An industrial scale propylene production via oxidative dehydrogenation of propane (ODHP) in multi-tubular re- actors was modeled. Multi-tubular fixed-bed reactor used for ODHP process, employing 10000 of small diame...An industrial scale propylene production via oxidative dehydrogenation of propane (ODHP) in multi-tubular re- actors was modeled. Multi-tubular fixed-bed reactor used for ODHP process, employing 10000 of small diameter tubes immersed in a shell through a proper coolant flows. Herein, a theory-based pseudo-homogeneous model to describe the operation of a fixed bed reactor for the ODHP to correspondence olefln over V2O5/γ-Al203 catalyst was presented. Steady state one dimensional model has been developed to identify the operation parameters and to describe the propane and oxygen conversions, gas process and coolant temperatures, as well as other pa- rameters affecting the reactor performance such as pressure. Furthermore, the applied model showed that a double-bed multitubular reactor with intermediate air injection scheme was superior to a single-bed design due to the increasing of propylene selectivity while operating under lower oxygen partial pressures resulting in propane conversion of about 37.3%. The optimized length of the reactor needed to reach 100% conversion of the oxygen was theoretically determined. For the single-bed reactor the optimized length of 11.96 m including 0.5 m of inert section at the entrance region and for the double-bed reactor design the optimized lengths of 5.72 m for the first and 7.32 m for the second reactor were calculated. Ultimately, the use of a distributed oxygen feed with limited number of injection points indicated a significant improvement on the reactor performance in terms of propane conversion and propylene selectivity. Besides, this concept could overcome the reactor run- away temperature problem and enabled operations at the wider range of conditions to obtain enhanced propyl- ene production in an industrial scale reactor.展开更多
Glycyrrhetic acid 3-O-mono-β-D-glucuronide (GAMG), the major functional ingredient in licorice, has widespread applications in food, pharmacy and cosmetics industry. The production of GAMG through Penicillium purpu...Glycyrrhetic acid 3-O-mono-β-D-glucuronide (GAMG), the major functional ingredient in licorice, has widespread applications in food, pharmacy and cosmetics industry. The production of GAMG through Penicillium purpurogenum Li-3 cultivation was for the first time performed through both batch and fed-batch processes in bioreactors. In batch process, under optimal conditions (pH 5.0, temperature 32℃, agitation speed 100 r. rain 1), 3.55 g. L^-1 GAMG was obtained in a 2.5 L fermentor. To further enhance GAMG production, a fine fed-batch process was developed by using pH and DO as feedback parameters. Starting from 48 h, 100 m190 g-L 1 substrate Glycyrrhizin (GL) was fed each time when pH increased to above 5.0 and DO was increased to above 80%. This strategy can significantly enhance GAMG production: the achieved GL conversion was 95.34% with GAMG yield of 95.15%, and GAMG concentration was 16.62 g. L^-1 which was 5 times higher than that of batch. Then, a two-step separation strat- egy was established to separate GAMG from fermentation broth by crude extraction of 15 ml column packed with D10I resin followed by fine purification with preparative C18 chromatography. The obtained GAMG purity was 95.79%. This study provides a new insight into the industrial bioprocess of high-level GAMG production.展开更多
The fish farming was introduced in Burundi in about 1950s. Actually, several fish ponds were abandoned and many others were still unproductive. This study aims to present current state and perspectives of the fish far...The fish farming was introduced in Burundi in about 1950s. Actually, several fish ponds were abandoned and many others were still unproductive. This study aims to present current state and perspectives of the fish farming for its real contribution to the socio-economic development. The results presented are compilation of physical and chemical parameters series measured in fish ponds and inquiries led in 2010-2014 to the fish farmers in seven provinces (40% of the total area of the country). Weak values of some physical and chemical parameters showed that the majority of ponds are badly maintained. Thus, the dissolved oxygen values varied between 0.2 mg/L and 3.5 mg/L. The high relinquishment rate of the fish fanning (between 40% and 67% according to the provinces) could be explained by many constraints: no centers of fish farming breeding for various fish species and no production center of complete foods with local sub-products. About 75% of fish famers confirmed that they have never benefited framing in fish fanning. In spite of the diverse constraints, Burundi has a dense rivers system with favorable physical and chemical parameters and many appropriate sites for the fish farming. Thus, the main suggestions concern the sector reorganization.展开更多
River estuarine environment plays a key role in the cycling of biological and chemical parameters and a significant region for the transaction of freshwater and seawater. In the present study, a first attempt has been...River estuarine environment plays a key role in the cycling of biological and chemical parameters and a significant region for the transaction of freshwater and seawater. In the present study, a first attempt has been made towards the development of a coupled three-dimensional hydrodynamic circulation model with four compartment (nitrate, phytoplankton, zooplankton and detritus) biogeochemical model in the Hooghly estuary (21 °36′-22° 16′1 and 87°42'-88°15′E) to simulate the varying effect of plankton biomass with the heavy input of anthropogenic litter from industrial effluents of Haldia port which is effecting the chemical and biological processes that control the plankton dynamics in the estuary. In-situ observational data for physico-chemical and biological parameters are collected from Calcutta University during 2010 are assimilated using multiscale OA (objective analysis) for different seasons and incorporated in ROMS (Regional Ocean Modeling System) to develop a high resolution (0.5 km x 0.5 kin) biogeochemical model. Recent analysis on physico-chemical parameters of the estuary is done as it is one of the largest estuaries in India and is the habitat for vast biodiversity. Influence of high nitrate (above 34 μg/L) and phosphate (5.22 μg/L) is predominant whereas DO (dissolved oxygen) is low (4.07 mg/L) in the Haldi River mouth which is sliding the productivity (less than 1 mg/L) and also affects water quality.展开更多
Commercially, many methods are adopted for the production of the Virgin Coconut Oil (VCO). Nowadays, natural fermentation is widely employed to produce VCO in wet processing. But the problem in natural fermentation ...Commercially, many methods are adopted for the production of the Virgin Coconut Oil (VCO). Nowadays, natural fermentation is widely employed to produce VCO in wet processing. But the problem in natural fermentation process has much contamination, due to surplus micro organisms present in natural environment, which leads to the poor quality of VCO. To overcome this, usage of probiotic organism like Lactobacillus fermentum is more beneficial for the fermentative production of VCO. Fermentation studies were conducted scientifically in computer controlled bioreactor to determine the effect of pH, temperature, inoculum concentration, oxygen requirement and incubation time on the yield of VCO. Yield efficiency of VCO in each parameter was determined. The pH of 5± 0.1, temperature at 45 ± 0.1 ~C, inoculum concentration of 2%, fermentation end time of 48 hrs and microaerophilic conditions are the most suitable parameters for the superior production of VCO.展开更多
文摘An industrial scale propylene production via oxidative dehydrogenation of propane (ODHP) in multi-tubular re- actors was modeled. Multi-tubular fixed-bed reactor used for ODHP process, employing 10000 of small diameter tubes immersed in a shell through a proper coolant flows. Herein, a theory-based pseudo-homogeneous model to describe the operation of a fixed bed reactor for the ODHP to correspondence olefln over V2O5/γ-Al203 catalyst was presented. Steady state one dimensional model has been developed to identify the operation parameters and to describe the propane and oxygen conversions, gas process and coolant temperatures, as well as other pa- rameters affecting the reactor performance such as pressure. Furthermore, the applied model showed that a double-bed multitubular reactor with intermediate air injection scheme was superior to a single-bed design due to the increasing of propylene selectivity while operating under lower oxygen partial pressures resulting in propane conversion of about 37.3%. The optimized length of the reactor needed to reach 100% conversion of the oxygen was theoretically determined. For the single-bed reactor the optimized length of 11.96 m including 0.5 m of inert section at the entrance region and for the double-bed reactor design the optimized lengths of 5.72 m for the first and 7.32 m for the second reactor were calculated. Ultimately, the use of a distributed oxygen feed with limited number of injection points indicated a significant improvement on the reactor performance in terms of propane conversion and propylene selectivity. Besides, this concept could overcome the reactor run- away temperature problem and enabled operations at the wider range of conditions to obtain enhanced propyl- ene production in an industrial scale reactor.
基金Supported by the National Natural Science Foundation of China(21176028 and21506011)the National Science Fund for Distinguished Young Scholars of China(21425624)Doctoral Fund of Ministry of Education of China(20121101110050)
文摘Glycyrrhetic acid 3-O-mono-β-D-glucuronide (GAMG), the major functional ingredient in licorice, has widespread applications in food, pharmacy and cosmetics industry. The production of GAMG through Penicillium purpurogenum Li-3 cultivation was for the first time performed through both batch and fed-batch processes in bioreactors. In batch process, under optimal conditions (pH 5.0, temperature 32℃, agitation speed 100 r. rain 1), 3.55 g. L^-1 GAMG was obtained in a 2.5 L fermentor. To further enhance GAMG production, a fine fed-batch process was developed by using pH and DO as feedback parameters. Starting from 48 h, 100 m190 g-L 1 substrate Glycyrrhizin (GL) was fed each time when pH increased to above 5.0 and DO was increased to above 80%. This strategy can significantly enhance GAMG production: the achieved GL conversion was 95.34% with GAMG yield of 95.15%, and GAMG concentration was 16.62 g. L^-1 which was 5 times higher than that of batch. Then, a two-step separation strat- egy was established to separate GAMG from fermentation broth by crude extraction of 15 ml column packed with D10I resin followed by fine purification with preparative C18 chromatography. The obtained GAMG purity was 95.79%. This study provides a new insight into the industrial bioprocess of high-level GAMG production.
文摘The fish farming was introduced in Burundi in about 1950s. Actually, several fish ponds were abandoned and many others were still unproductive. This study aims to present current state and perspectives of the fish farming for its real contribution to the socio-economic development. The results presented are compilation of physical and chemical parameters series measured in fish ponds and inquiries led in 2010-2014 to the fish farmers in seven provinces (40% of the total area of the country). Weak values of some physical and chemical parameters showed that the majority of ponds are badly maintained. Thus, the dissolved oxygen values varied between 0.2 mg/L and 3.5 mg/L. The high relinquishment rate of the fish fanning (between 40% and 67% according to the provinces) could be explained by many constraints: no centers of fish farming breeding for various fish species and no production center of complete foods with local sub-products. About 75% of fish famers confirmed that they have never benefited framing in fish fanning. In spite of the diverse constraints, Burundi has a dense rivers system with favorable physical and chemical parameters and many appropriate sites for the fish farming. Thus, the main suggestions concern the sector reorganization.
文摘River estuarine environment plays a key role in the cycling of biological and chemical parameters and a significant region for the transaction of freshwater and seawater. In the present study, a first attempt has been made towards the development of a coupled three-dimensional hydrodynamic circulation model with four compartment (nitrate, phytoplankton, zooplankton and detritus) biogeochemical model in the Hooghly estuary (21 °36′-22° 16′1 and 87°42'-88°15′E) to simulate the varying effect of plankton biomass with the heavy input of anthropogenic litter from industrial effluents of Haldia port which is effecting the chemical and biological processes that control the plankton dynamics in the estuary. In-situ observational data for physico-chemical and biological parameters are collected from Calcutta University during 2010 are assimilated using multiscale OA (objective analysis) for different seasons and incorporated in ROMS (Regional Ocean Modeling System) to develop a high resolution (0.5 km x 0.5 kin) biogeochemical model. Recent analysis on physico-chemical parameters of the estuary is done as it is one of the largest estuaries in India and is the habitat for vast biodiversity. Influence of high nitrate (above 34 μg/L) and phosphate (5.22 μg/L) is predominant whereas DO (dissolved oxygen) is low (4.07 mg/L) in the Haldi River mouth which is sliding the productivity (less than 1 mg/L) and also affects water quality.
文摘Commercially, many methods are adopted for the production of the Virgin Coconut Oil (VCO). Nowadays, natural fermentation is widely employed to produce VCO in wet processing. But the problem in natural fermentation process has much contamination, due to surplus micro organisms present in natural environment, which leads to the poor quality of VCO. To overcome this, usage of probiotic organism like Lactobacillus fermentum is more beneficial for the fermentative production of VCO. Fermentation studies were conducted scientifically in computer controlled bioreactor to determine the effect of pH, temperature, inoculum concentration, oxygen requirement and incubation time on the yield of VCO. Yield efficiency of VCO in each parameter was determined. The pH of 5± 0.1, temperature at 45 ± 0.1 ~C, inoculum concentration of 2%, fermentation end time of 48 hrs and microaerophilic conditions are the most suitable parameters for the superior production of VCO.