Endohedral metallofullerene Gd@C2n were synthesized with high-yield using the carbon-arc discharge method of activating the Gd2O3-containing graphite anode in situ and back-burning technique. A series of Cd@C（2n） fo...Endohedral metallofullerene Gd@C2n were synthesized with high-yield using the carbon-arc discharge method of activating the Gd2O3-containing graphite anode in situ and back-burning technique. A series of Cd@C（2n） for 2n from 70 to 96 were effectively extracted by toluene at high-temperature and under high-pressure condition. Gd@C（82）,Gd@C（74） were considered to be fairly stable and soluble metallofullerene species.展开更多
文摘Endohedral metallofullerene Gd@C2n were synthesized with high-yield using the carbon-arc discharge method of activating the Gd2O3-containing graphite anode in situ and back-burning technique. A series of Cd@C（2n） for 2n from 70 to 96 were effectively extracted by toluene at high-temperature and under high-pressure condition. Gd@C（82）,Gd@C（74） were considered to be fairly stable and soluble metallofullerene species.
