Preparation of ultrafine rhenium powders by CVD hydrogen reduction of volatile rhenium oxides

A novel CVD process for the preparation of ultrafine rhenium powders was investigated using ammonium perrhenate as starting materials. In the process, volatile rhenium oxides, such as ReO4 and Re2O7, were vaporized under a controlled oxidizing atmosphere via the pyrolysis of ammonium perrhenate, and carried into reduction zone by carrier gas, and there reduced into rhenium powders by hydrogen gas. Thermodynamic calculations indicated that Re207 could be prevented from further decomposition through controlling the oxygen partial pressure higher than 10 1.248 Pa in the pyrolysis of ammonium perrhenate. This result was further validated via DSC-TGA analysis of ammonium perrhenate. The typical rhenium powders prepared by the CVD method proposed show irregular polyhedron morphology with particle size in the range of 100-800 nm and a Ds0 of 308 nm. The specific surface area and oxygen content were measured to be 4.37 m^2/g and 0.45%, respectively.

做好培养方案修订 助力学校健康发展

培养方案是一所大学组织教学和进行教学管理的主要依据,是学校对教育教学质量进行监控和评价的基础性文件,也是实现学校目标的重要依托和环节,本文从培养方案修订的几个原则出发,探讨了我校培养方案修订的思路,希望借此完善学校培养方案,助力学校健康、快速发展。

NUMERICAL PREDICTION OF AIRCRAFT HYDRAULIC SYSTEM BASED ON THERMAL DYNAMIC ANALYSIS

A mathematical model of principal elements of the aircraft hydraulic system is presented based on the heat transfer theory. The dynamic heat transfer process of the hydraulic oil and the pump shells within an aircraft hydraulic system are analyzed by the difference method. A kind of means for the prediction to variational trends of the aircraft hydraulic system temperature is provided during operation. The numerical prediction and simulation under the operational conditions are presented for ground trial running and the decelerated operation in flight. Computational results show that there is a good coincidence between the experimental data and the numerical predictions.

Transformation of Flue-Gas-Desulfurization Gypsum to α-Hemihydrated Gypsum in Salt Solution at Atmospheric Pressure

Direct phase transformation of flue gas desulfurization gypsum in hot salt solution at atmospheric pres-sure was investigated.The effects of temperature,salt species,salt concentration,solids content,pH and modifier were examined.The crystals obtained under different conditions and solubility of calcium sulfate in contact with solid gypsum were also determined.α-Calcium sulfate hemihydrate crystals of stubby columnar shape and regular pentahedral sides were obtained under the following conditions：salt concentration 20%-30%,operation tempera-ture 95-100 °C,solids mass content in the slurry 10%-30% and neutral pH.Thermodynamic analysis revealed that phase transformation of calcium sulfate dihydrate to α-calcium sulfate hemihydrate occurs because of the difference in solubilities between the two solid gypsum phases in this system.

Study of vehicle accident reconstruction based on the information of the tire marks

The tire mark is the important legacy information left at the accident scene. Based on the vehicle collision dynamics model, this study provided an optimized algorithm with vehicle final location and other related information for the tire marks. When the tire marks simulation results fit the real one well, the state of vehicle can be understood as the real state in the accident. Based on above, the vehicle velocity and direction are decided. According to the velocity and direction of the vehicle, the complete accident process can be simulated. With the help of the Pc-Crash software, the method has been applied in typical collision accident cases analysis. The reconstruction results will provide the scientific and numerical references for vehicle collision accidents analyzing and appraising.

Damage and fragmentation of rock under experiencing impact load

The principle of energy dissipation in rock impacted by impulse loading was investigated. Associated with damage mechanics, a new method was proposed to calculate the cumulative damage of rock under a repeated loading at the damage stage, which was studied from the point of the action density of energy. The concept of abstract fractal characteristic of damage parameter was put forward based on the intrinsic physical meaning of damage, which was applied to the fragmentation phase of rock. The relationship between fractal damage and the number of fragments was set up. According to the principles of energy dissipation and dynamic fracture of rock experiencing impact load, the damage evolution equation in the fragmentation phase of rock was presented. The results of experiment show that the two methods coincide well with each other.

Configuration Consideration for Expander in Transcritical Carbon Dioxide Two-Stage Compression Cycle

To investigate the configuration consideration of expander in transcritical carbon dioxide two-stage compression cycle, the best place in the cycle should be searched for to reinvest the recovery work so as to improve the system efficiency. The expander and the compressor are connected to the same shaft and integrated into one unit, with the latter being driven by the former, thus the transfer loss and leakage loss can be decreased greatly. In these systems, the expander can be either connected with the first stage compressor (shortened as DCDL cycle) or the second stage compressor (shortened as DCDH cycle), but the two configuration ways can get different performances. By setting up theoretical model for two kinds of expander configuration ways in the transcritical carbon dioxide two-stage compression cycle, the first and the second laws of thermodynamics are used to analyze the coefficient of performance, exergy efficiency, inter-stage pressure, discharge temperature and exergy losses of each component for the two cycles. From the model results, the performance of DCDH cycle is better than that of DCDL cycle. The analysis results are indispensable to providing a theoretical basis for practical design and operating.

Simulation of Melting Behavior of the MgSi03 Perovskite Under Lower Mantle Conditions

The melting curve of MgSiO3 perovskite was simulated using molecular dynamics method combining with the effective pair potentials under the lower mantle conditions. It was shown that the state equation simulated for MgSiO3 perovskite is very successful in reproducing accurately the experimental data over a wide range of pressure. The pressure dependence of the simulated melting temperature of MgSiO3 perovskite is in agreement with the recent experimental data. The melting curve simulated for MgSiO3 is very steep at pressures below 60 GPa first, then it becomes smooth with increasing pressure. At the core mantle boundary pressure 135 GPa, MgSiO3 perovskite melts at 6500 K, which is significantly lower than that of the extrapolations of the experimental data from Zerr and Boehler.

Special nanostructures in Al-Mg alloys subjected to high pressure torsion

Deformation twins and stacking faults were observed in nanostructure A1-Mg alloys subjected to high pressure torsion. These observations are surprising because deformation twinnings have never been observed in their coarse-grained counterparts under normal conditions. Experimental evidences are introduced on non-equilibrium grain boundaries, deformation twinnings and partial dislocation emissions from grain boundaries. Some of these features can be explained by the results reported from molecular-dynamics simulations of pure FCC metals. Special emphasis is laid on the recent observations of high density hexagonal and rhombic shaped nanostructures with an average size of 3 nm in the A1-Mg alloys processed by high pressure torsion. A possible formation process of these nanostructures is proposed based on molecular-dynamics simulations.

Molecular Dynamics Simulations of Liquid Phosphorus at High Temperature and Pressure

By performing ab initio molecular dynamics simulations, we have investigated the microstructure, dynamical and electronic properties of liquid phosphorus （P） under high temperature and pressure. In our simulations, the calculated coordination number （CN） changes discontinuously with density, and seems to increase rapidly after liquid P is compressed to 2.5 g/cm3. Under compression, liquid P shows the first-order liquid-liquid phase transition from the molecular liquid composed of the tetrahedral P4 molecules to complex polymeric form with three-dimensional network structure, accompanied by the nonmetal to metal transition of the electronic structure. The order parameters Q6 and Q4 are sensitive to the microstructural change of liquid P. By calculating diffusion coefficients, we show the dynamical anomaly of liquid P by compression. At lower temperatures, a maximum exists at the diffusion coefficients as a function of density; at higher temperatures, the anomalous behavior is weakened. The excess entropy shows the same phenomena as the diffusion coefficients. By analysis of the angle distribution functions and angular limited triplet correlation functions, we can clearly find that the Peierls distortion in polymeric form of liquid P is reduced by further compression.

A micro-sphere catalyst complex with nano CaCO_3 precursor for hydrogen production used in ReSER process

This paper describes the preparation and evaluation of a micro-sphere catalytic complex for the hydrogen production in a Reactive Sorption Enhanced Reforming （ReSER） process. The catalytic complex made by a spray technique has a dual function containing Ni as a catalytic material and CaO as an adsorption material used in the ReSER process. The attrition characteristics of the catalytic complex are acceptable for the commercial used. The nano GaCO3 material used as a precursor of CaO showed a desirable durability with a CO2 sorption capacity of 0.6 mol CO2/kg after 10 repeating cycles under the carbonation temperature of 600 ℃, a CO2 partial pressure of 0.02 MPa, and a calcination temperature of 750 ℃ in N2 measured by a thermal gravimetric analyzer. The testing of the catalytic complex for ReSER showed a hydrogen yield of over 95 % （v/v） in the laboratory fixed fluidized bed reactor. The catalytic system has an attractive prospect in the ReSER process for hydrogen production, especially in the fluidized mode where reactor and regenerator combined in a cycling process.

Pressure Drop Measurements on Distillation Columns

Pressure drops are of major importance for distillation/absorption columns. This paper mainly discusses how to correctly measure, interpret and use pressure drop data. The possible causes of incorrect pressure drop measurements are studied including the effects of pressure tap dimensions, locations, and vapor condensation etc. The effect of the static head of vapor on the pressure drop data and column pressures is evaluated. Variations of sectional pressure drops along the column are investigated based on the experimental data obtained from commercial size distillation columns at Fractionation Research, Inc. （FRI）. For a packed column, it is found that the spacing between the liquid distributor and the top of the bed affects the overall pressure drop measurements, which is confirmed by a fundamental fluid dynamics analysis.

Compact Threshold Voltage Model for FinFETs

A 2D analytical electrostatics analysis for the cross-section of a FinFET (or tri-gate MOSFET) is performed to calculate the threshold voltage.The analysis results in a modified gate capacitance with a coefficient H introduced to model the effect of tri-gates and its asymptotic behavior in 2D is that for double-gate MOSFET.The potential profile obtained analytically at the cross-section agrees well with numerical simulations.A compact threshold voltage model for FinFET,comprising quantum mechanical effects,is then proposed.It is concluded that both gate capacitance and threshold voltage will increase with a decreased height,or a decreased gate-oxide thickness of the top gate,which is a trend in FinFET design.

Properties inhomogeneity of AM60 magnesium alloy processed by cyclic extrusion compression angular pressing followed by extrusion

A new severe plastic deformation(SPD)technique for improvement of the metallurgical properties of the magnesium alloys is presented.In this process,a cyclic extrusion compression angular pressing(CECAP)process is followed by an extrusion step in the outlet playing the role of additional back pressure.Therefore,more uniform and enhanced mechanical properties are expected in comparison with equal channel angular pressing(ECAP).In order to evaluate the effectiveness and capabilities of this new method,an AM60 magnesium alloy was processed.Finite element results exhibited a significant increase in strain values as well as uniform strain distribution for the new method.In addition,~110%increase in compressive stress was observed in new method compared to the conventional ECAP.Experimental results revealed a noticeable increase in the hardness and strength of the specimens processed by the new technique as a result of the formation of finer grains and more homogeneous microstructure with good distribution of refinedβ-phase along the boundaries.It may be concluded that the new process is very promising for future magnesium alloy products.

Thermal-hydraulic modeling and analysis of hydraulic system by pseudo-bond graph

To increase the efficiency and reliability of the thermodynamics analysis of the hydraulic system, the method based on pseudo-bond graph is introduced. According to the working mechanism of hydraulic components, they can be separated into two categories: capacitive components and resistive components. Then, the thermal-hydraulic pseudo-bond graphs of capacitive C element and resistance R element were developed, based on the conservation of mass and energy. Subsequently, the connection rule for the pseudo-bond graph elements and the method to construct the complete thermal-hydraulic system model were proposed. On the basis of heat transfer analysis of a typical hydraulic circuit containing a piston pump, the lumped parameter mathematical model of the system was given. The good agreement between the simulation results and experimental data demonstrates the validity of the modeling method.

Statistical Study on Cement-Soil Mixture Strength

This paper presents an investigation on strength of cement deep mixing （CDM） mixture. Four typical works of offshore or land-based projects are introduced. With samples from these projects and laboratory tests, statistical analysis is made on the increment law of the strength of cement-soil mixture with different amount of cement, and strengths under different working conditions are compared. It is found that the amount of cement in the cement-soil mixture is closely related to the unconfined compressive strength of the mixture. At the age of 90 d,the unconfined compressive strength of the cement-soil mixture increased by 0.054 MPa—0.124 MPa with each cement increasing 10 kg/m3 in the cement-soil mixture, averagely increased by 0.085 MPa, while that at the age of 120 d increased by 1100 in comparison.The quality of the cement-soil mixture should be comprehensively evaluated in accordance with the trimmed average of strength, coefficient of variation and rock quality designation （RQD） indicators of sampling ratio.

Deformation Behavior of Hot Isostatic Pressing FGH96 Superalloy

The deformation behavior of hot isostatic pressing （HIP） FGH96 superalloy was characterized in the temperature range of 1000-1100 ℃ and strain rate range of 0. 001-0. 1 s^-1 using hot compression testing. The flow curves of HIP FGH96, superalloy during hot deformation was analyzed systematically. The results show that deformation temperature, strain rate and strain are the main influence factors on flow stress of HIP FGH96 superalloy during hot deformation. The flow stress displays a peak at a critical strain and then decreases with further increase in strain. For a given strain, the flow stress decreases with the increase of deformation temperature, and increases with the increase of strain rate. A mathematical model of these flow curves was established through regression analysis and taking the strain as a modification factor. The calculated stress values agree well with the experimental values.

Numerical Simulation of Wind Turbine Blade-Tower Interaction

Numerical simulations of wind turbine blade-tower interaction by using the open source OpenFOAM tools coupled with arbitrary mesh interface （AMI） method were presented. The governing equations were the unsteady Reynolds-averaged Navier-Stokes （RANS） which were solved by the pimpleDyMFoam solver, and the AMI method was employed to handle mesh movements. The National Renewable Energy Laboratory （NREL） phase VI wind turbine in upwind configuration was selected for numerical tests with different incoming wind speeds （5, 10, 15, and 25 m/s） at a fixed blade pitch and constant rotational speed. Detailed numerical results of vortex structure, time histories of thrust, and pressure distribution on the blade and tower were presented. The findings show that the wind turbine tower has little effect on the whole aerodynamic performance of an upwind wind turbine, while the rotating rotor will induce an obvious cyclic drop in the front pressure of the tower. Also, strong interaction of blade tip vortices with separation from the tower was observed.

Parametric design of an electrorheological shock absorber with the mixed-mode

A mathematical model based on an electrorheological (ER) shock absorber with the mixed-mode is presented. Its application to the parametric design of an electrorheological fluid shock absorber with the simulation calculation performed by program MATLAB demonstrates that the model can predict the behavior of ER shock absorbers satisfactorily, shorten the design period of an electrorheological shock absorber, and reduce the cost in the prototype manufacturing. The strength analysis based on a three-dimensional finite element model for the electrorheological shock absorber confirm that the structure design of the ER shock absorber is reasonable, and the stress distribution is uniform.

The Impact of the South Asia High Bimodality on the Chemical Composition of the Upper Troposphere and Lower Stratosphere

The South Asia High （SAH） is the dominant feature of the circulation in the upper troposphere and lower stratosphere （UTLS） during the boreal summer, and the upper tropospheric anticyclonic circulation extends into the lower stratosphere. The preferred locations of the center of the SAH occur in two different regions, and the center can be located over the Iranian Plateau or over the Tibetan Plateau. This bimodality has an impact on the distribution of chemical constituents in the UTLS region. We analyzed water vapor （H20）, carbon monoxide （CO）, and ozone （03） data derived from the Aura Microwave Limb Sounder （MLS） and total column ozone data from the Ozone Monitoring Instrument （OMI）. For the Iranian Plateau mode of the SAH, the tropospheric tracers exhibited a positive anomaly over the Iranian Plateau and a negative anomaly over the Tibetan Plateau, whereas the stratospheric tracer exhibited a negative and a positive anomaly over the Iranian Plateau and the Tibetan Plateau, respectively. For the Tibetan Plateau mode, however, the distribution of the anomaly was the reverse of that found for the chemical species in the UTLS region. Furthermore, the locations of the extrema within the anomaly seemed to differ across chemical species. The anomaly extrema for H20 occurred in the vicinity of the SAH ridgeline, whereas CO and O3 exhibited a northward shift of 4-8 degrees. These impacts of the variation in the SAH on the chemical constitutes in the UTLS region can be attributed in part to the dynamical structure delineated by the tropopause field and the temperature field at 100 hPa.