Grassland fire is one of the most important disturbance factors in the natural ecosystems.This paper focuses on the spatial distribution of long-term grassland fire patterns in the Hulun Buir Grassland located in the ...Grassland fire is one of the most important disturbance factors in the natural ecosystems.This paper focuses on the spatial distribution of long-term grassland fire patterns in the Hulun Buir Grassland located in the northeast of Inner Mongolia Autonomous Region in China.The density or ratio of ignition can reflect the relationship between grassland fire and different ignition factors.Based on the relationship between the density or ratio of ignition in different range of each ignition factor and grassland fire events,an ignition probability model was developed by using binary logistic regression function and its overall accuracy averaged up to 81.7%.Meanwhile it was found that daily relative humidity,daily temperature,elevation,vegetation type,distance to county-level road,distance to town are more important determinants of spatial distribution of fire ignitions.Using Monte Carlo method,we developed a time-dependent stochastic ignition probability model based on the distribution of inter-annual daily relative humidity and daily temperature.Through this model,it is possible to estimate the spatial patterns of ignition probability for grassland fire,which will be helpful to the quantitative evaluation of grassland fire risk and its management in the future.展开更多
An account of recent work on supported single‐atom catalyst design is given here for reactions as diverse as the low‐temperature water‐gas shift,methanol steam reforming,selective ethanol dehydrogenation,and select...An account of recent work on supported single‐atom catalyst design is given here for reactions as diverse as the low‐temperature water‐gas shift,methanol steam reforming,selective ethanol dehydrogenation,and selective hydrogenation of alkynes and dienes.It is of fundamental interest to investigate the intrinsic activity and selectivity of the active metal atom site and compare them to the properties of the corresponding metal nanoparticles and sub‐nm clusters.It is also important to understand what constitutes a stable active metal atom site in the various reaction environments,and maximize their loadings to allow us to design robust catalysts for industrial applications.Combined activity and stability studies,ideally following the evolution of the active site as a function of catalyst treatment in real time are recommended.Advanced characterization methods with atomic resolution will play a key role here and will be used to guide the design of new catalysts.展开更多
This paper proposes a numerical methodology for the prediction of the first three modes of vibration of an electric motor fixed on a rigid base. A deep literature review supported the production of four ad hoc prototy...This paper proposes a numerical methodology for the prediction of the first three modes of vibration of an electric motor fixed on a rigid base. A deep literature review supported the production of four ad hoc prototypes that aided the development of the proposed approach. Tests carried out with the prototypes led to the procurement of the modal parameters be used to calibrate the numerical models, as well as the FRF (frequency response function) curves be used to validate the numerical solution. The validated model allowed structural changes to be then promoted on the prototypes, in order to make them more robust to variations in manufacturing and assembling processes. The mentioned adjustments and structural changes were accomplished by means of a process of structural optimization using Genetic Algorithm. The solution was developed based on the commercial finite element code ANSYS. The practical results obtained in this study show that a numerical model for modal analysis of an electric motor fixed on a rigid base with errors less than 3% for the first three modes of vibration can be achieved, allowing positive structural changes to be performed in the machine design that result in the minimization of manufacturing reworks associated with the dynamic behavior of the studied motor.展开更多
The ability of 42 Coupled Model Intercomparison Project Phase 5(CMIP5) models in simulating the annual and seasonal temperature and precipitation over China is first examined by using their historical experiments for ...The ability of 42 Coupled Model Intercomparison Project Phase 5(CMIP5) models in simulating the annual and seasonal temperature and precipitation over China is first examined by using their historical experiments for 1986–2005, and then 39 relatively reliable models are chosen to project temperature and precipitation changes against the natural internal variability over the country under the Representative Concentration Pathways(RCP) scenarios in the 21 st century. The result shows the temperature continuing to increase, especially in northern China. The annual warming for 2081–2099 relative to 1986–2005 over the whole of the country is larger than the background variability, with the multimodel median changes under RCP2.6, RCP4.5, RCP6.0, and RCP8.5 being 9.9, 19.3, 22.8, and 35.9 times greater than one standard deviation of internal variability, respectively. The annual precipitation is projected to increase by 6.1%, 9.3%, 9.6%, and 16.2% for 2081–2099 relative to 1986–2005 under RCP2.6, RCP4.5, RCP6.0, and RCP8.5 respectively, while large changes with high model agreement only occur over the northern Tibetan Plateau and Northeast China, which is mainly due to the robust changes in winter and spring under RCP6.0 and RCP8.5.展开更多
The mainstream depth of a return flow can be viewed as an intrinsic depth of horizontal convection. By using a theoretical tube model combined with the application of the Maximum Entropy Production Principle (MaxEPP) ...The mainstream depth of a return flow can be viewed as an intrinsic depth of horizontal convection. By using a theoretical tube model combined with the application of the Maximum Entropy Production Principle (MaxEPP) in thermodynamics, the following statements can be made. Under fixed external forcing, the system chooses a particular depth as the mainstream depth of its return flow, the depth of which not only satisfies the maximum circulation rate and the maximum heat transport, but also satisfies the maximum entropy production rate. A comparison between this intrinsic depth and the container height leads to the definition of a relative partial and full-penetration pattern of the circulation. Moreover, this intrinsic depth is found to vary with the external forcing; the regulation of this variation is related to the Modified Rayleigh number.展开更多
We investigated seasonal variations in cyanobacterial biomass and the forms of its dominant population (M. aeruginosa) and their correlation with environmental factors in the water source area of Chaohu City, China ...We investigated seasonal variations in cyanobacterial biomass and the forms of its dominant population (M. aeruginosa) and their correlation with environmental factors in the water source area of Chaohu City, China from December 2011 to October 2012. The results show that species belonging to the phylum Cyanophyta occupied the maximum proportion of phytoplankton biomass, and that the dominant population in the water source area of Chaohu City was M. aeruginosa. The variation in cyanobacterial biomass from March to August 2012 was well fitted to the logistic growth model. The growth rate of cyanobacteria was the highest in June, and the biomass of cyanobacteria reached a maximum in August. From February to March 2012, the main form of M. aeruginosa was the single-cell form; M. aeruginosa colonies began to appear from April, and blooms appeared on the water surface in May. The maximum diameter of the colonies was recorded in July, and then gradually decreased from August. The diameter range ofM. aeruginosa colonies was 18.37-237.77μm, and most of the colonies were distributed in the range 20-200μm, comprising 95.5% of the total number of samples. Temperature and photosynthetically active radiation may be the most important factors that influenced the annual variation in M. aeruginosa biomass and forms. The suitable temperature for cyanobaeterial growth was in the range of 15-30℃. In natural water bodies, photosynthetically active radiation had a significant positive influence on the colonial diameter of M. aeruginosa (P〈0.01).展开更多
The pyrolysis of zeolitic imidazolate frameworks(ZIFs) is becoming a popular approach for the synthesis of catalysts comprising porphyrin-like metal single atom catalysts(SACs) on N-doped carbons(M-N-C).Understanding ...The pyrolysis of zeolitic imidazolate frameworks(ZIFs) is becoming a popular approach for the synthesis of catalysts comprising porphyrin-like metal single atom catalysts(SACs) on N-doped carbons(M-N-C).Understanding the structural evolution of M-N-C as a function of ZIF pyrolysis temperature is important for realizing high performance catalysts.Herein,we report a detailed investigation of the evolution of Zn single atom catalyst sites during the pyrolysis of ZIF-8 at temperatures ranging from 500 to 900℃.Results from Zn L-edge and Zn K-edge X-ray absorption spectroscopy studies reveal that tetrahedral ZnN4 centers in ZIF-8 transform to porphyrin-like ZnN4 centers supported on N-doped carbon at temperatures as low as 600℃.As the pyrolysis temperature increased in the range 600-900℃,the Zn atoms moved closer to the N4 coordination plane.This subtle geometry change in the ZnN4 sites alters the electron density on the Zn atoms(formally Zn2+),strongly impacting the catalytic performance for the peroxidase-like decomposition of H2 O2.The catalyst obtained at 800℃(Zn-N-C-800) offered the best performance for H2 O2 decomposition.This work provides valuable new insights about the evolution of porphyrin-like single metal sites on N-doped carbons from ZIF precursors and the factors influencing SAC activity.展开更多
Influences of water head variations on the performances of a prototype reversible pump turbine are experimentally studied in generating mode within a wide range of load conditions(from 25% to 96% of the rated power). ...Influences of water head variations on the performances of a prototype reversible pump turbine are experimentally studied in generating mode within a wide range of load conditions(from 25% to 96% of the rated power). The pressure fluctuations of the reversible pump turbine at three different water heads(with non-dimensional values being 0.48, 0.71 and 0.90) are measured and compared based on the pressure data recorded in the whole flow passage of the turbine. Furthermore, effects of monitoring points and load variations on the impeller-induced unstable behavior(e.g. blade passing frequency and its harmonics) are quantitatively discussed. Our findings reveal that water head variations play a significant role on the pressure fluctuations and their propagation mechanisms inside the reversible pump turbine.展开更多
We develop a model for the effect of thermal annealing on forming In--N dusters in GalnNP according to thermodynamics. The average energy variation for forming an In--N bond in the model is estimated according to the ...We develop a model for the effect of thermal annealing on forming In--N dusters in GalnNP according to thermodynamics. The average energy variation for forming an In--N bond in the model is estimated according to the theoretical calculation. Using the model, the added number of In--N bonds per mol of InGaNP, the added number of nearest-neighbor In atoms per N atom and the average number of nearest-neighbor In atoms per N atom after annealing are calculated. The different function of In--N clusters in InGaNP and InGaN is also discussed, which is due to the different environments around the In--N clusters.展开更多
基金Under the auspices of National Science & Technology Support Program of China(No.2006BAD20B00)
文摘Grassland fire is one of the most important disturbance factors in the natural ecosystems.This paper focuses on the spatial distribution of long-term grassland fire patterns in the Hulun Buir Grassland located in the northeast of Inner Mongolia Autonomous Region in China.The density or ratio of ignition can reflect the relationship between grassland fire and different ignition factors.Based on the relationship between the density or ratio of ignition in different range of each ignition factor and grassland fire events,an ignition probability model was developed by using binary logistic regression function and its overall accuracy averaged up to 81.7%.Meanwhile it was found that daily relative humidity,daily temperature,elevation,vegetation type,distance to county-level road,distance to town are more important determinants of spatial distribution of fire ignitions.Using Monte Carlo method,we developed a time-dependent stochastic ignition probability model based on the distribution of inter-annual daily relative humidity and daily temperature.Through this model,it is possible to estimate the spatial patterns of ignition probability for grassland fire,which will be helpful to the quantitative evaluation of grassland fire risk and its management in the future.
基金financial support of the work by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES), under Awards Grant Number DE-FG02-05ER15730
文摘An account of recent work on supported single‐atom catalyst design is given here for reactions as diverse as the low‐temperature water‐gas shift,methanol steam reforming,selective ethanol dehydrogenation,and selective hydrogenation of alkynes and dienes.It is of fundamental interest to investigate the intrinsic activity and selectivity of the active metal atom site and compare them to the properties of the corresponding metal nanoparticles and sub‐nm clusters.It is also important to understand what constitutes a stable active metal atom site in the various reaction environments,and maximize their loadings to allow us to design robust catalysts for industrial applications.Combined activity and stability studies,ideally following the evolution of the active site as a function of catalyst treatment in real time are recommended.Advanced characterization methods with atomic resolution will play a key role here and will be used to guide the design of new catalysts.
文摘This paper proposes a numerical methodology for the prediction of the first three modes of vibration of an electric motor fixed on a rigid base. A deep literature review supported the production of four ad hoc prototypes that aided the development of the proposed approach. Tests carried out with the prototypes led to the procurement of the modal parameters be used to calibrate the numerical models, as well as the FRF (frequency response function) curves be used to validate the numerical solution. The validated model allowed structural changes to be then promoted on the prototypes, in order to make them more robust to variations in manufacturing and assembling processes. The mentioned adjustments and structural changes were accomplished by means of a process of structural optimization using Genetic Algorithm. The solution was developed based on the commercial finite element code ANSYS. The practical results obtained in this study show that a numerical model for modal analysis of an electric motor fixed on a rigid base with errors less than 3% for the first three modes of vibration can be achieved, allowing positive structural changes to be performed in the machine design that result in the minimization of manufacturing reworks associated with the dynamic behavior of the studied motor.
基金supported by the National Basic Research Program of China(Grant No.2012CB955401)the National Natural Science Foundation of China(Grant No.41375084)
文摘The ability of 42 Coupled Model Intercomparison Project Phase 5(CMIP5) models in simulating the annual and seasonal temperature and precipitation over China is first examined by using their historical experiments for 1986–2005, and then 39 relatively reliable models are chosen to project temperature and precipitation changes against the natural internal variability over the country under the Representative Concentration Pathways(RCP) scenarios in the 21 st century. The result shows the temperature continuing to increase, especially in northern China. The annual warming for 2081–2099 relative to 1986–2005 over the whole of the country is larger than the background variability, with the multimodel median changes under RCP2.6, RCP4.5, RCP6.0, and RCP8.5 being 9.9, 19.3, 22.8, and 35.9 times greater than one standard deviation of internal variability, respectively. The annual precipitation is projected to increase by 6.1%, 9.3%, 9.6%, and 16.2% for 2081–2099 relative to 1986–2005 under RCP2.6, RCP4.5, RCP6.0, and RCP8.5 respectively, while large changes with high model agreement only occur over the northern Tibetan Plateau and Northeast China, which is mainly due to the robust changes in winter and spring under RCP6.0 and RCP8.5.
基金Supported by the The National Basic Research Program (973 Program) (Nos. 2007CB816004, 2005CB422302)the National Outstanding Youth Natural Science Foundation of China (No. 40725017)
文摘The mainstream depth of a return flow can be viewed as an intrinsic depth of horizontal convection. By using a theoretical tube model combined with the application of the Maximum Entropy Production Principle (MaxEPP) in thermodynamics, the following statements can be made. Under fixed external forcing, the system chooses a particular depth as the mainstream depth of its return flow, the depth of which not only satisfies the maximum circulation rate and the maximum heat transport, but also satisfies the maximum entropy production rate. A comparison between this intrinsic depth and the container height leads to the definition of a relative partial and full-penetration pattern of the circulation. Moreover, this intrinsic depth is found to vary with the external forcing; the regulation of this variation is related to the Modified Rayleigh number.
基金Supported by the Major Science and Technology Program for Water Pollution Control and Treatment of China(Nos.2012ZX07103-005-01,2012ZX07103-004-02)the National Natural Science Foundation of China(Nos.41171366,41471075)the Science Foundation of Nanjing Institute of Geography and Limnology,Chinese Academy of Sciences(No.NIGLAS2012135013)
文摘We investigated seasonal variations in cyanobacterial biomass and the forms of its dominant population (M. aeruginosa) and their correlation with environmental factors in the water source area of Chaohu City, China from December 2011 to October 2012. The results show that species belonging to the phylum Cyanophyta occupied the maximum proportion of phytoplankton biomass, and that the dominant population in the water source area of Chaohu City was M. aeruginosa. The variation in cyanobacterial biomass from March to August 2012 was well fitted to the logistic growth model. The growth rate of cyanobacteria was the highest in June, and the biomass of cyanobacteria reached a maximum in August. From February to March 2012, the main form of M. aeruginosa was the single-cell form; M. aeruginosa colonies began to appear from April, and blooms appeared on the water surface in May. The maximum diameter of the colonies was recorded in July, and then gradually decreased from August. The diameter range ofM. aeruginosa colonies was 18.37-237.77μm, and most of the colonies were distributed in the range 20-200μm, comprising 95.5% of the total number of samples. Temperature and photosynthetically active radiation may be the most important factors that influenced the annual variation in M. aeruginosa biomass and forms. The suitable temperature for cyanobaeterial growth was in the range of 15-30℃. In natural water bodies, photosynthetically active radiation had a significant positive influence on the colonial diameter of M. aeruginosa (P〈0.01).
基金supported by the Ministry of Business, Innovation and Employment Catalyst Fund (MAUX 1609)the University of Auckland Faculty Research Development Fund+1 种基金the MacDiarmid Institute for Advanced Materials and Nanotechnologya generous philanthropic donation from Greg and Kathryn Trounson。
文摘The pyrolysis of zeolitic imidazolate frameworks(ZIFs) is becoming a popular approach for the synthesis of catalysts comprising porphyrin-like metal single atom catalysts(SACs) on N-doped carbons(M-N-C).Understanding the structural evolution of M-N-C as a function of ZIF pyrolysis temperature is important for realizing high performance catalysts.Herein,we report a detailed investigation of the evolution of Zn single atom catalyst sites during the pyrolysis of ZIF-8 at temperatures ranging from 500 to 900℃.Results from Zn L-edge and Zn K-edge X-ray absorption spectroscopy studies reveal that tetrahedral ZnN4 centers in ZIF-8 transform to porphyrin-like ZnN4 centers supported on N-doped carbon at temperatures as low as 600℃.As the pyrolysis temperature increased in the range 600-900℃,the Zn atoms moved closer to the N4 coordination plane.This subtle geometry change in the ZnN4 sites alters the electron density on the Zn atoms(formally Zn2+),strongly impacting the catalytic performance for the peroxidase-like decomposition of H2 O2.The catalyst obtained at 800℃(Zn-N-C-800) offered the best performance for H2 O2 decomposition.This work provides valuable new insights about the evolution of porphyrin-like single metal sites on N-doped carbons from ZIF precursors and the factors influencing SAC activity.
基金supported by the National Natural Science Foundation of China(Grant No.51506051)the Fundamental Research Funds for the Central Universities(Grant No.JB2015RCY04)+2 种基金the Open Research Fund Program of Key Laboratory of Fluid and Power Machinery(Xihua University)Ministry of Education(Grant No.szjj-2017-100-1-001)the Open Research Fund Program of State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(Grant No.LAPS16014)
文摘Influences of water head variations on the performances of a prototype reversible pump turbine are experimentally studied in generating mode within a wide range of load conditions(from 25% to 96% of the rated power). The pressure fluctuations of the reversible pump turbine at three different water heads(with non-dimensional values being 0.48, 0.71 and 0.90) are measured and compared based on the pressure data recorded in the whole flow passage of the turbine. Furthermore, effects of monitoring points and load variations on the impeller-induced unstable behavior(e.g. blade passing frequency and its harmonics) are quantitatively discussed. Our findings reveal that water head variations play a significant role on the pressure fluctuations and their propagation mechanisms inside the reversible pump turbine.
基金supported by the Special Funds for the Major State Basic Research Project (Grant No.2011CB301900)the National Natural Science Foundation of China (Grant Nos.60990311,60820106003,60906025,60936004 and 61177078)+1 种基金the Natural Science Foundation of Jiangsu Province (Grant Nos.BK2008019,BK2010385,BK2009255 and BK2010178)the Research Funds from NJU-Yangzhou Institute of Opto-electronics
文摘We develop a model for the effect of thermal annealing on forming In--N dusters in GalnNP according to thermodynamics. The average energy variation for forming an In--N bond in the model is estimated according to the theoretical calculation. Using the model, the added number of In--N bonds per mol of InGaNP, the added number of nearest-neighbor In atoms per N atom and the average number of nearest-neighbor In atoms per N atom after annealing are calculated. The different function of In--N clusters in InGaNP and InGaN is also discussed, which is due to the different environments around the In--N clusters.