Effects of citrate concentration and pH on the electrochemical reduction process of Co（Ⅱ） were investigated by cyclic voltammetry（CV） and electrochemical impedance spectroscopy（EIS）. The results show that Co（...Effects of citrate concentration and pH on the electrochemical reduction process of Co（Ⅱ） were investigated by cyclic voltammetry（CV） and electrochemical impedance spectroscopy（EIS）. The results show that Co（Ⅱ） is reduced into two species which are free Co2＋ and [Co（C6H607）] in the solution composed of 0.05 mol/L CoS04·5H2O, 0.20 mol/L Na2SO4 and 0-0.40 mol/L C6H5O7Na3·2H2O in the pH range of 3-9. The reduction behavior depends on the pH of the solution. Co（H） is mainly reduced into the form of free Co^2＋ at pH 3 and into the form of [Co（C6H6O7）] at the pH range of 4-6 in citrate solution. The [Co（C6H6O7）] is first reduced to an intermediate state and then to Co°. Adsorption of the intermediate state exists on the surface of the electrode. Co（Ⅱ） is difficult to be reduced in the solution with the pH above 7, because the existing Co（Ⅱ）-citrate complex species [Co（C6H5O7）]- and [Co（C6H4O7）]2- are more difficult to be reduced than the hydrogen ion.展开更多
The microscopic recollision dynamics in strong-field nonsequential double ionization of Ar atoms is in- vestigated using three-dimensional classical ensembles. By adjusting the nuclear Coulomb potential, we can excell...The microscopic recollision dynamics in strong-field nonsequential double ionization of Ar atoms is in- vestigated using three-dimensional classical ensembles. By adjusting the nuclear Coulomb potential, we can excellently reproduce the experimental results both within the laser intensity regimes well above the reeollision threshold and well below the recollision threshold quantitatively. More importantly, our trajectory analysis clearly reveals the particular electronic dynamics in recollision process： the momentum of the recolliding electron encounters a sudden change both in magnitude and in direction when it approaches the nucleus closely, which show that the nuclear Coulomb attraction plays a key role in the recollision process of nonsequential double ionization of Ar atoms.展开更多
基金Project(200800560002)supported by the Ph.D.Programs Foundation of Ministry of Education of China
文摘Effects of citrate concentration and pH on the electrochemical reduction process of Co（Ⅱ） were investigated by cyclic voltammetry（CV） and electrochemical impedance spectroscopy（EIS）. The results show that Co（Ⅱ） is reduced into two species which are free Co2＋ and [Co（C6H607）] in the solution composed of 0.05 mol/L CoS04·5H2O, 0.20 mol/L Na2SO4 and 0-0.40 mol/L C6H5O7Na3·2H2O in the pH range of 3-9. The reduction behavior depends on the pH of the solution. Co（H） is mainly reduced into the form of free Co^2＋ at pH 3 and into the form of [Co（C6H6O7）] at the pH range of 4-6 in citrate solution. The [Co（C6H6O7）] is first reduced to an intermediate state and then to Co°. Adsorption of the intermediate state exists on the surface of the electrode. Co（Ⅱ） is difficult to be reduced in the solution with the pH above 7, because the existing Co（Ⅱ）-citrate complex species [Co（C6H5O7）]- and [Co（C6H4O7）]2- are more difficult to be reduced than the hydrogen ion.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 11005088 and 11047145the Science & Technology Project of Henan Province in China under Grant Nos. 102300410241 and 112300410021the Scientific Research Foundation of Education Department of Henan Province in China under Grant Nos. 2009A140006 and 2011B140018
文摘The microscopic recollision dynamics in strong-field nonsequential double ionization of Ar atoms is in- vestigated using three-dimensional classical ensembles. By adjusting the nuclear Coulomb potential, we can excellently reproduce the experimental results both within the laser intensity regimes well above the reeollision threshold and well below the recollision threshold quantitatively. More importantly, our trajectory analysis clearly reveals the particular electronic dynamics in recollision process： the momentum of the recolliding electron encounters a sudden change both in magnitude and in direction when it approaches the nucleus closely, which show that the nuclear Coulomb attraction plays a key role in the recollision process of nonsequential double ionization of Ar atoms.
