The composite oxides xAg/Co_(0.93)Ce_(0.07)(x=Ag/(Co+Ce) molar ratio),intended for use as high performance catalytic materials,were successfully prepared via citric acid complexation.The effects of silver on ...The composite oxides xAg/Co_(0.93)Ce_(0.07)(x=Ag/(Co+Ce) molar ratio),intended for use as high performance catalytic materials,were successfully prepared via citric acid complexation.The effects of silver on the performance of these substances during soot combustion were subsequently investigated.Under O_2,the 0.3Ag/Co_(0.93)Ce_(0.07) catalyst resulted in the lowest ignition temperature,T_(10),of197 ℃,while the minimum light-off temperature was obtained from both 0.2Ag/Co_(0.93)Ce_(0.07) and0.3Ag/Co_(0.93)Ce_(0.07) in the NO_x atmosphere.These materials were also characterized by various techniques,including H_2,soot and NO_x temperature programmed reduction,X-ray diffraction,and electron paramagnetic resonance,Raman,X-ray photoelectron,and Fourier transform infrared spectroscopic analyses.The results demonstrated that silver significantly alters the catalytic behavior under both O_2 and NO_x,even though the lattice structure of the mixed oxide is not affected.Surface silver oxides generated under the O_2 atmosphere favor soot combustion by participating in the redox cycles between soot and the silver oxide,whereas the AgNO_3 that forms in a NO_x-rich atmosphere facilitates soot abatement at a lower temperature.The inferior activity of AgNO_3 relative to that of Ag_2O results in the different catalytic performance in the presence of NO_x or O_2.展开更多
The multi-stages humidifier semi-dry flue gas cleaning technology, the CRS plasma flue gas cleaning technology and oxidative additive flue gas cleaning technology were investigated for multi-pollutants removal. The se...The multi-stages humidifier semi-dry flue gas cleaning technology, the CRS plasma flue gas cleaning technology and oxidative additive flue gas cleaning technology were investigated for multi-pollutants removal. The semi-dry flue gas cleaning technology using multi-stages humidifier and additive can improve oxidation and absorption, and it can achieve high multi-pollutants removal efficiency. The CRS discharge can produce many OH radicals that promote NO oxidation. Combining NaOH absorption can achieve high deSO2 and deNO, efficiencies. It is fit for the reconstruction of primary wet flue gas desulfurization (WFGD). In addition, using NaClO2 as additive in the absorbent of WFGD can obtain very high removal efficiency of SO2 and NOx.展开更多
[Objective] This study aimed to investigate the control effect of different concentrations of 80% nicosulfuron·atrazine water-dispersible granules on weeds in spring maize field. [Method] Maize field was sprayed ...[Objective] This study aimed to investigate the control effect of different concentrations of 80% nicosulfuron·atrazine water-dispersible granules on weeds in spring maize field. [Method] Maize field was sprayed with 300, 375, 450, 750 g/hm280% nicosulfuron·atrazine water-dispersible granules respectively, with 40 g/L nicosulfuron suspending concentrate and 38% atrazine suspending concentrate as control agents. Artificial weeding and control(CK) plots were set. [Result] Fresh weight control efficiency of 375-750 g/hm280% nicosulfuron·atrazine water-dispersible granules was significantly higher than that of 40 g/L nicosulfuron suspending concentrate and 38% atrazine suspending concentrate; no obvious phytotoxicity symptoms were observed after application of 300-450 g/hm280% nicosulfuron·atrazine waterdispersible granules; 750 g/hm280% nicosulfuron·atrazine water-dispersible granules posed certain impact on the growth of maize seedlings. Compared with control plots, various doses of 80% nicosulfuron·atrazine water-dispersible granules significantly improved the yield of maize. [Conclusion] In the present study, 375-450 g/hm280% nicosulfuron·atrazine water-dispersible granules exhibited high control effect on weeds in maize field and were safe for the growth of maize seedlings.展开更多
基金supported by the National Natural Science Foundation of China(21577088)~~
文摘The composite oxides xAg/Co_(0.93)Ce_(0.07)(x=Ag/(Co+Ce) molar ratio),intended for use as high performance catalytic materials,were successfully prepared via citric acid complexation.The effects of silver on the performance of these substances during soot combustion were subsequently investigated.Under O_2,the 0.3Ag/Co_(0.93)Ce_(0.07) catalyst resulted in the lowest ignition temperature,T_(10),of197 ℃,while the minimum light-off temperature was obtained from both 0.2Ag/Co_(0.93)Ce_(0.07) and0.3Ag/Co_(0.93)Ce_(0.07) in the NO_x atmosphere.These materials were also characterized by various techniques,including H_2,soot and NO_x temperature programmed reduction,X-ray diffraction,and electron paramagnetic resonance,Raman,X-ray photoelectron,and Fourier transform infrared spectroscopic analyses.The results demonstrated that silver significantly alters the catalytic behavior under both O_2 and NO_x,even though the lattice structure of the mixed oxide is not affected.Surface silver oxides generated under the O_2 atmosphere favor soot combustion by participating in the redox cycles between soot and the silver oxide,whereas the AgNO_3 that forms in a NO_x-rich atmosphere facilitates soot abatement at a lower temperature.The inferior activity of AgNO_3 relative to that of Ag_2O results in the different catalytic performance in the presence of NO_x or O_2.
基金supported by NSF of Zhejiang (Y507079)EOP of Zhejiang (Y200702725)PSF of China (20080431325)
文摘The multi-stages humidifier semi-dry flue gas cleaning technology, the CRS plasma flue gas cleaning technology and oxidative additive flue gas cleaning technology were investigated for multi-pollutants removal. The semi-dry flue gas cleaning technology using multi-stages humidifier and additive can improve oxidation and absorption, and it can achieve high multi-pollutants removal efficiency. The CRS discharge can produce many OH radicals that promote NO oxidation. Combining NaOH absorption can achieve high deSO2 and deNO, efficiencies. It is fit for the reconstruction of primary wet flue gas desulfurization (WFGD). In addition, using NaClO2 as additive in the absorbent of WFGD can obtain very high removal efficiency of SO2 and NOx.
文摘[Objective] This study aimed to investigate the control effect of different concentrations of 80% nicosulfuron·atrazine water-dispersible granules on weeds in spring maize field. [Method] Maize field was sprayed with 300, 375, 450, 750 g/hm280% nicosulfuron·atrazine water-dispersible granules respectively, with 40 g/L nicosulfuron suspending concentrate and 38% atrazine suspending concentrate as control agents. Artificial weeding and control(CK) plots were set. [Result] Fresh weight control efficiency of 375-750 g/hm280% nicosulfuron·atrazine water-dispersible granules was significantly higher than that of 40 g/L nicosulfuron suspending concentrate and 38% atrazine suspending concentrate; no obvious phytotoxicity symptoms were observed after application of 300-450 g/hm280% nicosulfuron·atrazine waterdispersible granules; 750 g/hm280% nicosulfuron·atrazine water-dispersible granules posed certain impact on the growth of maize seedlings. Compared with control plots, various doses of 80% nicosulfuron·atrazine water-dispersible granules significantly improved the yield of maize. [Conclusion] In the present study, 375-450 g/hm280% nicosulfuron·atrazine water-dispersible granules exhibited high control effect on weeds in maize field and were safe for the growth of maize seedlings.