Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3...Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3 systems,as revealed by ultraviolet-visible diffuse-reflectance spectrometry,photocurrent response and electrochemical impedance spectroscopy. The Ag/AgC l/BiO IO3 composites are applied to the visible-light photocatalytic oxidization of NO in air and exhibit an enhanced activity for NO removal in comparison with Ag/AgC l and pure BiO IO3. A possible photocatalytic mechanism for Ag/AgC l/BiO IO3 is proposed,which is related to the surface plasmon resonance effects of Ag metal and the effective carrier separation ability of BiO IO3. This work provides insight into the design and preparation of BiO IO3-based materials with enhanced visible-light photocatalysis ability.展开更多
To explore the influence of compound bioelectret material′s dielectric property on the cell growth,several kinds of compound bioelectret materials of collagen/chitosan were developed Their TSDC(thermally stimulated ...To explore the influence of compound bioelectret material′s dielectric property on the cell growth,several kinds of compound bioelectret materials of collagen/chitosan were developed Their TSDC(thermally stimulated depolarization current)spectra were analyzed,and the compound bioelectret collagen/chitosan whose t α and I α were 37℃ and 2×10 -9 A respectively at polarized state was selected The cell culture study showed that the compound bioelectret material could promote normal cell growth when singly negatively polarized,and could inhibit cancer cell growth when singly positively polarized It proves that the rational designation of compound bioelectret has a broad application for clinical medicine展开更多
To improve the photocatalytic oxidation reaction activity for NO removal, photocatalysts with excellent activity are required to activate molecular oxygen. Solid solution and heterojunction were suggested as effective...To improve the photocatalytic oxidation reaction activity for NO removal, photocatalysts with excellent activity are required to activate molecular oxygen. Solid solution and heterojunction were suggested as effective strategies to enhance the molecular oxygen activation viaexciton and carrier photocatalysis. In this study, a solid solution and heterojunction containing BiOBr0.5I0.5/BiOI catalyst was synthesized, and it showed improved photocatalytic activity for removing NO. The photocatalytic NO removal mechanism indicated that synergistic effects between the solid solution and heterojunction induced the enhanced activity for molecular oxygen activation. The photogenerated holes, superoxide, and singlet oxygen generated by the carrier and exciton photocatalysis supported the high photocatalytic NO removal efficiency. This study provides new ideas for designing efficient Bi-O-X(X = Cl, Br, I) photocatalysts for oxidation reactions.展开更多
Nitrobenzene-containing industrial wastewater was degraded in the presence of ozone coupled with H2O2 by high gravity technology. The effect of high gravity factor, H2O2 concentration, pH value, liquid flow-rate, and ...Nitrobenzene-containing industrial wastewater was degraded in the presence of ozone coupled with H2O2 by high gravity technology. The effect of high gravity factor, H2O2 concentration, pH value, liquid flow-rate, and reaction time on the efficiency for removal of nitrobenzene was investigated. The experimental results show that the high gravity technology enhances the ozone utilization efficiency with O3/H202 showing synergistic effect. The degradation efficiency in terms of the COD removal rate and nitrobenzene removal rate reached 45.8% and 50.4%, respectively, under the following reaction conditions, viz.： a high gravity factor of 66.54, a pH value of 9, a H2O2/O3 molar ratio of 1：1, a liquid flow rate of 140 L/h, an ozone concentration of 40 rag/L, a H2O2 multiple dosing mode of 6 mL/h, and a reaction time of 4 h. Compared with the performance of conventional stirred aeration mixers, the high gravity technology could increase the COD and nitrobenzene removal rate related with the nitrobenzene-containing wastewater by 22.9% and 23.3%, respectively.展开更多
In order to reasonably utilize the iron resources of copper slags, the smelting chlorination process was used to remove copper from copper slags. Higher holding temperature and O2 flow rate are beneficial to increasin...In order to reasonably utilize the iron resources of copper slags, the smelting chlorination process was used to remove copper from copper slags. Higher holding temperature and O2 flow rate are beneficial to increasing copper removal rate. However,the Cu2O mode is formed by the reaction of surplus O2 and CuCl with O2 flow rate increasing over 0.4 L/min, causing CuCl volatilization rate and copper removal rate to decrease. The resulting copper removal rate of 84.34% is obtained under the optimum conditions of holding temperature of 1573 K, residence time of 10 min, Ca Cl2 addition amount of 0.1(mass ratio of CaCl2 and the copper slag) and oxygen flow rate of 0.4 L/min. The efficient removal of copper from copper slags through chlorination is feasible.展开更多
Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as pe...Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as per standard method of analysis and the treatment results were analyzed in terms of chemical oxygen demand （COD） removal efficiency o.f thespent.wash. The experiments were performed to s.tudy the effect of operating parameterssuch as current density, pH of the spent wash, agitation speed, electrolysis time and the distance between the elec- trodes on the COD removal efficiency of the spent wash. It was observed that aluminum electrodes were more suitable for treatment of distillery spent wash as compared to iron electrodes. The maximum COD removal effi- ciency of 81.3% was obtained with A1-A1 electrodes at the current density of 0.187 A.cm-2 and pH 3 for an elec-trolysis time of 2 h.展开更多
The growth of reeds was impeded remarkably under a salinity of 15.0±3.4 g CI·L-1 in the first year of this experiment, recovered in the second year and then increased year-by-year afterward. The growth of re...The growth of reeds was impeded remarkably under a salinity of 15.0±3.4 g CI·L-1 in the first year of this experiment, recovered in the second year and then increased year-by-year afterward. The growth of reeds under a salinity of 9.3±1.9 g CI·Ll was much better than those under 15.0 ± 3.4 g CI·L1. The stress effect was significant for shoot extension but not for the quantity of shoots increase. The dense vegetation bed during the vegetation period （June-October） provided a high rate of evapotranspiration and water loss from HFs （horizontal subsurface flow constructed wetlands）, which made large contributions to reducing pollutant load. The HFs with die-back reeds in the non-vegetation periods （November-March） provided slight evapotranspiration and water loss and made less of a contribution to reducing pollutants removal compared to HFs with the dense vegetation bed in the vegetation periods. However, the HFs with die-back reeds in the non-vegetation periods had higher removal performance than the HF without reeds. This indicated that the rhizosphere of HFs with reeds might play important roles, such as that the microbes around rhizomes might have a higher amount of pollutant-removing microbe activity than those in the HF without reeds during the non-vegetation period.展开更多
基金supported by the National Natural Science Foundation of China(5147807051108487)the Science and Technology Project from Chongqing Education Commission(KJ1400617)~~
文摘Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3 systems,as revealed by ultraviolet-visible diffuse-reflectance spectrometry,photocurrent response and electrochemical impedance spectroscopy. The Ag/AgC l/BiO IO3 composites are applied to the visible-light photocatalytic oxidization of NO in air and exhibit an enhanced activity for NO removal in comparison with Ag/AgC l and pure BiO IO3. A possible photocatalytic mechanism for Ag/AgC l/BiO IO3 is proposed,which is related to the surface plasmon resonance effects of Ag metal and the effective carrier separation ability of BiO IO3. This work provides insight into the design and preparation of BiO IO3-based materials with enhanced visible-light photocatalysis ability.
文摘To explore the influence of compound bioelectret material′s dielectric property on the cell growth,several kinds of compound bioelectret materials of collagen/chitosan were developed Their TSDC(thermally stimulated depolarization current)spectra were analyzed,and the compound bioelectret collagen/chitosan whose t α and I α were 37℃ and 2×10 -9 A respectively at polarized state was selected The cell culture study showed that the compound bioelectret material could promote normal cell growth when singly negatively polarized,and could inhibit cancer cell growth when singly positively polarized It proves that the rational designation of compound bioelectret has a broad application for clinical medicine
文摘To improve the photocatalytic oxidation reaction activity for NO removal, photocatalysts with excellent activity are required to activate molecular oxygen. Solid solution and heterojunction were suggested as effective strategies to enhance the molecular oxygen activation viaexciton and carrier photocatalysis. In this study, a solid solution and heterojunction containing BiOBr0.5I0.5/BiOI catalyst was synthesized, and it showed improved photocatalytic activity for removing NO. The photocatalytic NO removal mechanism indicated that synergistic effects between the solid solution and heterojunction induced the enhanced activity for molecular oxygen activation. The photogenerated holes, superoxide, and singlet oxygen generated by the carrier and exciton photocatalysis supported the high photocatalytic NO removal efficiency. This study provides new ideas for designing efficient Bi-O-X(X = Cl, Br, I) photocatalysts for oxidation reactions.
基金financially supported by the National Natural Science Foundation of China(21206153)Science and Technology Development Program Fund of Taiyuan City(120164053)
文摘Nitrobenzene-containing industrial wastewater was degraded in the presence of ozone coupled with H2O2 by high gravity technology. The effect of high gravity factor, H2O2 concentration, pH value, liquid flow-rate, and reaction time on the efficiency for removal of nitrobenzene was investigated. The experimental results show that the high gravity technology enhances the ozone utilization efficiency with O3/H202 showing synergistic effect. The degradation efficiency in terms of the COD removal rate and nitrobenzene removal rate reached 45.8% and 50.4%, respectively, under the following reaction conditions, viz.： a high gravity factor of 66.54, a pH value of 9, a H2O2/O3 molar ratio of 1：1, a liquid flow rate of 140 L/h, an ozone concentration of 40 rag/L, a H2O2 multiple dosing mode of 6 mL/h, and a reaction time of 4 h. Compared with the performance of conventional stirred aeration mixers, the high gravity technology could increase the COD and nitrobenzene removal rate related with the nitrobenzene-containing wastewater by 22.9% and 23.3%, respectively.
基金Project(51204082)supported by the National Natural Science Foundation of ChinaProject(KKZ3201252011)supported by Talent Cultivation Project of Kunming University of Science and Technology,China
文摘In order to reasonably utilize the iron resources of copper slags, the smelting chlorination process was used to remove copper from copper slags. Higher holding temperature and O2 flow rate are beneficial to increasing copper removal rate. However,the Cu2O mode is formed by the reaction of surplus O2 and CuCl with O2 flow rate increasing over 0.4 L/min, causing CuCl volatilization rate and copper removal rate to decrease. The resulting copper removal rate of 84.34% is obtained under the optimum conditions of holding temperature of 1573 K, residence time of 10 min, Ca Cl2 addition amount of 0.1(mass ratio of CaCl2 and the copper slag) and oxygen flow rate of 0.4 L/min. The efficient removal of copper from copper slags through chlorination is feasible.
文摘Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as per standard method of analysis and the treatment results were analyzed in terms of chemical oxygen demand （COD） removal efficiency o.f thespent.wash. The experiments were performed to s.tudy the effect of operating parameterssuch as current density, pH of the spent wash, agitation speed, electrolysis time and the distance between the elec- trodes on the COD removal efficiency of the spent wash. It was observed that aluminum electrodes were more suitable for treatment of distillery spent wash as compared to iron electrodes. The maximum COD removal effi- ciency of 81.3% was obtained with A1-A1 electrodes at the current density of 0.187 A.cm-2 and pH 3 for an elec-trolysis time of 2 h.
文摘The growth of reeds was impeded remarkably under a salinity of 15.0±3.4 g CI·L-1 in the first year of this experiment, recovered in the second year and then increased year-by-year afterward. The growth of reeds under a salinity of 9.3±1.9 g CI·Ll was much better than those under 15.0 ± 3.4 g CI·L1. The stress effect was significant for shoot extension but not for the quantity of shoots increase. The dense vegetation bed during the vegetation period （June-October） provided a high rate of evapotranspiration and water loss from HFs （horizontal subsurface flow constructed wetlands）, which made large contributions to reducing pollutant load. The HFs with die-back reeds in the non-vegetation periods （November-March） provided slight evapotranspiration and water loss and made less of a contribution to reducing pollutants removal compared to HFs with the dense vegetation bed in the vegetation periods. However, the HFs with die-back reeds in the non-vegetation periods had higher removal performance than the HF without reeds. This indicated that the rhizosphere of HFs with reeds might play important roles, such as that the microbes around rhizomes might have a higher amount of pollutant-removing microbe activity than those in the HF without reeds during the non-vegetation period.
