聚偏氟乙烯超滤膜仿生矿化增强及其抗压密性能的研究

通过仿生矿化技术在PVDF超滤膜表面和孔壁修饰无机ZrO2矿化层来制备PVDF/ZrO2矿化膜,考察矿化时间对膜的微观结构、机械强度和抗压密性能的影响。结果表明,ZrO2矿化层均匀负载于膜表面和膜孔内壁,且随着矿化时间的增加矿化层逐渐增厚;无机ZrO2矿化层可显著提高PVDF膜的结构刚性,矿化时间为60 min的PVDF/ZrO2矿化膜的拉伸强度和硬度比纯PVDF膜分别提高了76%、79%,运行过程中因机械压密产生的通量衰减率则从纯PVDF膜的53%降低至32%,达到利用ZrO2矿化层提高PVDF膜抗压密性能、抑制通量衰减的目的。同时,ZrO2矿化层改善了PVDF膜的透水性能,PVDF/ZrO2矿化膜的纯水通量和BSA截留率分别达到165.2 L/m^2·h和91.4%。

填料颗粒组成与压密关系的探讨

针对长江干堤增高培厚工程中填土压密问题，在大量的室内外试验与测试的基础上，对填料的颗粒组成与压密性能之间的关系进行了分析，修正了最优含水量的估算公式。当填料中粉砂粒含量较高时，峰值干密度附近含水量的容许变化范围较小，最优含水量较低，易被压密；而当粘粒含量较高时，则相反，且必须在较大压实能量的间歇作用下，方可取得较大的干密度。

Compressive properties and energy absorption characteristics of open-cell nickel foams

Open-cell nickel foams with different relative densities and pre-stretching degrees were subjected to room temperature quasi-static compressive tests to explore their compressive properties. The compressive properties of the nickel foams including yield strength, elastic modulus, energy absorption density and energy absorption efficiency were calculated accurately. The results show that the compressive properties of yield strength, elastic modulus and energy absorption density increase with the increase of relative density of nickel foams. The compressive properties are sensitive to the pre-stretching degree, and the values of yield strength, elastic modulus and energy absorption density decrease with the increase of pre-stretching degree. However, the energy absorption efficiency at the densification strain state exhibits the independence of relative density and pre-stretching degree. The value of energy absorption efficiency reaches its peak when the strain is at the end of the collapse plateau region.

Study on hydrostatic gas lubricated non-contacting mechanical seal

The principle and characteristics of hydrostatic gas lubricated non-contacting mechanical seal （HSGLNMS） are introduced. The flow field of the gas film is established by numerical analysis of end faces of HSGLNMS. The distribution of gas film pressure and seal performance parameters inclu- ding opening force and leakage are obtained. Influence of operating parameters and sealing configu- ration on the sealing performance is studied. HSGLNMS has been designed and manufactured. Its working film thickness and leakage are measured to verify the theoretical analysis. The investigation results show that HSGLNMS demonstrates good speed adaptability, which means that the seal runs successfully with both low and high speed, showing excellent performance. The seal can be regula- ted and controlled online ; the opening force will not be raised greatly with the increasing of the num- ber of throttle orifices, but the leakage of seal increases apparently ; the uniform pressure groove im- proves the sealing performance, for example, opening force and stiffness are raised obviously. While leakage is reduced. Finally, the theoretical analysis is verified by experiment.

Analysis of the sealing performance of combined sealing structure under deep-sea high pressure environment

For the requirement of safe and stable operation,the combined sealing structure was used for reciprocating motion in the deep sea high-pressure environment,and the effects of different seawater depths and shaft movement speed on the sealing performance of the combined sealing structure were studied.The change rule of the sealing performance of the combined sealing structure of reciprocating motion under different working conditions is proved.The study shows that in the combined sealing structure of reciprocating movement,the Von Mises stress and the contact stress of the O-ring varies with the direction of the shaft movement.The Von Mises stress and contact stress of the O-ring,the Von Mises stress and the contact stress on each sealing lip of the slip ring gradually increase with the increasing of seawater depths.At the same time,the Von Mises stress of the O-ring which in the process of the shaft upward movement is greater than the shaft downward movement,making the shaft upward movement more likely to cause the O-ring relaxation and fatigue.The shaft movement speed has no significant influence on the Von Mises stress and contact stress of the O-ring.The research results provide theoretical guidance and technical support for the selection and optimization of the geometrical parameters of the combined sealing structure in the deep-sea high-pressure environment.

The research of the evaluation system for the sealability of hydraulic supports and jacks＇ seals

In order to enhance the sealing quality and assemble efficiency of hydraulic supports, the evaluation system for the sealability of the hydraulic support and jack＇s seals was established through the testing and experimenting technology in respects, such as seals＇ dimensions, reasonable amounts of compression, sealability, life, resistance to pressure, etc. Through life detecting test of the seal, found the longest life seal ring under the same conditions, and through the reciprocating test of the hydraulic support, found the most appropriate amount of interference between the groove and the seal ring, thus, to decrease the leakage and extend the life span of the hydraulic support.

Numerical Analysis of the Thermal Behavior of a Hermetic Reciprocating Compressor

A numerical model to predict the temperature field in a hermetic reciprocating compressor for household refrigeration appliances is presented in this work. The model combines a high resolution three-dimensional heat conduction formulation of the compressor＇s solid parts, a three-dimensional CFD （computational fluid dynamics） approach for the gas line domain and lumped formulations of the shell gas and the lubrication oil. Heat transfer coefficients are determined by applying CFD to the gas line side and correlations from the literature on the shell gas and oil side, respectively. The valve in the gas line simulation is modelled as a parallel moving fiat plate. By means of an iterative loop the temperature field of the solid parts acts as boundary condition for the CFD calculation of the gas line which returns a cycle averaged quantity of heat to the solid parts. Using an iteration method which is based on the temperature deviation between two iteration steps, the total number of iterations and consequently the computational time can be reduced. The loop is continued until a steady-state temperature field is obtained. Calculated temperatures of the solid parts are verified by temperature measurements of a calorimeter test bench.

High tap density of Ni_3(PO_4)_2 coated LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 with enhanced cycling performance at high cut-off voltage

The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer(ICP) analysis and it testified to be 1:1:1. It is indicated that Ni3(PO4)2-coated Li Ni1/3Co1/3Mn1/3O2 has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy(EIS) results show that the current exchange density i0 of the coated sample is higher than that of Li Ni1/3Co1/3Mn1/3O2, which is beneficial to its electrochemical performances. All the conclusions show that the Ni3(PO4)2coating can prominently enhance the high rate performance of the Li Ni1/3Co1/3Mn1/3O2, especially at high cut-off voltage.

Use of Fractals Channels to Improve a Proton Exchange Membrane Fuel Cell Performance

One of the most important and effective hardware elements for improvement of efficiency and power density of proton exchange membrane fuel cells is the flow field plate. The design and the pattern of the flow field plate have a considerable effect on the effectiveness of mass transport as well as on the electrochemical reactions inside the cell. The configuration of the flow field plate aims at ensuring a low pressure-drop over all channels in the stack. In this work, a FPFFP （fractal parallel flow field plate）, with bio-inspired configuration by insertion of fractals in a classic PFFP （parallel flow field plate）, is proposed, increasing the flow area of the hydrogen at anode side without increasing the section＇s area of the flow field plate. By simulating was observed that, the use of channels in fractal shape can increase the hydrogen flow area without occuring pressure loss in the cell. The fluid dynamic behavior in the FPFFP at smaller scales was replicated in the same plate, with better advantage of the active area of the electrode. Increasing the hydrogen flow area without causing pressure loss could be a good tactic to increase the power density of fuel cells, and consequently improving the cell performance.

Experimental Study on Frictional and Sealing Performances of Packing Rings in an Oil-free Gas Compressor

To enhance the reliability and to extend service life of packing rings, tribological and sealing perfor- mances are investigated based on the experimental results. Friction force, leakage rate and power consumption of three materials of pressure packing seals are measured in a refitted vertical gas compressor. The rings are made of common filled polytetrafiuroethylene （Filled PTFE）, PTFE reinforced with 30% mass fraction carbon fiber （30%CF^PTFE）, and carbon-carbon composites infiltrated with PTFE （C/C＋PTFE）, respectively. It is found that packing rings will periodically vibrate with the periodic vibration of pressure packing after the travel direction of motion abruptly turns to the reverse direction. Furthermore, the amplitude of vibration slows down with the increasing crank angle. Approximate value of friction force is available by multiple-point fast Fourier transformation （FFT） employed to process the experimental results by reducing the impact of vibration to a great extent. Of three materials of rings employed in experiments, Filled PTFE presents minimal leakage rate accom- panied with maximum power consumption. And 30%CF＋PTFE exhibits minimum friction power and moderate leakage rate. As for C/C＋PTFE, its high mechanical and thermal properties are favorable factors to enhance the ability of operating under high pressure and velocity and to improve the wear resistance. Unfortunately, this also leads to a large leakage rate. Comprehensive consideration should be taken into to evaluate the availability, reliability and service life for a type of packing ring under dry running conditions.

Tailoring electrolyte enables high-voltage Ni-rich NCM cathode against aggressive cathode chemistries for Li-ion batteries

The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(Ni-rich NCM)cathode materials suffer from electrochemical performance degradation upon cycling due to detrimental cathode interface reactions and irreversible surface phase transition when operating at a high voltage(≥4.5 V).Herein,a traditional carbonate electrolyte with lithium difluoro(oxalato)borate(Li DFOB)and tris(trimethylsilyl)phosphate(TMSP)as dual additives that can preferentially oxidize and decompose to form a stable F,B and Si-rich cathode-electrolyte interphase(CEI)that effectively inhibits continual electrolyte decomposition,transition metal dissolves,surface phase transition and gas generation.In addition,TMSP also removes trace H_(2)O/HF in the electrolyte to increase the electrolyte stability.Owing to the synergistic effect of Li DFOB and TMSP,the Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) half cells exhibit the capacity retention 76.3%after 500 cycles at a super high voltage of 4.7 V,the graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)full cells exhibit high capacity retention of 82.8%after 500 cycles at 4.5 V,and Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)pouch cells exhibit high capacity retention 94%after 200 cycles at 4.5 V.This work is expected to provide an effective electrolyte optimizing strategy compatible with high energy density lithium-ion battery manufacturing systems.