Oil immersed power transformer is the main electrical equipment in power system.Its operation reliability has an important impact on the safe operation of power system.In the process of production,installation and ope...Oil immersed power transformer is the main electrical equipment in power system.Its operation reliability has an important impact on the safe operation of power system.In the process of production,installation and operation,its insulation structure may be damaged,resulting in partial discharge and even breakdown inside the transformer.In this paper,S9-M-100/10 oil immersed distribution transformer is taken as the research object,and the distribution laws of electromagnetic field and temperature field in transformer under normal operation,inter turn short circuit and inter layer short circuit are simulated and analyzed.The simulation results show that under normal conditions,the temperatures at the oil gap between the transformer core and the high and low voltage windings and the middle position of the high-voltage winding are high.When there are inter turn and inter layer short circuit faults,the electromagnetic loss of the fault part of the transformer increases,and the temperature rises suddenly.The influence of the two faults on the internal temperature field of the transformer is different,and the influence of the inter turn short circuit fault on the temperature nearby is obvious.The analysis results can provide reference for the thermal fault interpretation and fault classification of transformer.展开更多
A polypyrrole-modified glassy carbon electrode （PPy/GC electrode） was prepared and its electrocatalytic behavior towards naphthoquinone in the presence of acid was characterized by linear sweep voltammetry （LSV）. ...A polypyrrole-modified glassy carbon electrode （PPy/GC electrode） was prepared and its electrocatalytic behavior towards naphthoquinone in the presence of acid was characterized by linear sweep voltammetry （LSV）. A well-defined new reduction peak appeared at a more positive potential than the original reduction peak. The new reduction peak current was linearly related to the acid value （AV） of oil. Based on it, a rapid electrochemical method for determining AV of transformer oil was developed using PPy/GC electrode. A working curve was obtained in the AV range of 0.01 to 0.40 mg（KOH）.g^-1, with a sensitivity of 39.42 μA0.5/（mg（KOH）.g-l） and the detection limit of 0.0014 mg（KOH）.g^-1 （signal-to-noise ratio is 3, standard deviation is 2.247%）. Moreover, the proposed method has been successfully applied to AV determination of several transformer oil samples with advantages of rapidness, high sensitivity and accuracy compared to the conventional method.展开更多
A new method, which is based on formation fracturing test and Kaiser effect method, has been developed for confirming the oilfield in-situ stress in this paper. The new method has been used in a certain oilfield of Ch...A new method, which is based on formation fracturing test and Kaiser effect method, has been developed for confirming the oilfield in-situ stress in this paper. The new method has been used in a certain oilfield of China and the determined oilfield in-situ stresses is more accurate than that based on one single method.展开更多
A methodology for kinetic modeling of conversion processes is presented.The proposed approach allows to overcome the lack of molecular detail of the petroleum fractions and to simulate the reactions of the process by ...A methodology for kinetic modeling of conversion processes is presented.The proposed approach allows to overcome the lack of molecular detail of the petroleum fractions and to simulate the reactions of the process by means of a two-step procedure.In the first step,a synthetic mixture of molecules representing the feedstock is generated via a molecular reconstruction method,termed SR-REM molecular reconstruction.In the second step,a kinetic Monte Carlo method,termed stochastic simulation algorithm(SSA),is used to simulate the effect of the conversion reactions on the mixture of molecules.The resulting methodology is applied to the Athabasca vacuum residue hydrocracking.An adequate molecular representation of the vacuum residue is obtained using the SR-REM algorithm.The reaction simulations present a good agreement with the laboratory data for Athabasca vacuum residue conversion.In addition,the proposed methodology provides the molecular detail of the vacuum residue conversion throughout the reactions simulations.展开更多
基金Science and Technology Project of State Grid Gansu Electric Power Company(No.52272219000Q)。
文摘Oil immersed power transformer is the main electrical equipment in power system.Its operation reliability has an important impact on the safe operation of power system.In the process of production,installation and operation,its insulation structure may be damaged,resulting in partial discharge and even breakdown inside the transformer.In this paper,S9-M-100/10 oil immersed distribution transformer is taken as the research object,and the distribution laws of electromagnetic field and temperature field in transformer under normal operation,inter turn short circuit and inter layer short circuit are simulated and analyzed.The simulation results show that under normal conditions,the temperatures at the oil gap between the transformer core and the high and low voltage windings and the middle position of the high-voltage winding are high.When there are inter turn and inter layer short circuit faults,the electromagnetic loss of the fault part of the transformer increases,and the temperature rises suddenly.The influence of the two faults on the internal temperature field of the transformer is different,and the influence of the inter turn short circuit fault on the temperature nearby is obvious.The analysis results can provide reference for the thermal fault interpretation and fault classification of transformer.
基金Project(11JJ3015)supported by the Natural Science Foundation of Hunan Province,China
文摘A polypyrrole-modified glassy carbon electrode （PPy/GC electrode） was prepared and its electrocatalytic behavior towards naphthoquinone in the presence of acid was characterized by linear sweep voltammetry （LSV）. A well-defined new reduction peak appeared at a more positive potential than the original reduction peak. The new reduction peak current was linearly related to the acid value （AV） of oil. Based on it, a rapid electrochemical method for determining AV of transformer oil was developed using PPy/GC electrode. A working curve was obtained in the AV range of 0.01 to 0.40 mg（KOH）.g^-1, with a sensitivity of 39.42 μA0.5/（mg（KOH）.g-l） and the detection limit of 0.0014 mg（KOH）.g^-1 （signal-to-noise ratio is 3, standard deviation is 2.247%）. Moreover, the proposed method has been successfully applied to AV determination of several transformer oil samples with advantages of rapidness, high sensitivity and accuracy compared to the conventional method.
文摘A new method, which is based on formation fracturing test and Kaiser effect method, has been developed for confirming the oilfield in-situ stress in this paper. The new method has been used in a certain oilfield of China and the determined oilfield in-situ stresses is more accurate than that based on one single method.
文摘A methodology for kinetic modeling of conversion processes is presented.The proposed approach allows to overcome the lack of molecular detail of the petroleum fractions and to simulate the reactions of the process by means of a two-step procedure.In the first step,a synthetic mixture of molecules representing the feedstock is generated via a molecular reconstruction method,termed SR-REM molecular reconstruction.In the second step,a kinetic Monte Carlo method,termed stochastic simulation algorithm(SSA),is used to simulate the effect of the conversion reactions on the mixture of molecules.The resulting methodology is applied to the Athabasca vacuum residue hydrocracking.An adequate molecular representation of the vacuum residue is obtained using the SR-REM algorithm.The reaction simulations present a good agreement with the laboratory data for Athabasca vacuum residue conversion.In addition,the proposed methodology provides the molecular detail of the vacuum residue conversion throughout the reactions simulations.
