锰对ZA27合金压蠕变行为的影响

采用自制的实验装置研究了锰对 ZA2 7合金在常温及高温时的压蠕变行为的影响。研究表明 ,在所试验的温度为 2 0℃到 16 0℃和压应力为 5 0 MPa到 137.5 MPa的范围内 ,加入锰的合金 ZA2 7- Mn和未加锰的 ZA2 7合金的压蠕变量均随着温度和应力的升高而增大 ,ZA2 7- Mn合金的压蠕变速率小于 ZA2 7合金的压蠕变速率。加入锰后 ,合金在压蠕变过程中的负蠕变量及出现负蠕变的温度和应力范围增大。两种合金的稳态蠕变速率均符合于半经验公式 εs=Aσnexp(- Qa/RT)。但在不同的温度 ,ZA2 7- Mn合金的应力指数 n和表观激活能 Qa 均大于 ZA2 7合金的应力指数和表观激活能 ,而 ZA2 7- Mn合金的材料结构常数 A为 1.5 4× 10 - 4,低于 ZA2 7合金的材料结构常数 A(0 .0 0 2 )。两种合金的稳态蠕变速率均是由锌的点阵自扩散和位错的攀移所控制。

锆对ZA27合金压蠕变行为的影响

采用自制的压蠕变试验装置研究了锆对ZA2 7合金压蠕变行为的影响。结果表明 ,在试验温度 2 0℃～ 1 60℃和压应力 50MPa～ 1 37 5MPa范围内 ,ZA2 7 Zr和ZA2 7合金压蠕变第一阶段的变形量和稳态蠕变速率随着温度和应力的增高而增大 ,但在 1 0 0℃以下时 ,ZA2 7 Zr合金第一阶段的蠕变量及稳态蠕变速率低于ZA2 7合金 ,合金的压蠕变抗力高于ZA2 7合金 ,在 1 60℃则相反。合金的压蠕变行为可用等式 :lnt=C -nlnσ +Q RT表达 ,其中 ,材料结构常数C不同导致两种合金的蠕变行为不同。ZA2 7 Zr合金的应力指数n和蠕变激活能Q分别为 3 63和 87 32kJ·mol-1 ,ZA2 7合金的应力指数和蠕变激活能分别为 3 46和 81 0 9kJ·mol-1 。表明Zr的加入并不影响ZA2 7合金的蠕变机制 。

Microstructures,mechanical properties and compressive creep behaviors of as-cast Mg-5%Sn-(0-1.0)%Pb alloys

The microstructures,tensile properties and compressive creep behaviors of Mg-5%Sn-(0-1.0)%Pb (mass fraction) alloys were studied. The microstructures of the Mg-Sn-Pb alloys consist of dendritic α-Mg and Mg2Sn phase. The addition of Pb can refine the size of Mg-2Sn phase and grain size,reduce the amount of Mg-2Sn phase at grain or inter-dendrite boundaries and change the distribution of Mg-2Sn phase. Pb exists in the Mg-2Sn phase or dissolves in α-Mg matrix. The mechanical properties of the tested alloys at room temperature are improved with the addition of Pb. When the Pb content is over 0.5%,the mechanical properties are decreased gradually. The Mg-5%Sn-0.5%Pb shows the best ultimate tensile strength and elongation,174 MPa and 14.3%,respectively. However,the compressive creep resistance of the Mg-Sn-Pb alloys is much lower than that of the Mg-Sn binary alloy at 175 °C with applied load of 55 MPa,which means that Pb has negative effects on the compressive creep resistance of the as-cast Mg-Sn alloys.