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原位制备磁性壳聚糖纳米粒子及其对Ag(I)的吸附性能 被引量:2
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作者 周利民 尚超 《东华理工大学学报(自然科学版)》 CAS 2012年第3期285-290,共6页
以壳聚糖、Fe2+/Fe3+盐为水相,环已烷/正已醇为油相,TritonX-100为乳化剂,通过在W/O微乳体系中加NaOH溶液沉淀剂,原位制备磁性壳聚糖纳米粒子(MCN),用于吸附Ag(I)。考察了pH值、Ag(I)浓度和温度对MCN吸附Ag(I)的影响。结果表明,MCN分散... 以壳聚糖、Fe2+/Fe3+盐为水相,环已烷/正已醇为油相,TritonX-100为乳化剂,通过在W/O微乳体系中加NaOH溶液沉淀剂,原位制备磁性壳聚糖纳米粒子(MCN),用于吸附Ag(I)。考察了pH值、Ag(I)浓度和温度对MCN吸附Ag(I)的影响。结果表明,MCN分散良好,粒径15~40nm,饱和磁化强度25.6emu·g-1,pH6.0时吸附最佳,Ag(I)吸附容量随温度升高而降低。吸附动力学符合拟二级方程,且为自发放热过程。吸附等温线分别用Langmuir,Freundich和D-R模型拟合,表明Langmuir模型拟合最好,为单分子层吸附,最大吸附容量2.06mmol/g。吸附活化能E为8.94~9.10kJ/mol,表明以化学吸附为主。 展开更多
关键词 原粒制备 磁性壳聚糖 吸附 AG(I)
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Aluminum matrix composites reinforced by in situ Al_2O_3 and Al_3Zr particles fabricated via magnetochemistry reaction 被引量:3
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作者 赵玉涛 张松利 陈刚 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第11期2129-2133,共5页
Aluminum matrix composites reinforced by in situ Al2O3 and Al3Zr particles are fabricated from A356-Zr(CO3)2 system via magnetochemistry reaction,and the morphologies,sizes and distributions of the in situ particles a... Aluminum matrix composites reinforced by in situ Al2O3 and Al3Zr particles are fabricated from A356-Zr(CO3)2 system via magnetochemistry reaction,and the morphologies,sizes and distributions of the in situ particles as well as the microstructures,mechanical mechanisms of the composites are investigated by XRD,SEM,TEM and in situ tensile tests.The results indicate that with the pulsed magnetic field assistance,the morphologies of the in situ particles are mainly with ball-shape,the sizes are in nanometer scale and the distributions in the matrix are uniform.The interfaces between the in situ particles and the aluminum matrix are net and no interfacial outgrowth is observed.These are due to the strong vibration induced by the applied magnetic field in the aluminum melt,which in turn,accelerates the melt reactions.The effects of the magnetic field on the above contributions are discussed in detail. 展开更多
关键词 aluminum matrix composites magnetochemistry reaction Al2O3 AL3ZR in situ tensile
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Rapid Preparation Process of Silver Nanoparticles by Bioreduction and Their Characterizations 被引量:13
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作者 傅谋兴 李清彪 +5 位作者 孙道华 卢英华 何宁 邓旭 王惠璇 黄加乐 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第1期114-117,共4页
Bioreduction as a novel nanoparticle synthesizing technology attracts increasing attention. Dried cells of the bacterium Aeromonas sp. SH10 rapidly reduced [Ag(NH3)2]^+ to Ago in the solution into which some amount... Bioreduction as a novel nanoparticle synthesizing technology attracts increasing attention. Dried cells of the bacterium Aeromonas sp. SH10 rapidly reduced [Ag(NH3)2]^+ to Ago in the solution into which some amount of OH^- was introduced. The surface plasmon resonance centered at 425 nm on the UV-vis spectra and five broad Bragg reflections on the XRD pattern showed that stable silver nanoparticles were formed during the bioreduction process. TEM and SEM observations suggested that the silver nanoparticles were uniform in size and well dispersed on the cells and in the solution. Therefore, silver nanoparticles could be prepared rapidly by this bioreduction technology. 展开更多
关键词 BIOREDUCTION silver NANOPARTICLE BACTERIUM HYDROXIDE
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