In this article, we mainly analysis the soil carbon storage of the alpine grassland under different land uses in Qinghai-Tibet Plateau. The samples of this investigation include six experimental fields which are fence...In this article, we mainly analysis the soil carbon storage of the alpine grassland under different land uses in Qinghai-Tibet Plateau. The samples of this investigation include six experimental fields which are fenced mowing grassland, artificial grassland, winter and spring grazing meadowland, summer and autumn mild grazing land, summer and autumn moderate grazing pasture and summer and autumn severe grazing land and seven soil layers included 0 cm-5 cm, 5 cm-10 cm, 10 cm-20 cm, 20 cm-30 cm, 30 cm-50 cm, 50 cm-70 cm and 70 cm-100 cm. The results show that the soil carbon storage in different soil layers will gradually reduce and the difference was remarkable (P 〈 0.05). What is more, the soil carbon storage of alpine grassland under different land uses has following sequence: winter and spring grazing grassland 〉 summer and autumn mild grazing land 〉 artificial grassland 〉 summer and autumn moderate grazing meadowland 〉 summer and autumn severe grazing pasture 〉 fenced mowing meadow, and the significant difference between them is remarkable (P 〈 0.05).展开更多
Soil organic carbon (SOC) and its relationship with landscape attributes are important for evaluating current regional, continental, and global carbon stores. Data of SOC in surface soils (0–20 cm) of four main soils...Soil organic carbon (SOC) and its relationship with landscape attributes are important for evaluating current regional, continental, and global carbon stores. Data of SOC in surface soils (0–20 cm) of four main soils, Cambisol, Arenosol, Phaeozem, and Chernozem, were collected at 451 locations in Nongan County under maize monoculture in the Song-Nen Plain, Northeast China. The spatial characteristics of soil organic carbon were studied, using geographic information systems (GIS) and geostatistics. Effects of other soil physical and chemical properties, elevation, slope, and soil type on SOC were explored. SOC concentrations followed a normal distribution, with an arithmetic mean of 14.91 g kg-1 . The experimental variogram of SOC was fitted with a spherical model. There were significant correlations between soil organic carbon and bulk density (r =-0.374**), pH (r = 0.549**), total nitrogen (r = 0.781**), extractable phosphorus (r =-0.109*), exchangeable potassium (r = 0.565**), and cation exchange capacity (r = 0.313**). Generally, lower SOC concentrations were significantly associated with high elevation (r =-0.429**). Soil organic carbon was significantly negatively correlated with slope gradient (r =-0.195**). Samples of the Cambisol statistically had the highest SOC concentrations, and samples of the Arenosol had the lowest SOC value.展开更多
Although both the aerobic photocatalytic oxidation of organic pollutants into CO2 and the anaerobic photocatalytic reduction of CO2 into solar fuels have been intensively studied,few efforts have been devoted to combi...Although both the aerobic photocatalytic oxidation of organic pollutants into CO2 and the anaerobic photocatalytic reduction of CO2 into solar fuels have been intensively studied,few efforts have been devoted to combining these carbon-involved photocatalytic oxidation-reduction processes together,by which an artificial photocatalytic carbon cycling process can be established.The key challenge lies in the exploitation of efficient bifunctional photocatalysts,capable of triggering both aerobic oxidation and anaerobic reduction reactions.In this work,a bifunctional ternary g-C3N4/Bi/BiVO4 hybrid photocatalyst is successfully constructed,which not only demonstrates superior aerobic photocatalytic oxidation performance in degrading an organic pollutant(using the dye,Rhodamine B as a model),but also exhibits impressive photocatalytic CO2 reduction performance under anaerobic conditions.Moreover,a direct conversion of Rhodamine B to solar fuels in a one-pot anaerobic reactor can be achieved with the as-prepared ternary g-C3N4/Bi/BiVO4 hybrid photocatalyst.The excellent bifunctional photocatalytic performance of the g-C3N4/Bi/BiVO4 photocatalyst is associated with the formation of efficient S-scheme hybrid junctions,which contribute to promoting the appropriate charge dynamics,and sustaining favorable charge potentials.The formation of the S-scheme heterojunction is supported by scavenger studies and density functional theory calculations.Moreover,the in-situ formed plasmonic metallic Bi nanoparticles in the S-scheme hybrid g-C3N4/Bi/BiVO4 photocatalyst enhances vectorial interfacial electron transfer.This novel bifunctional S-scheme g-C3N4/Bi/BiVO4 hybrid photocatalyst system provides new insights for the further development of an integrated aerobic-anaerobic reaction system for photocatalytic carbon cycling.展开更多
The purpose of this study was to assess the effect of long-term cultivation and water erosion on the soil organic carbon (OC) in particle-size fractions. The study site is located at Nihegou Watershed in the Souther...The purpose of this study was to assess the effect of long-term cultivation and water erosion on the soil organic carbon (OC) in particle-size fractions. The study site is located at Nihegou Watershed in the Southern Loess Plateau, China. The soil at this site is loess with loose and silty structure, and contains macropores. The results showed that the OC concentrations in sediments and in the particle-size fractions of sediments were higher than those in soils and in the particle-size fractions of soils. The OC concentration was highest in the clay particles and was lowest in the sand particles. Clay particles possessed higher OC enrichment ability than silt and sand particles. The proportions of OC in the silt fractions of soil and sediment were the highest (mean value of 53.87% and 58.48%, respectively), and the total proportion of OC in the clay and silt fractions accounted for 96% and 98% of the total OC in the soil and sediment, respectively. The loss of OC was highest in silt particles, with an average value of 0.16 Mg ha^-1 y^-1, and was lowest in the sand (0.003 Mg ha^-1 y^-l). This result suggests that the fine particle-size fraction in the removed sediment may be an important indicator to assess soil OC losses.展开更多
Grassland is a major carbon sink in the terrestrial ecosystem. The dynamics of grassland carbon stock profoundly influence the global carbon cycle. In the published literatures so far, however, there are limited studi...Grassland is a major carbon sink in the terrestrial ecosystem. The dynamics of grassland carbon stock profoundly influence the global carbon cycle. In the published literatures so far, however, there are limited studies on the long-term dynamics and influential factors of grassland carbon stock, including soil organic carbon. In this study, spatial-temporal substitution method was applied to explore the characteristics of Medicago sativa L. (alfalfa) grassland biomass carbon and soil organic carbon density (SOCD) in a loess hilly region with different growing years and management patterns. The results demonstrated that alfalfa was the mono-dominant community during the cutting period (viz. 0-10 year). Community succession began after the abandonment of alfalfa grassland and then the important value of alfalfa in the community declined. The artificial alfalfa community abandoned for 30 years was replaced by the S. bungeana community. Accordingly, the biomass carbon density of the clipped alfalfa showed a significant increase over the time during 0-10 year. During 0-30 year, the SOCD from 0-100 cm of the soil layer of all 5 management patterns increased over time with a range between 5.300 ± 0.981 kg/m2 and 12.578 ± 0.863 kg/m2. The sloping croplands had the lowest SOCD at 5.300 ± 0.981 kg/m2 which was quite different from the abandoned grasslands growing for 30 years which exhibited the highest SOCD with 12.578 ± 0.863 kg/m2. The ecosystem carbon density of the grassland clipped for 2 years increased 0.1 kg/m2 compared with the sloping cropland, while that of the grassland clipped for 10 years substantially increased to 10.30 ± 1.26 kg/m2. Moreover, the ecosystem carbon density for abandoned grassland became 12.62± 0.50 kg/m2 at 30 years. The carbon density of the grassland undisturbed for l0 years was similar to that of the sloping cropland and the grassland clipped for 2 years. Different management patterns imposed great different effects on the accumulation of biomass carbon on artificial grasslands, whereas the ecosystem carbon density of the grassland showed a slight increase from the clipping to abandonment of grassland in general.展开更多
Cropland (CP),native grassland (NG) and two shrub land treatments which were converted from cropland in 1985:seabuckthorn (Hippophae rhamnoides L.) (ST),and branchytamarisk (Tamarix ramosissima) (BT) were investigated...Cropland (CP),native grassland (NG) and two shrub land treatments which were converted from cropland in 1985:seabuckthorn (Hippophae rhamnoides L.) (ST),and branchytamarisk (Tamarix ramosissima) (BT) were investigated to evaluate effects of land use conversion on soil organic carbon (SOC) and soil nutrients in the semi-arid region of the Loess Plateau of China.Total organic carbon (TOC),light fraction organic carbon (LFOC),heavy fraction organic carbon (HFOC),total N (TN),nitrate nitrogen (NO 3-N) and nitrite nitrogen (NO 2-N),ammonium nitrogen (NH + 4-N),total P,and available P (AP) were measured.The results showed that SOC in NG,ST and BT were 12.7%,27.7% and 34.8% higher than that of the cropland,respectively.LFOC,light fraction (LF) dry matter,ratio of TOC to TN (C/N) and the ratio of TOC to AP (C/P) were higher in the shrub land or native grassland than in the cropland.Cropland had the highest TN,the sum of NO 3-N and NO 2-N,TP and AP due to the use of chemical fertilizers.TOC significantly correlated with LFOC,HFOC and C/N.LFOC significantly correlated with dry matter of the LF and C/N.TN,the sum of NO 3-N and NO 2-N and AP were significantly negatively correlated with TOC and LFOC.Therefore,land use conversion from cropland to shrub land,or maybe grassland,contributed to SOC sequestration and improved soil nutrients stabilization.展开更多
The aim of the study was to characterize humus system of natural and artificial products. Humus systems from leonardite, lignite biotransformed with Trichoderma sp. (Plantagra), plant materials after pyrolisis (cha...The aim of the study was to characterize humus system of natural and artificial products. Humus systems from leonardite, lignite biotransformed with Trichoderma sp. (Plantagra), plant materials after pyrolisis (charcoal) and composts are compared. Humus systems are characterized by Kononova-Belchikova's method, and heavy metals content was measured by atomic absorption spectroscopy (AAS). Humic acids from the International Humic Substances Society (IHSS) collection are the standards for humus substances quality of compared products. Data obtained for leonardite indicate that the studied substances from factory, Izmir, Turkey contain humic acids over 94%. Compared to the standard, heavy metals content in these materials demonstrate high amounts. Organic carbon content in the composts is very low compared to the leonardite materials and IHSS collection, where the heavy metals content is lower. Biotransformed lignite is characterized with lower content of organic carbon, but humic acids are with high degree of humification. Results obtained show that the fourth studied humus systems may be used in agriculture on base of the high humic acids content. It is recommended to measure heavy metals content before applying the materials in agriculture.展开更多
The full-potential linearized augmented plane wave (FPLAPW) method with the generalized gradient approximations (GGA) is applied to study the compound [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<...The full-potential linearized augmented plane wave (FPLAPW) method with the generalized gradient approximations (GGA) is applied to study the compound [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> (NITmPy = 2 - (3' - Pyridy1) -4, 4, 5, 5 - tetramethylimidazolin - 1 - oxy1 - 3 - oxide). The total density of states (DOS) and the partial density of states (pDOS) are calculated to explain the electronic and the magnetic properties of [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB>. It is found that [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> is stable in the ferromagnetic state and the magnetic moment of the molecule mainly comes from the Cu atoms (0.518 μ<SUB>B</SUB>) with partial contribution from N, O atoms of nitronyl nitroxide radicals. There exist orbital hybridization between 3d orbital of Cu and p orbitals of N(1) (from pyridyl rings of the NITmPy ligands) and N(4) (from azido group) and the weak direct exchange interactions between Cu and O atoms of nitronyl nitroxides. In addition, the bridging carbon atom (C(6)) carries a significant negative spin density (-0.019 μ<SUB>B</SUB>). The sign alternation of the magnetic moment along zthe pyridyl ring is obtained, which agrees with experiments.展开更多
The authors discovered a new magnetic properties of the phosphorous and carbon with a four and five bond, and stibine, bismuthine in organometallic chemistry. This allows to modify many of classical reactions by repla...The authors discovered a new magnetic properties of the phosphorous and carbon with a four and five bond, and stibine, bismuthine in organometallic chemistry. This allows to modify many of classical reactions by replacing with the nitrogen atoms to atoms of phosphorus, arsenic, antimony and bismuth. The authors have proposed a new mechanism for the possible reactions.展开更多
This study is aimed at characterizing the organic matter preserved in the Triassic Lockatong formation deposited in the Newark Basin. On the basis of the TOC (Total Organic Carbon), the Lockatong formation was depos...This study is aimed at characterizing the organic matter preserved in the Triassic Lockatong formation deposited in the Newark Basin. On the basis of the TOC (Total Organic Carbon), the Lockatong formation was deposited in a reducing environment in the deep NW part of the basin, which is favorable to the accumulation of organic matter. However, the Lockatong formation of the SE border of the basin was deposited in oxic conditions that prevented the preservation of organic matter if there is any. The structuration of the basin into deep subsiding NW section due to the reactivation of the NE-SW striking faults and the development of anoxic conditions were favorable for the accumulation and preservation of the organic matter in the deep part of the basin.展开更多
Labile organic carbon(LOC) is one of the most important indicators of soil organic matter quality and dynamics elevation and plays important function in the Tibetan Plateau climate. However, it is unknown what the s...Labile organic carbon(LOC) is one of the most important indicators of soil organic matter quality and dynamics elevation and plays important function in the Tibetan Plateau climate. However, it is unknown what the sources and causes of LOC contamination are. In this study, soil organic carbon(SOC), total nitrogen(TN), microbial biomass carbon(MBC), microbial biomass nitrogen(MBN) and LOC were analyzed based on different soil horizons and elevations using turnover time in an experimental site(3700 m to 4300 m area) in Sygera. SOC and LOC in higher-elevation vegetation types were higher than that of in lower-elevation vegetation types. Our results presented that the soil microbial biomass carbon(SMBC) and soil microbial biomass nitrogen(SMBN)were positively correlated with SOC. The content of easily oxidized carbon(EOC), particulate organic carbon(POC) and light fraction organic carbon(LFOC) decreased with depth increasing and the content were the lowest in the 60 cm to 100 cm depth.The total SOC, ROC and POC contents decreased with increasing soil horizons. The SOC, TN, MBC and MBN contents increased with increasing altitude in the Sygera Mountains. The MBC and MBN contents weredifferent with the changes of SOC(p&lt;0.05),meanwhile, both LFOC and POC were related to total SOC(p&lt;0.05). The physical and chemical properties of soil, including temperature, humidity, and altitude,were involved in the regulation of SOC, TN, MBC,MBN and LFOC contents in the Sygera Mountains,Tibetan Plateau.展开更多
Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for t...Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for the synthesis of nitrogen and oxygen dual-doped meso-porous layer-structured carbon electrocatalyst embedded with graphitic carbon coated cobalt nanoparticles by direct pyrolysis of a layer-structured metal-organic framework. The elec- trocatalyst prepared at 800℃ exhibits comparable ORR performance to Pt/C catalysts but possesses superior stability to Pt/C catalysts. This synthetic approach provides new prospects in developing sustainable carbon-based electrocatalysts for electrochemical energy conversion devices.展开更多
The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within t...The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within the modern global carbon cycle.The chemical analysis of some dissolved species transported by rivers,such as elevated Sr/Ca and Mg/Ca ratios but also heavy stable Ca isotopic compositions,witness the formation of secondary calcite in rivers draining arid regions.However,in areas affected by active tectonics and rapid physical erosion,co-variations in the fluvial Sr/Ca and Mg/Ca ratios could also be related to incongruent carbonate weathering processes.Here,we present a model to assess the roles played by incongruent carbonate dissolution and secondary calcite precipitation in modern weathering processes.We tested and applied the model to rivers draining the Himalayan–Tibetan region.The results suggest that regional aridity in the drainage basin promotes carbon sequestration as secondary carbonate but that for a given runoff,incongruent dissolution of carbonate possibly related to rapid physical erosion amplifies such sequestration.The isotopic compositions(^(13)C/^(12)C and^(18)O/^(16)O)of detrital carbonate transported by the main rivers in South and South-East Tibet imply that around 1%of the suspended material transported by those rivers corresponds to secondary carbonate and can represent between 5%and 15%of the alkalinity flux.Most of these alkalinity transported as particulate material is,nevertheless related to the weathering of carbonate lithologies and is also subjected to dissolution prior its final storage in sedimentary basins.However,on glacial-interglacial timescale this will amplify the significant role of mountain weathering on climatic variations.展开更多
This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine gr...This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine grassland stations and North China flux stations, with a total of 34 stations and 77 soil profiles. Measured data indicate that the topsoils of alpine grasslands contain high SOC contents than underlying soil layers, which leads to higher soil porosity values and lower thermal conductivity and bulk density values in the topsoils. However, this stratification is not evident at the lowland stations due to low SOC contents. Evaluations against measured data show that three thermal conductivity schemes used in land surface models severely overestimate the values for soils with high SOC content (i.e. topsoils of alpine grassland), but they are better for soils with low SOC content. A new parameterization is then developed to take the impacts of SOC into account. The new one can well estimate the soil thermal conductivity values in both low and high SOC content cases, and therefore, it is a potential candidate of thermal conductivity scheme to be used in land surface models.展开更多
There is a limited knowledge of spatial heterogeneity in soil nutrients and soil respiration in the semi-arid and arid grasslands of China. This study investigated the spatial differences in soil nutrients and soil re...There is a limited knowledge of spatial heterogeneity in soil nutrients and soil respiration in the semi-arid and arid grasslands of China. This study investigated the spatial differences in soil nutrients and soil respiration among three desertified grasslands and within two shrub-dominated communities on the Ordos Plateau of Inner Mongolia, China in 2006. Both soil organic carbon (SOC) and total nitrogen (TN) were significantly different (P 〈 0.01) among the three desertified grasslands along a degradation gradient. Within the two shrub-dominated communities, the SOC and TN contents decreased with increasing distance from the main stems of the shrub, and this "fertile island" effect was most pronounced in the surface soil. The total soil respirations during the growing season were 131.26, 95.95, and 118.66 g C m^-2, respectively, for the steppe, shrub, and shrub-perennial grass communities. The coefficient of variability of soil respiration was the highest in the shrub community and lowest in the steppe community. CO2 effiuxes from the soil under the canopy of shrub were significantly higher than those from the soil covered with biological crusts and the bare soil in the interplant spaces in the shrub community. However, soil respiration beneath the shrubs was not different from that of the soil in the inter-shrub of the shrub-perennial grass community. This is probably due to the smaller shrub size. In the two shrub-dominated communities, spatial variability in soil respiration was found to depend on soil water content and C:N ratio.展开更多
Understanding the spatial variability of soil carbon (C) storage and its relationship with climate and soil texture is critical for developing regional C models and for predicting the potential impact of climate cha...Understanding the spatial variability of soil carbon (C) storage and its relationship with climate and soil texture is critical for developing regional C models and for predicting the potential impact of climate change on soil C storage. On the basis of soil data from a transect across the Inner Mongolian grasslands, we determined the quantitative relationships of C and nitrogen (N) in bulk soil and particle-size fractions (sand, silt, and clay) with climate and soil texture to evaluate the major factors controlling soil C and N storage and to predict the effect of climate changes on soil C and N storage. The contents of C and N in the bulk soil and the different fractions in the 0 20 and 20 40 cm soil layers were positively correlated with the mean annum precipitation (MAP) and negatively correlated with the mean annual temperature (MAT). The responses of C storage in the soil and particle-size fractions to MAP and MAT were more sensitive in the 0-20 cm than in the 2(~40 cm soil layer. Although MAP and MAT were both important factors influencing soil C storage, the models that include only MAP could well explain the variation in soil C storage in the Inner Mongolian grasslands. Because of the high correlation between MAP and MAT in the region, the models including MAT did not significantly enhance the model precision. Moreover, the contribution of the fine fraction (silt and clay) to the variation in soil C storage was rather small because of the very low fine fraction content in the Inner Mongolian grasslands.展开更多
文摘In this article, we mainly analysis the soil carbon storage of the alpine grassland under different land uses in Qinghai-Tibet Plateau. The samples of this investigation include six experimental fields which are fenced mowing grassland, artificial grassland, winter and spring grazing meadowland, summer and autumn mild grazing land, summer and autumn moderate grazing pasture and summer and autumn severe grazing land and seven soil layers included 0 cm-5 cm, 5 cm-10 cm, 10 cm-20 cm, 20 cm-30 cm, 30 cm-50 cm, 50 cm-70 cm and 70 cm-100 cm. The results show that the soil carbon storage in different soil layers will gradually reduce and the difference was remarkable (P 〈 0.05). What is more, the soil carbon storage of alpine grassland under different land uses has following sequence: winter and spring grazing grassland 〉 summer and autumn mild grazing land 〉 artificial grassland 〉 summer and autumn moderate grazing meadowland 〉 summer and autumn severe grazing pasture 〉 fenced mowing meadow, and the significant difference between them is remarkable (P 〈 0.05).
基金Projcet supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX2-YW-341)the National Basic Research Program of China (No. 2009CB421103)the National Natural Science Foundation ofChina (Nos. 40871187 and 40930527)
文摘Soil organic carbon (SOC) and its relationship with landscape attributes are important for evaluating current regional, continental, and global carbon stores. Data of SOC in surface soils (0–20 cm) of four main soils, Cambisol, Arenosol, Phaeozem, and Chernozem, were collected at 451 locations in Nongan County under maize monoculture in the Song-Nen Plain, Northeast China. The spatial characteristics of soil organic carbon were studied, using geographic information systems (GIS) and geostatistics. Effects of other soil physical and chemical properties, elevation, slope, and soil type on SOC were explored. SOC concentrations followed a normal distribution, with an arithmetic mean of 14.91 g kg-1 . The experimental variogram of SOC was fitted with a spherical model. There were significant correlations between soil organic carbon and bulk density (r =-0.374**), pH (r = 0.549**), total nitrogen (r = 0.781**), extractable phosphorus (r =-0.109*), exchangeable potassium (r = 0.565**), and cation exchange capacity (r = 0.313**). Generally, lower SOC concentrations were significantly associated with high elevation (r =-0.429**). Soil organic carbon was significantly negatively correlated with slope gradient (r =-0.195**). Samples of the Cambisol statistically had the highest SOC concentrations, and samples of the Arenosol had the lowest SOC value.
基金financially supported by the National Natural Science Foundation of China(51872341,51572209)the Start-up Funds for High-Level Talents of Sun Yat-sen University(38000-31131105)+1 种基金the Fundamental Research Funds for the Central Universities(19lgzd29)the Science and Technology Program of Guangzhou(201707010095)~~
文摘Although both the aerobic photocatalytic oxidation of organic pollutants into CO2 and the anaerobic photocatalytic reduction of CO2 into solar fuels have been intensively studied,few efforts have been devoted to combining these carbon-involved photocatalytic oxidation-reduction processes together,by which an artificial photocatalytic carbon cycling process can be established.The key challenge lies in the exploitation of efficient bifunctional photocatalysts,capable of triggering both aerobic oxidation and anaerobic reduction reactions.In this work,a bifunctional ternary g-C3N4/Bi/BiVO4 hybrid photocatalyst is successfully constructed,which not only demonstrates superior aerobic photocatalytic oxidation performance in degrading an organic pollutant(using the dye,Rhodamine B as a model),but also exhibits impressive photocatalytic CO2 reduction performance under anaerobic conditions.Moreover,a direct conversion of Rhodamine B to solar fuels in a one-pot anaerobic reactor can be achieved with the as-prepared ternary g-C3N4/Bi/BiVO4 hybrid photocatalyst.The excellent bifunctional photocatalytic performance of the g-C3N4/Bi/BiVO4 photocatalyst is associated with the formation of efficient S-scheme hybrid junctions,which contribute to promoting the appropriate charge dynamics,and sustaining favorable charge potentials.The formation of the S-scheme heterojunction is supported by scavenger studies and density functional theory calculations.Moreover,the in-situ formed plasmonic metallic Bi nanoparticles in the S-scheme hybrid g-C3N4/Bi/BiVO4 photocatalyst enhances vectorial interfacial electron transfer.This novel bifunctional S-scheme g-C3N4/Bi/BiVO4 hybrid photocatalyst system provides new insights for the further development of an integrated aerobic-anaerobic reaction system for photocatalytic carbon cycling.
基金supported by the grants from President Foundation of Northwest A & F University, China
文摘The purpose of this study was to assess the effect of long-term cultivation and water erosion on the soil organic carbon (OC) in particle-size fractions. The study site is located at Nihegou Watershed in the Southern Loess Plateau, China. The soil at this site is loess with loose and silty structure, and contains macropores. The results showed that the OC concentrations in sediments and in the particle-size fractions of sediments were higher than those in soils and in the particle-size fractions of soils. The OC concentration was highest in the clay particles and was lowest in the sand particles. Clay particles possessed higher OC enrichment ability than silt and sand particles. The proportions of OC in the silt fractions of soil and sediment were the highest (mean value of 53.87% and 58.48%, respectively), and the total proportion of OC in the clay and silt fractions accounted for 96% and 98% of the total OC in the soil and sediment, respectively. The loss of OC was highest in silt particles, with an average value of 0.16 Mg ha^-1 y^-1, and was lowest in the sand (0.003 Mg ha^-1 y^-l). This result suggests that the fine particle-size fraction in the removed sediment may be an important indicator to assess soil OC losses.
基金Under the auspices of Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA05000000)National Natural Science Foundation of China(No.41271518)Sci-technology Project of Shaanxi Province(No.2013kw19-01)
文摘Grassland is a major carbon sink in the terrestrial ecosystem. The dynamics of grassland carbon stock profoundly influence the global carbon cycle. In the published literatures so far, however, there are limited studies on the long-term dynamics and influential factors of grassland carbon stock, including soil organic carbon. In this study, spatial-temporal substitution method was applied to explore the characteristics of Medicago sativa L. (alfalfa) grassland biomass carbon and soil organic carbon density (SOCD) in a loess hilly region with different growing years and management patterns. The results demonstrated that alfalfa was the mono-dominant community during the cutting period (viz. 0-10 year). Community succession began after the abandonment of alfalfa grassland and then the important value of alfalfa in the community declined. The artificial alfalfa community abandoned for 30 years was replaced by the S. bungeana community. Accordingly, the biomass carbon density of the clipped alfalfa showed a significant increase over the time during 0-10 year. During 0-30 year, the SOCD from 0-100 cm of the soil layer of all 5 management patterns increased over time with a range between 5.300 ± 0.981 kg/m2 and 12.578 ± 0.863 kg/m2. The sloping croplands had the lowest SOCD at 5.300 ± 0.981 kg/m2 which was quite different from the abandoned grasslands growing for 30 years which exhibited the highest SOCD with 12.578 ± 0.863 kg/m2. The ecosystem carbon density of the grassland clipped for 2 years increased 0.1 kg/m2 compared with the sloping cropland, while that of the grassland clipped for 10 years substantially increased to 10.30 ± 1.26 kg/m2. Moreover, the ecosystem carbon density for abandoned grassland became 12.62± 0.50 kg/m2 at 30 years. The carbon density of the grassland undisturbed for l0 years was similar to that of the sloping cropland and the grassland clipped for 2 years. Different management patterns imposed great different effects on the accumulation of biomass carbon on artificial grasslands, whereas the ecosystem carbon density of the grassland showed a slight increase from the clipping to abandonment of grassland in general.
基金Project supported by the National Basic Research Program (973 Program) of China (No. 2007CB106804)the International S&T Cooperation Program (ISTCP) of China (No. 2006DFA31070)the International Foundation for Sciences(No. C/3313-2)
文摘Cropland (CP),native grassland (NG) and two shrub land treatments which were converted from cropland in 1985:seabuckthorn (Hippophae rhamnoides L.) (ST),and branchytamarisk (Tamarix ramosissima) (BT) were investigated to evaluate effects of land use conversion on soil organic carbon (SOC) and soil nutrients in the semi-arid region of the Loess Plateau of China.Total organic carbon (TOC),light fraction organic carbon (LFOC),heavy fraction organic carbon (HFOC),total N (TN),nitrate nitrogen (NO 3-N) and nitrite nitrogen (NO 2-N),ammonium nitrogen (NH + 4-N),total P,and available P (AP) were measured.The results showed that SOC in NG,ST and BT were 12.7%,27.7% and 34.8% higher than that of the cropland,respectively.LFOC,light fraction (LF) dry matter,ratio of TOC to TN (C/N) and the ratio of TOC to AP (C/P) were higher in the shrub land or native grassland than in the cropland.Cropland had the highest TN,the sum of NO 3-N and NO 2-N,TP and AP due to the use of chemical fertilizers.TOC significantly correlated with LFOC,HFOC and C/N.LFOC significantly correlated with dry matter of the LF and C/N.TN,the sum of NO 3-N and NO 2-N and AP were significantly negatively correlated with TOC and LFOC.Therefore,land use conversion from cropland to shrub land,or maybe grassland,contributed to SOC sequestration and improved soil nutrients stabilization.
文摘The aim of the study was to characterize humus system of natural and artificial products. Humus systems from leonardite, lignite biotransformed with Trichoderma sp. (Plantagra), plant materials after pyrolisis (charcoal) and composts are compared. Humus systems are characterized by Kononova-Belchikova's method, and heavy metals content was measured by atomic absorption spectroscopy (AAS). Humic acids from the International Humic Substances Society (IHSS) collection are the standards for humus substances quality of compared products. Data obtained for leonardite indicate that the studied substances from factory, Izmir, Turkey contain humic acids over 94%. Compared to the standard, heavy metals content in these materials demonstrate high amounts. Organic carbon content in the composts is very low compared to the leonardite materials and IHSS collection, where the heavy metals content is lower. Biotransformed lignite is characterized with lower content of organic carbon, but humic acids are with high degree of humification. Results obtained show that the fourth studied humus systems may be used in agriculture on base of the high humic acids content. It is recommended to measure heavy metals content before applying the materials in agriculture.
文摘The full-potential linearized augmented plane wave (FPLAPW) method with the generalized gradient approximations (GGA) is applied to study the compound [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> (NITmPy = 2 - (3' - Pyridy1) -4, 4, 5, 5 - tetramethylimidazolin - 1 - oxy1 - 3 - oxide). The total density of states (DOS) and the partial density of states (pDOS) are calculated to explain the electronic and the magnetic properties of [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB>. It is found that [Cu(NTTmPy)<SUB>2</SUB>(N<SUB>3</SUB>)<SUB>2</SUB>]<SUB>n</SUB> is stable in the ferromagnetic state and the magnetic moment of the molecule mainly comes from the Cu atoms (0.518 μ<SUB>B</SUB>) with partial contribution from N, O atoms of nitronyl nitroxide radicals. There exist orbital hybridization between 3d orbital of Cu and p orbitals of N(1) (from pyridyl rings of the NITmPy ligands) and N(4) (from azido group) and the weak direct exchange interactions between Cu and O atoms of nitronyl nitroxides. In addition, the bridging carbon atom (C(6)) carries a significant negative spin density (-0.019 μ<SUB>B</SUB>). The sign alternation of the magnetic moment along zthe pyridyl ring is obtained, which agrees with experiments.
文摘The authors discovered a new magnetic properties of the phosphorous and carbon with a four and five bond, and stibine, bismuthine in organometallic chemistry. This allows to modify many of classical reactions by replacing with the nitrogen atoms to atoms of phosphorus, arsenic, antimony and bismuth. The authors have proposed a new mechanism for the possible reactions.
文摘This study is aimed at characterizing the organic matter preserved in the Triassic Lockatong formation deposited in the Newark Basin. On the basis of the TOC (Total Organic Carbon), the Lockatong formation was deposited in a reducing environment in the deep NW part of the basin, which is favorable to the accumulation of organic matter. However, the Lockatong formation of the SE border of the basin was deposited in oxic conditions that prevented the preservation of organic matter if there is any. The structuration of the basin into deep subsiding NW section due to the reactivation of the NE-SW striking faults and the development of anoxic conditions were favorable for the accumulation and preservation of the organic matter in the deep part of the basin.
基金supported by CFERN & GENE Award Funds on Ecological Paper
文摘Labile organic carbon(LOC) is one of the most important indicators of soil organic matter quality and dynamics elevation and plays important function in the Tibetan Plateau climate. However, it is unknown what the sources and causes of LOC contamination are. In this study, soil organic carbon(SOC), total nitrogen(TN), microbial biomass carbon(MBC), microbial biomass nitrogen(MBN) and LOC were analyzed based on different soil horizons and elevations using turnover time in an experimental site(3700 m to 4300 m area) in Sygera. SOC and LOC in higher-elevation vegetation types were higher than that of in lower-elevation vegetation types. Our results presented that the soil microbial biomass carbon(SMBC) and soil microbial biomass nitrogen(SMBN)were positively correlated with SOC. The content of easily oxidized carbon(EOC), particulate organic carbon(POC) and light fraction organic carbon(LFOC) decreased with depth increasing and the content were the lowest in the 60 cm to 100 cm depth.The total SOC, ROC and POC contents decreased with increasing soil horizons. The SOC, TN, MBC and MBN contents increased with increasing altitude in the Sygera Mountains. The MBC and MBN contents weredifferent with the changes of SOC(p&lt;0.05),meanwhile, both LFOC and POC were related to total SOC(p&lt;0.05). The physical and chemical properties of soil, including temperature, humidity, and altitude,were involved in the regulation of SOC, TN, MBC,MBN and LFOC contents in the Sygera Mountains,Tibetan Plateau.
文摘Developing highly active and durable electrocatalysts for the oxygen reduction reaction (ORR) is crucial to large-scale commercialization of fuel cells and metal-air batteries. Here we report a facile approach for the synthesis of nitrogen and oxygen dual-doped meso-porous layer-structured carbon electrocatalyst embedded with graphitic carbon coated cobalt nanoparticles by direct pyrolysis of a layer-structured metal-organic framework. The elec- trocatalyst prepared at 800℃ exhibits comparable ORR performance to Pt/C catalysts but possesses superior stability to Pt/C catalysts. This synthetic approach provides new prospects in developing sustainable carbon-based electrocatalysts for electrochemical energy conversion devices.
文摘The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within the modern global carbon cycle.The chemical analysis of some dissolved species transported by rivers,such as elevated Sr/Ca and Mg/Ca ratios but also heavy stable Ca isotopic compositions,witness the formation of secondary calcite in rivers draining arid regions.However,in areas affected by active tectonics and rapid physical erosion,co-variations in the fluvial Sr/Ca and Mg/Ca ratios could also be related to incongruent carbonate weathering processes.Here,we present a model to assess the roles played by incongruent carbonate dissolution and secondary calcite precipitation in modern weathering processes.We tested and applied the model to rivers draining the Himalayan–Tibetan region.The results suggest that regional aridity in the drainage basin promotes carbon sequestration as secondary carbonate but that for a given runoff,incongruent dissolution of carbonate possibly related to rapid physical erosion amplifies such sequestration.The isotopic compositions(^(13)C/^(12)C and^(18)O/^(16)O)of detrital carbonate transported by the main rivers in South and South-East Tibet imply that around 1%of the suspended material transported by those rivers corresponds to secondary carbonate and can represent between 5%and 15%of the alkalinity flux.Most of these alkalinity transported as particulate material is,nevertheless related to the weathering of carbonate lithologies and is also subjected to dissolution prior its final storage in sedimentary basins.However,on glacial-interglacial timescale this will amplify the significant role of mountain weathering on climatic variations.
基金supported by National Natural Science Foundation of China (Grant No. 41105003)Key Project of Chinese Academy of Sciences (Grant No.KZCX2-YW-Q10-2)+1 种基金National Natural Science Foundation of China (Grant No. 91025004)Open Fund from the State Key Laboratory of Remote Sensing Science (Grant No. OFSLRSS201108) that is cosponsored by the Institute of Remote Sensing Applications of Chinese Academy of Sciences and Beijing Normal University
文摘This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine grassland stations and North China flux stations, with a total of 34 stations and 77 soil profiles. Measured data indicate that the topsoils of alpine grasslands contain high SOC contents than underlying soil layers, which leads to higher soil porosity values and lower thermal conductivity and bulk density values in the topsoils. However, this stratification is not evident at the lowland stations due to low SOC contents. Evaluations against measured data show that three thermal conductivity schemes used in land surface models severely overestimate the values for soils with high SOC content (i.e. topsoils of alpine grassland), but they are better for soils with low SOC content. A new parameterization is then developed to take the impacts of SOC into account. The new one can well estimate the soil thermal conductivity values in both low and high SOC content cases, and therefore, it is a potential candidate of thermal conductivity scheme to be used in land surface models.
基金Supported by the National Natural Science Foundation of China(Nos.40730105,40501072 and 40973057)the National"Eleventh Five Years Plan"Key Project on Science and Technology of China(No.2007BAC03A11)
文摘There is a limited knowledge of spatial heterogeneity in soil nutrients and soil respiration in the semi-arid and arid grasslands of China. This study investigated the spatial differences in soil nutrients and soil respiration among three desertified grasslands and within two shrub-dominated communities on the Ordos Plateau of Inner Mongolia, China in 2006. Both soil organic carbon (SOC) and total nitrogen (TN) were significantly different (P 〈 0.01) among the three desertified grasslands along a degradation gradient. Within the two shrub-dominated communities, the SOC and TN contents decreased with increasing distance from the main stems of the shrub, and this "fertile island" effect was most pronounced in the surface soil. The total soil respirations during the growing season were 131.26, 95.95, and 118.66 g C m^-2, respectively, for the steppe, shrub, and shrub-perennial grass communities. The coefficient of variability of soil respiration was the highest in the shrub community and lowest in the steppe community. CO2 effiuxes from the soil under the canopy of shrub were significantly higher than those from the soil covered with biological crusts and the bare soil in the interplant spaces in the shrub community. However, soil respiration beneath the shrubs was not different from that of the soil in the inter-shrub of the shrub-perennial grass community. This is probably due to the smaller shrub size. In the two shrub-dominated communities, spatial variability in soil respiration was found to depend on soil water content and C:N ratio.
基金Supported by the National Natural Science Foundation of China(Nos.31270519,31070431 and 41373080)the State Key Laboratory of Forest and Soil Ecology,China(No.LFSE2013-03)
文摘Understanding the spatial variability of soil carbon (C) storage and its relationship with climate and soil texture is critical for developing regional C models and for predicting the potential impact of climate change on soil C storage. On the basis of soil data from a transect across the Inner Mongolian grasslands, we determined the quantitative relationships of C and nitrogen (N) in bulk soil and particle-size fractions (sand, silt, and clay) with climate and soil texture to evaluate the major factors controlling soil C and N storage and to predict the effect of climate changes on soil C and N storage. The contents of C and N in the bulk soil and the different fractions in the 0 20 and 20 40 cm soil layers were positively correlated with the mean annum precipitation (MAP) and negatively correlated with the mean annual temperature (MAT). The responses of C storage in the soil and particle-size fractions to MAP and MAT were more sensitive in the 0-20 cm than in the 2(~40 cm soil layer. Although MAP and MAT were both important factors influencing soil C storage, the models that include only MAP could well explain the variation in soil C storage in the Inner Mongolian grasslands. Because of the high correlation between MAP and MAT in the region, the models including MAT did not significantly enhance the model precision. Moreover, the contribution of the fine fraction (silt and clay) to the variation in soil C storage was rather small because of the very low fine fraction content in the Inner Mongolian grasslands.