压缩近邻法是一种简单的非参数原型选择算法,其原型选取易受样本读取序列、异常样本等干扰.为克服上述问题,提出了一个基于局部均值与类全局信息的近邻原型选择方法.该方法既在原型选取过程中,充分利用了待学习样本在原型集中k个同异类...压缩近邻法是一种简单的非参数原型选择算法,其原型选取易受样本读取序列、异常样本等干扰.为克服上述问题,提出了一个基于局部均值与类全局信息的近邻原型选择方法.该方法既在原型选取过程中,充分利用了待学习样本在原型集中k个同异类近邻局部均值和类全局信息的知识,又设定原型集更新策略实现对原型集的动态更新.该方法不仅能较好克服读取序列、异常样本对原型选取的影响,降低了原型集规模,而且在保持高分类精度的同时,实现了对数据集的高压缩效应.图像识别及UCI(University of California Irvine)基准数据集实验结果表明,所提出算法集具有较比较算法更有效的分类性能.展开更多
针对传统K近邻分类器在大规模数据集中存在时间和空间复杂度过高的问题,可采取原型选择的方法进行处理,即从原始数据集中挑选出代表原型(样例)进行K近邻分类而不降低其分类准确率.本文在CURE聚类算法的基础上,针对CURE的噪声点不易确定...针对传统K近邻分类器在大规模数据集中存在时间和空间复杂度过高的问题,可采取原型选择的方法进行处理,即从原始数据集中挑选出代表原型(样例)进行K近邻分类而不降低其分类准确率.本文在CURE聚类算法的基础上,针对CURE的噪声点不易确定及代表点分散性差的特点,利用共享邻居密度度量给出了一种去噪方法和使用最大最小距离选取代表点进行改进,从而提出了一种新的原型选择算法PSCURE (improved prototype selection algorithm based on CURE algorithm).基于UCI数据集进行实验,结果表明:提出的PSCURE原型选择算法与相关原型算法相比,不仅能筛选出较少的原型,而且可获得较高的分类准确率.展开更多
The advent of rapid prototyping & manufacturing techniques represents a major breakthrough in production engineering. This paper is concerned with the software system aspects of the selective laser sintering (SL...The advent of rapid prototyping & manufacturing techniques represents a major breakthrough in production engineering. This paper is concerned with the software system aspects of the selective laser sintering (SLS),i.e.the issues that deal with an external geometric CAD model to automatically control the physical layering fabrication process as directly as possible ,regardless of the source of the model. The general issues are described and some key methods are given in this paper.展开更多
Discovering highly selective catalysts is key to achieve effective CO_(2) photoreduction to hydrocarbon fuels.In this work,we construct an ultrathin dimension-matched S-scheme Bi_(3)NbO_(7)/g-C_(3)N_(4) heterostructur...Discovering highly selective catalysts is key to achieve effective CO_(2) photoreduction to hydrocarbon fuels.In this work,we construct an ultrathin dimension-matched S-scheme Bi_(3)NbO_(7)/g-C_(3)N_(4) heterostructure,which permits the highly selective photocatalytic reduction of CO_(2) to CH_(4),as shown by 13C isotopic measurements.Density functional theory calculations combined with solid-state characterization confirm the electron transfer from g-C_(3)N_(4) nanosheets to Bi_(3)NbO_(7),establishing an internal electric field.The internal electric field drives photogenerated electrons from Bi_(3)NbO_(7) to g-C_(3)N_(4),as revealed by in-situ X-ray photoelectron spectroscopy,demonstrating the presence of an S-scheme charge transfer path in Bi_(3)NbO_(7)/g-C_(3)N_(4) heterostructures allowing efficient and selective CO2 photoreduction.As a result,the optimized sample achieved a CH_(4) evolution rate of 37.59μmol·g^(-1)·h^(-1),a ca.15-fold enhancement compared to ultrathin g-C_(3)N_(4) nanosheets,and also retained stability after 10 reaction cycles and 40 h of simulated solar irradiation with no sacrificial reagents.The optimized Bi3 Nb O7/g-C_(3)N_(4) composites achieve almost 90%selectivity for CH_(4) production over CO.展开更多
Squeezing properties in the nondegenerate two-photon Jaynes-Cummings model are investigated. The effects of direct selective atomic measurement and the application of the classical field followed by atomic measurement...Squeezing properties in the nondegenerate two-photon Jaynes-Cummings model are investigated. The effects of direct selective atomic measurement and the application of the classical field followed by atomic measurement are analyzed. Different values of the parameters of the classical field are taken into account. It is found that the field squeezing can be enhanced by measurement.展开更多
We propose a simple scheme to not only generate GHZ states and W states of the multiparticle but also form a new category of multiparticle entangled states by letting the A-type three-level atoms simultaneously intera...We propose a simple scheme to not only generate GHZ states and W states of the multiparticle but also form a new category of multiparticle entangled states by letting the A-type three-level atoms simultaneously interacting with a coherent cavity field followed by the selective measurements on the cavity mode. We investigate the influence of the cavity dissipation on the generated entangled state and discuss the experimental feasibility of our scheme. It is shown that the intensity of the coherent cavity field plays an instructive role in contribution to state preparation process while the cavity decay and the detuning between the atoms and cavity mode result in the deterioration of the generated entangled state.展开更多
Short chain chlorinated paraffins （SCCPs） are not only research focus of environmental issues but also interesting model mol- ecules for organic chemistry which exhibit diverse conformation preference and intramolec...Short chain chlorinated paraffins （SCCPs） are not only research focus of environmental issues but also interesting model mol- ecules for organic chemistry which exhibit diverse conformation preference and intramolecular noncovalent interactions （NCIs）. A systematic study was conducted to reveal the conlk）rmation preference and the related intramolecular NCIs in two C^-isomers of SCCPs, 5,5,6,6-tetrachlorodecane and 4,4,6,6-1etrachlorodecane. The overall conformation profile was deter- mined on the basis of relative energies calculated at the MP2/6-311＋＋G（d,p） level with the geometries optimized by B3LYP/6-31 l＋＋G（d,p） method. Then, quantum theory of atoms in molecules （QTAIM） has been adopted to identify the NCls in the selected conformers of the model molecules at both B31~YP/6-31 l＋＋G（d,p） and M06-2X/aug-cc-pvdz level. Different chlorine substitution modes result in varied conformation preference. No obvious gauche effect can be observed tk）r the SCCPs with chlorination on adjacent carbon atoms. The most stable conformer of 5,5,6,6-tetrachlorodecane （tTt） has its three dihedral angles in the T configuration, and there is no intramolecular N（3s found in this molecule. On the contrary, the chlorination on interval carbon atoms favors the adoption of gauche configmation for the H C C CI axis. Not only inlramolecular H-..CI contacts but also H---H interactions have been identified as driving forces to compensate the instability from steric crowding ot the gauche configuration. The gggg and g＇g＇g＇g＇ conformers are the most popular ones, while the populations of tggg and tg＇g＇g＇ conformer are second to those of the gggg and g＇g＇g＇g＇ conformers. Meanwhile, the M06-2X method with large basis sets is preferred for identification of subtle intramolecular NCIs in large molecules like SCCPs.展开更多
The objective of this paper is to quantify the complexity of rank and nuclear norm constrained methods for low rank matrix estimation problems. Specifically, we derive analytic forms of the degrees of freedom for thes...The objective of this paper is to quantify the complexity of rank and nuclear norm constrained methods for low rank matrix estimation problems. Specifically, we derive analytic forms of the degrees of freedom for these types of estimators in several common settings. These results provide efficient ways of comparing different estimators and eliciting tuning parameters. Moreover, our analyses reveal new insights on the behavior of these low rank matrix estimators. These observations are of great theoretical and practical importance. In particular, they suggest that, contrary to conventional wisdom, for rank constrained estimators the total number of free parameters underestimates the degrees of freedom, whereas for nuclear norm penalization, it overestimates the degrees of freedom. In addition, when using most model selection criteria to choose the tuning parameter for nuclear norm penalization, it oftentimes suffices to entertain a finite number of candidates as opposed to a continuum of choices. Numerical examples are also presented to illustrate the practical implications of our results.展开更多
文摘压缩近邻法是一种简单的非参数原型选择算法,其原型选取易受样本读取序列、异常样本等干扰.为克服上述问题,提出了一个基于局部均值与类全局信息的近邻原型选择方法.该方法既在原型选取过程中,充分利用了待学习样本在原型集中k个同异类近邻局部均值和类全局信息的知识,又设定原型集更新策略实现对原型集的动态更新.该方法不仅能较好克服读取序列、异常样本对原型选取的影响,降低了原型集规模,而且在保持高分类精度的同时,实现了对数据集的高压缩效应.图像识别及UCI(University of California Irvine)基准数据集实验结果表明,所提出算法集具有较比较算法更有效的分类性能.
文摘针对传统K近邻分类器在大规模数据集中存在时间和空间复杂度过高的问题,可采取原型选择的方法进行处理,即从原始数据集中挑选出代表原型(样例)进行K近邻分类而不降低其分类准确率.本文在CURE聚类算法的基础上,针对CURE的噪声点不易确定及代表点分散性差的特点,利用共享邻居密度度量给出了一种去噪方法和使用最大最小距离选取代表点进行改进,从而提出了一种新的原型选择算法PSCURE (improved prototype selection algorithm based on CURE algorithm).基于UCI数据集进行实验,结果表明:提出的PSCURE原型选择算法与相关原型算法相比,不仅能筛选出较少的原型,而且可获得较高的分类准确率.
文摘The advent of rapid prototyping & manufacturing techniques represents a major breakthrough in production engineering. This paper is concerned with the software system aspects of the selective laser sintering (SLS),i.e.the issues that deal with an external geometric CAD model to automatically control the physical layering fabrication process as directly as possible ,regardless of the source of the model. The general issues are described and some key methods are given in this paper.
文摘Discovering highly selective catalysts is key to achieve effective CO_(2) photoreduction to hydrocarbon fuels.In this work,we construct an ultrathin dimension-matched S-scheme Bi_(3)NbO_(7)/g-C_(3)N_(4) heterostructure,which permits the highly selective photocatalytic reduction of CO_(2) to CH_(4),as shown by 13C isotopic measurements.Density functional theory calculations combined with solid-state characterization confirm the electron transfer from g-C_(3)N_(4) nanosheets to Bi_(3)NbO_(7),establishing an internal electric field.The internal electric field drives photogenerated electrons from Bi_(3)NbO_(7) to g-C_(3)N_(4),as revealed by in-situ X-ray photoelectron spectroscopy,demonstrating the presence of an S-scheme charge transfer path in Bi_(3)NbO_(7)/g-C_(3)N_(4) heterostructures allowing efficient and selective CO2 photoreduction.As a result,the optimized sample achieved a CH_(4) evolution rate of 37.59μmol·g^(-1)·h^(-1),a ca.15-fold enhancement compared to ultrathin g-C_(3)N_(4) nanosheets,and also retained stability after 10 reaction cycles and 40 h of simulated solar irradiation with no sacrificial reagents.The optimized Bi3 Nb O7/g-C_(3)N_(4) composites achieve almost 90%selectivity for CH_(4) production over CO.
文摘Squeezing properties in the nondegenerate two-photon Jaynes-Cummings model are investigated. The effects of direct selective atomic measurement and the application of the classical field followed by atomic measurement are analyzed. Different values of the parameters of the classical field are taken into account. It is found that the field squeezing can be enhanced by measurement.
基金Supported by the Natural Science Foundation of Hunan Province under Grant No.06jj50014Key Project Foundation of the Education Commission of Hunan Province under Grant No.06A055the Young Core Teachers Foundation of Hunan Provincial Education Department
文摘We propose a simple scheme to not only generate GHZ states and W states of the multiparticle but also form a new category of multiparticle entangled states by letting the A-type three-level atoms simultaneously interacting with a coherent cavity field followed by the selective measurements on the cavity mode. We investigate the influence of the cavity dissipation on the generated entangled state and discuss the experimental feasibility of our scheme. It is shown that the intensity of the coherent cavity field plays an instructive role in contribution to state preparation process while the cavity decay and the detuning between the atoms and cavity mode result in the deterioration of the generated entangled state.
基金the Chinese Academy of Sciences (KZCX2-YW-BR-25, XDB14030500, YSW2013B01)the National High Technology Research and Development Program of China (2013AA065201)
文摘Short chain chlorinated paraffins （SCCPs） are not only research focus of environmental issues but also interesting model mol- ecules for organic chemistry which exhibit diverse conformation preference and intramolecular noncovalent interactions （NCIs）. A systematic study was conducted to reveal the conlk）rmation preference and the related intramolecular NCIs in two C^-isomers of SCCPs, 5,5,6,6-tetrachlorodecane and 4,4,6,6-1etrachlorodecane. The overall conformation profile was deter- mined on the basis of relative energies calculated at the MP2/6-311＋＋G（d,p） level with the geometries optimized by B3LYP/6-31 l＋＋G（d,p） method. Then, quantum theory of atoms in molecules （QTAIM） has been adopted to identify the NCls in the selected conformers of the model molecules at both B31~YP/6-31 l＋＋G（d,p） and M06-2X/aug-cc-pvdz level. Different chlorine substitution modes result in varied conformation preference. No obvious gauche effect can be observed tk）r the SCCPs with chlorination on adjacent carbon atoms. The most stable conformer of 5,5,6,6-tetrachlorodecane （tTt） has its three dihedral angles in the T configuration, and there is no intramolecular N（3s found in this molecule. On the contrary, the chlorination on interval carbon atoms favors the adoption of gauche configmation for the H C C CI axis. Not only inlramolecular H-..CI contacts but also H---H interactions have been identified as driving forces to compensate the instability from steric crowding ot the gauche configuration. The gggg and g＇g＇g＇g＇ conformers are the most popular ones, while the populations of tggg and tg＇g＇g＇ conformer are second to those of the gggg and g＇g＇g＇g＇ conformers. Meanwhile, the M06-2X method with large basis sets is preferred for identification of subtle intramolecular NCIs in large molecules like SCCPs.
基金supported by National Science Foundation of USA (Grant No. DMS1265202)National Institutes of Health of USA (Grant No. 1-U54AI117924-01)
文摘The objective of this paper is to quantify the complexity of rank and nuclear norm constrained methods for low rank matrix estimation problems. Specifically, we derive analytic forms of the degrees of freedom for these types of estimators in several common settings. These results provide efficient ways of comparing different estimators and eliciting tuning parameters. Moreover, our analyses reveal new insights on the behavior of these low rank matrix estimators. These observations are of great theoretical and practical importance. In particular, they suggest that, contrary to conventional wisdom, for rank constrained estimators the total number of free parameters underestimates the degrees of freedom, whereas for nuclear norm penalization, it overestimates the degrees of freedom. In addition, when using most model selection criteria to choose the tuning parameter for nuclear norm penalization, it oftentimes suffices to entertain a finite number of candidates as opposed to a continuum of choices. Numerical examples are also presented to illustrate the practical implications of our results.
