从压电传感的发展看学科交叉创新

压电学原先是物理学的一个分支学科 ,主要在气相或真空中应用。它和化学、生物学、医学相互交叉 ,在理论、方法和应用上获得发展 ,形成压电化学与生物传感新领域。这从一个侧面表明 :多学科交叉渗透是实现创新发展的一个有效途径。

用于红外凝视成像系统的光学微扫描器

空间分辨力不足限制了凝视型红外焦平面探测器的发展,微扫描技术可以在不降低探测器热灵敏度的前提下提高成像系统的空间分辨力,同时可以扩大成像系统的视场。为此设计了一种基于新型压电驱动器的光学微扫描器。介绍了新型压电驱动器和扫描器的工作原理,测试了扫描器的频响特性。采用软件补偿和串联硬件陷波器相结合的开环控制方法,补偿压电陶瓷迟滞效应和抑制机械谐振,加控制器后的100Hz三角波扫描非线性度从6%减小到了1%,提高了扫描线性度,实现了高频三角波扫描。

压电光子学效应及其应用

近年来,压电光子学作为一个新兴的研究领域吸引了学者们的广泛关注.压电光子学效应是压电半导体的压电极化和光激发的耦合,是利用应变诱导的压电极化调控材料能带结构进而控制电子-空穴的复合发光过程.压电光子学效应为新光源、智能触觉传感和机械光子学等重要技术提供了研究基础,尤其结合第三代、第四代半导体材料同时具有压电效应和半导体特性的优势,有望实现高性能的力-致发光器件.本文简要介绍了压电光子学效应的基本原理、材料体系以及压电光子学器件的研究进展,并对这一学科的未来发展进行了展望.

复合型超声马达

介绍一种纵振－扭振复合式超声马达，同时给出了相应的等效电路分析方法以及马达工作特性的测量结果。该马达的最大机电转换效率为４．１３％．

Electrochemical migration behavior and mechanism of PCB-ImAg and PCB-HASL under adsorbed thin liquid films

The electrochemical migration（ECM） behavior and mechanism of immersion silver processing circuit board（PCB-ImAg）and hot air solder leveling circuit board（PCB-HASL） under the 0.1 mol/L Na2SO4 absorbed thin liquid films with different thicknesses were investigated using stereo microscopy and scanning electron microscopy（SEM）.Meanwhile,the corrosion tendency and kinetics rule of metal plates after bias application were analyzed with the aid of electrochemical impedance spectroscopy（EIS）and scanning Kelvin probe（SKP）.Results showed that under different humidity conditions,the amount of migrating corrosion products of silver for PCB-ImAg was limited,while on PCB-HASL both copper dendrites and precipitates such as sulfate and metal oxides of copper/tin were found under a high humidity condition（exceeding 85%）.SKP results indicated that the cathode plate of two kinds of PCB materials had a higher corrosion tendency after bias application.An ECM model involving multi-metal reactions was proposed and the differences of ECM behaviors for two kinds of PCB materials were compared.

Piezopotential augmented photo-and photoelectro-catalysis with a built-in electric field

Rapid technological development and population growth are responsible for a series of imminent environmental problems and an ineluctable energy crisis.The application of semiconductor nanomaterials in photocatalysis or photoelectrocatalysis(PEC)for either the degradation of contaminants in the environment or the generation of hydrogen as clean fuel is an effective approach to alleviate these problems.However,the efficiency of such processes remains suboptimal for real applications.Reasonable construction of a built-in electric field is considered to efficiently enhance carrier separation and reduce carrier recombination to improve catalytic performance.In the past decade,as a new method to enhance the built-in electric field,the piezoelectric effect from piezoelectric materials has been extensively studied.In this review,we provide an overview of the properties of piezoelectric materials and the mechanisms of piezoelectricity and ferroelectricity for a built-in electric field.Then,piezoelectric and ferroelectric polarization regulated built-in electric fields that mediate catalysis are discussed.Furthermore,the applications of piezoelectric semiconductor materials are also highlighted,including degradation of pollutants,bacteria disinfection,water splitting for H2 generation,and organic synthesis.We conclude by discussing the challenges in the field and the exciting opportunities to further improve piezo-catalytic efficiency.

Electrochemical hydrogen compression and purification versus competing technologies: Part Ⅱ. Challenges in electrocatalysis

Hydrogen will be at the basis of the World’s energy policy in forthcoming decades, owing to its decarbonized nature, at least when produced from renewables. For now, hydrogen is still essentially produced from fossil feedstock(and to a minor extent from biomass);in consequence the present hydrogen gas on the market is containing non-negligible amounts of impurities that prevent its immediate usage in specialty chemistry or as an energy carrier in fuel cells, e.g. in transportation applications(cars, buses, trains, boats, etc.) that gradually spread on the planet. For these purposes, hydrogen must be of sufficient purity but also sufficiently compressed(at high pressures, typically 70 MPa), rendering purification and compression steps unavoidable in the hydrogen cycle. As shown in the first part of this contribution "Electrochemical hydrogen compression and purification versus competing technologies: Part I. pros and cons", electrochemical hydrogen compressors(EHCs), which enable both hydrogen purification and compression, exhibit many theoretical(thermodynamic) and practical(kinetics) advantages over their mechanical counterparts. However, in order to be competitive, EHCs must operate in very intensive conditions(high current density and low cell voltage) that can only be reached if their core materials, e.g. the membrane and the electrodes/electrocatalysts, are optimized. This contribution will particularly focus on the properties electrocatalysts must exhibit to be used in EHCs: they shall promote(very) fast hydrogen oxidation reaction(HOR) in presence of impurities, which implies that they are(very) tolerant to poisons as well. This consists of a prerequisite for the operation of the anode of an EHC used for the purification-compression of hydrogen, and the materials developed for poison-tolerance in the vast literature on low-temperature fuel cells, may not always satisfy these two criteria, as this contribution will review.

Electrochemical hydrogen compression and purification versus competing technologies: Part Ⅰ. Pros and cons

It is undisputed that hydrogen will play a great role in our future energetic mix, because it enables the storage of renewable electricity(power-to-H2) and the reversible conversion into electricity in fuel cell, not to speak of its wide use in the(petro)chemical industry. Whereas in these applications, pure hydrogen is required, today’s hydrogen production is still largely based on fossil fuels and can therefore not be considered pure. Therefore, purification of hydrogen is mandatory, at a large scale. In addition, hydrogen being the lightest gas, its volumetric energy content is well-below its competing fuels, unless it is compressed at high pressures(typically 70 MPa), making compression unavoidable as well. This contribution will detail the means available today for both purification and for compression of hydrogen. It will show that among the available technologies, the electrochemical hydrogen compressor(EHC), which also enables hydrogen purification, has numerous advantages compared to the classical technologies currently used at the industrial scale. EHC has their thermodynamic and operational advantages, but also their ease of use. However, the deployment of EHCs will be viable only if they reach sufficient performances, which implies some specifications that their base materials should stick to. The present contribution will detail these specifications.

Avoidant Learning Ability in Free Flying Housefly (Aldrichina grahami) by Electric Shock

Previous studies have confirmed that both honeybee and Drosophila are capable of learning and memory. This study aimed to investigate whether the house fly （Aldrichina grahami）, with strong instincts to adapt their living environment, have the learning ability to associate odor stimulus to avoid electric shock in free flying state using a device developed by the authors. The result showed the learning ability ofA. grahami at the electric shock voltages of 5 V, 25 V and 45 V AC. When 60 V was used, the flies were frequently injured. Our results indicate that A. grahami is a good model to study the neural mechanism of learning and memory. The paradigm in this study has some advantages that can be used in future studies of free insects.

A variational energy approach for electromechanical analysis of thick piezoelectric beam

A new two dimensional coupled electromechanical model for a thick, laminated beam with piezoelectric and isotropic lamina subjected to static external electric loading is developed. The model combined the first order shear deformation theory for the relatively thick elastic core and linear piezoelectric theory for the piezoelectric lamina. The actuation response is induced through the application of external electric voltage. Rayleigh-Ritz method is adopted to model the displacement and potential fields of the beam and governing equations were finally derived from the variational energy principle. The model allows the piezoelectric lamina to be formulated via a two-dimensional model because of the strong electro-mechanical coupling and the presence of a two-dimensional electric field. Numerical examples of piezoelectric laminated beam are presented. It is shown in this paper that a one-dimensional model for the piezoelectric beam-like layer is inadequate.

Multi-Physics Modeling of Solid Oxide Fuel Cell Fueled by Methane and Analysis of Carbon Deposition

Internal reformation of low steam methane fuel is important for the high efficiency and low cost operation of solid oxide fuel cell. Understanding and overcoming carbon deposition is crucial for the technology development. Here a multi-physics model is established for the relevant experimental cells. Balance of electrochemical potentials for the electrochemical reactions, generic rate expression for the methane steam reforming, dusty gas model in a form of Fick＇s model for anode gas transport are used in the model. Excellent agreement between the theoretical and experimental current-voltage relations is obtained, demonstrating the validity of the proposed theoretical model. The steam reaction order in low steam methane reforming reaction is found to be 1. Detailed information about the distributions of physical quantities is obtained by the numerical simulation. Carbon deposition is analyzed in detail and the mechanism for the coking inhibition by operating current is illustrated clearly. Two expressions of carbon activity are analyzed and found to be correct qualitatively, but not quantitatively. The role of anode diffusion layer on reducing the current threshold for carbon removal is also explained. It is noted that the current threshold reduction may be explained quantitatively with the carbon activity models that are only qualitatively correct.

Microscopic mechanical characteristics analysis of ultranano-crystalline diamond films

The microscopic mechanical characteristics of ultranano-crystalline diamond films which were prepared in four different atmospheres were investigated for the applications in microelectron-mechanical system（MEMS）.The loading-unloading curves and the change of modulus and hardness of samples along with depth were achieved through nanoindenter.The results show that the films which are made in atmosphere without Ar have the highest recovery of elasticity,hardness（72.9 GPa） and elastic modulus（693.7 GPa） among the samples.Meanwhile,samples fabricated at a low Ar content have higher hardness and modulus.All the results above demonstrate that atmosphere without Ar or low Ar content leads to better mechanical properties of nanodiamond films that are the candidates for applications in MEMS.

Dynamic anti-plane characteristic on an infinite piezoelectric medium with a movable rigid cylindrical inclusion

Scattering and dynamic stress concentrations of time harmonic SH-wave in an infinite elastic piezoelectric medium with a movable rigid cylindrical inclusion are studied in this paper with the help of complex variable and wave function expansion method. The relations that a movable rigid cylindrical inclusion depends on intensity of incident wave and electric field are revealed. The expressions of dynamic stress at the edge of the inclusion are obtained. Numerical calculations are made with different wave numbers and different piezoelectric characteristic parameters. The calculating results show that dynamic stress concentrations at the edge of the inclusion have linear dependence on the incident electric field. And dynamic analyses are very important for an infinite piezoelectric medium with a movable rigid cylindrical inclusion at larger piezoelectric characteristic parameters.

Transparent Electronic Skin Device Based on Microstructured Silver Nanowire Electrode

Transparent, flexible electronic skin holds a wide range of applications in robotics, humanmachine interfaces, artificial intelligence, prosthetics, and health monitoring. Silver nanowire are mechanically flexible and robust, which exhibit great potential in transparent and electricconducting thin film. Herein, we report on a silver-nanowire spray-coating and electrodemicrostructure replicating strategy to construct a transparent, flexible, and sensitive electronic skin device. The electronic skin device shows highly sensitive piezo-capacitance response to pressure. It is found that micropatterning the surface of dielectric layer polyurethane elastomer by replicating from microstructures of natural-existing surfaces such as lotus leaf, silk, and frosted glass can greatly enhance the piezo-capacitance performance of the device. The microstructured pressure sensors based on silver nanowire exhibit good transparency, excellent flexibility, wide pressure detection range （0-150 kPa）, and high sensitivity （1.28 kPa-1）.

Corrosion performance of high pressure die-cast Al-6Si-3Ni and Al-6Si-3Ni-2Cu alloys in aqueous NaCl solution

The corrosion performance of high pressure die-cast Al？6Si？3Ni （SN63） and Al-6Si-3Ni-2Cu （SNC632） alloys in 3.5%（mass fraction） NaCl solution was investigated. X-ray diffraction （XRD） and microstructural studies revealed the presence of singlephase Si and binary Al3Ni/Al3Ni2 phases along the grain boundary. Besides, the single Cu phase was also identified at the grainboundaries of the SNC632 alloy. Electrochemical corrosion results revealed that, the SNC632 alloy exhibited nobler shift incorrosion potential （φcorr）, lower corrosion current density （Jcorr） and higher corrosion resistance compared to the SN63 alloy.Equivalent circuit curve fitting analysis of electrochemical impedance spectroscopy （EIS） results revealed the existence of twointerfaces between the electrolyte and substrate. The surface layer and charge transfer resistance （Rct） of the SNC632 alloy was higherthan that of the SN63 alloy. Immersion corrosion test results also confirmed the lower corrosion rate of the SNC632 alloy andsubstantiated the electrochemical corrosion results. Cu addition improved the corrosion resistance, which was mainly attributed to theabsence of secondary Cu containing intermetallic phases in the SNC632 alloy and Cu presented as single phase.

Electro-rheological Effect of Barium Titanate Particles Coated with Urea and Suspended in Methyl Silicone Oil

Barium titanate nano-powders were synthesized under defined conditions. The surface of these particles was successfully modified by coating with urea. The characteristics of these composite particles were studied by X-ray diffraction,transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy. The electro-rheological (ER) effects of these particles suspended in methyl-silicone oil were measured. The particle,methyl-silicon oil ratio was 30%-35% weight percent. The experimental results indicate that these ER particles exhibit a remarkable ER effect. The ER fluid shows Bingham characteristics and the static shearing stress increases with an increase of the electric field strength. The highest static shearing stress under a 4 MV/m electric field is 13.2 kPa at room temperature,an increase of about 8.7 kPa compared to untreated BaTiO(C2O4)2 powders.

Invariants and Quantum Fluctuations of a Mesoscopic RLC Circuit in a Squeezed State and Squeezed Number State

The invariants for a mesoscopic RLC circuit with a power source are studied and used to construct the squeezed states and squeezed number states for the system. The quantum fluctuations of the mesoscopic RLC circuit in the squeezed states and squeezed number states are also investigated.

Investigating the potential of using acoustic frequency on the degradation of linear alkylbenzen sulfonates from aqueous solution

The effectiveness of using acoustical （sonochemical） reactor for degradation of linear alkylbenzen sulfonate （LAS） from aqueous solution was investigated. LASs are anionic surfactants, found in relatively high amounts in domestic and industrial wastewaters. In this study, experiments on LAS solution were performed using methylene blue active substances （MBAS） method. The effectiveness of acoustical processor reactor for LAS degradation is evaluated with emphasis on the effect of treatment time and initial LAS concentration. Experiments were performed at initial concentrations of 0.2, 0.5, 0.8 and 1.0 mg/L, acoustic frequency of 130 kHz, applied power of 500 W and temperature of 18℃-20℃. At the conditions involved, LAS degradation was found to increase with increasing sonochemical time. In addition, as the concentration increased, the LAS degradation rate decreased in the acoustical processor reactor.

Research on an inertial piezoelectric actuator for a micro in-pipe robot

A new kind of inertial piezoelectric actuator for a micro in-pipe robot is proposed and studied. The actuator is composed of a body, corresponding to a mass rod, and four elastic legs. Each leg is a composite piezoelectric bimorph beam, made up of a middle metal element, an upper and lower piezoelectric elements. The mechanism is driven by an asymmetric waveform voltage, such as saw-toothed waveform, and utilizes the dynamic relationship between the maximum static friction force and the inertial force. To study the actuator, firstly, the constituent equation of a composite piezoelectric bimorph under both applied voltage and external force was inferred by thermodynamics. Secondly, the dvnamic model of the actuator was established analyzing the relationship between the locomotive states, viz. displacement and velocity, and design parameters, such as piezoelectric strain constant, elastic modulus,length, width and thickness of the piezoelectric element, actuator mass, and driving vohage. At last, the dynamic equation was solved and the theoretical calculation of the inherent frequency was more consistent with the experimental data, which proved the rationality of the model. All these lay a theoretical foundation of the micro actuator parameter optimization and more research on a micro robot.

Modeling of sensor function for piezoelectric bender elements

An analytical sandwich beam model for piezoelectric bender elements is derived based on the first-order shear deformation theory (FSDT), which assumes a single rotation angle for the whole cross-section and a quadratic distribution for coupled electric potential in piezoelectric layers. Shear coefficient is introduced to correct the effect of transverse shear strain on shear force and the electric displacement integration. Static and free vibration analyses of simply-supported bender elements are carried out for the sensor function. The results illustrate the high accuracy of the present model compared with the exact 2D solutions.