期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
原位蒸汽辅助法用于一步制备多级孔Cu-BTC
1
作者 代艳辉 熊启钊 +5 位作者 房强 杨东晓 王毅 陈杨 李晋平 李立博 《化工学报》 EI CSCD 北大核心 2024年第9期3329-3337,共9页
金属有机骨架材料(MOF)因其比表面积大、孔隙率高、结构高度可调等优势在气体吸附分离、催化、传感及生物医学等领域展现出巨大的应用潜力。但大多数MOF的孔结构在微孔范围,狭窄的孔隙环境限制了其应用过程中的传质扩散以及活性位点释放... 金属有机骨架材料(MOF)因其比表面积大、孔隙率高、结构高度可调等优势在气体吸附分离、催化、传感及生物医学等领域展现出巨大的应用潜力。但大多数MOF的孔结构在微孔范围,狭窄的孔隙环境限制了其应用过程中的传质扩散以及活性位点释放,在微孔MOF结构的基础上进行多级孔的构建则可以解决这一问题。为实现经典Cu-BTC结构上的多级孔构筑,基于原位蒸汽辅助合成加刻蚀过程开发了一步制备多级孔Cu-BTC的新方法。通过绿色刻蚀剂乙酸用量、蒸汽辅助时间的调节,获得了孔径范围可调的多级孔Cu-BTC。由于多级孔结构对传质过程和活性位点的提升作用,该材料在CO_(2)电还原实验中展现出优秀的转化效率,最高乙烯的选择性可提升157%。通过蒸汽辅助耦合材料制备和刻蚀过程使得多级孔MOF的一步制备成为了可能,其具有的减少反应物用量和反应步骤的特点将进一步推动多级孔MOF在实际应用中的发展。 展开更多
关键词 金属有机骨架 多级孔 原位蒸汽辅助 一步制备 绿色刻蚀
下载PDF
Measurement of Viscosity Alteration for Emulsion and Numerical Simulation on Bitumen Production by SAGD Considering In-situ Emulsification
2
作者 Junpei Kumasaka Kyuro Sasaki +2 位作者 Yuichi Sugail Olalekan S. Alade Masanori Nakano 《Journal of Earth Science and Engineering》 2016年第1期10-17,共8页
A thermal steam stimulation process, such as steam-assisted gravity drainage (SAGD), induces water-in-oil emulsion of heavy oil or bitumen throughout the production. The present study investigated the effects of in-... A thermal steam stimulation process, such as steam-assisted gravity drainage (SAGD), induces water-in-oil emulsion of heavy oil or bitumen throughout the production. The present study investigated the effects of in-situ emulsification in the oil sands reservoir for SAGD process. The viscosities of water-in-oil emulsions produced were measured with respect to water-oil ratio (W/O), shear rates, pressures and temperatures. The results therefore were employed to develop the numerical model of viscosity alteration. Numerical simulations of the SAGD bitumen production considering viscosity alteration were also carried out to investigate distribution characteristics of emulsion, water, and bitumen at steam chamber boundary and effects of in-situ emulsification on bitumen production behavior. With a model named SAGD-Emulsion Model, it was found that the net recovery factor of bitumen for this model is 5 to 10% higher than that of conventional SAGD simulation. Ultimately, it was found that the recovery factor of bitumen increased with W/O of emulsion generated in the reservoir since higher water content would invariably allow bitumen to flow at higher relative permeability, while the increase in viscosity merely delayed bitumen production. 展开更多
关键词 Viscosity alteration BITUMEN EMULSION in-situ emulsification SAGD.
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部