sediments increases with the initial pressure increasing and decreasing temperatures. Furthermore, the decomposition rate of hydrate sediments decreases with decreasing particle size and increasing pore size. 展开更多
关键词 SEDIMENTS gas hydrate DECOMPOSITION effect factor experimental simulation
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The formation of liquid bridge in different operating modes of AFM 被引量:2
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作者 Zheng Wei Yan Sun +1 位作者 WenXuan Ding ZaiRan Wang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2016年第9期77-85,共9页
The liquid bridge is one of the principal factors that cause artifacts in ambient-pressure atomic force microscope(AFM) images.Additionally, it is the main component of the adhesion force in ambient conditions. To und... The liquid bridge is one of the principal factors that cause artifacts in ambient-pressure atomic force microscope(AFM) images.Additionally, it is the main component of the adhesion force in ambient conditions. To understand the AFM imaging mechanism and the sample characteristics, it is essential to study the liquid bridge. This study interprets the physical mechanism involved in liquid bridge formation, which is composed of three different physical processes: the squeezing process, capillary condensation,and liquid film flow. We discuss the contributions of these three mechanisms to the volume and the capillary force of the liquid bridge in different AFM operation modes. 展开更多
关键词 liquid bridge atomic force microscope formation mechanism
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