研究了分子链中含有聚甲基丙烯酸(PMAA)链段的两亲性嵌段共聚物PS b PMAA和双亲水性嵌段共聚物PVP b PMAA,PVA b PMAA的溶液性质.结果显示,这些共聚物溶液都表现出明显的聚电解质溶液的性质,并且随着分子链中PMAA链段长度的增加,共聚物...研究了分子链中含有聚甲基丙烯酸(PMAA)链段的两亲性嵌段共聚物PS b PMAA和双亲水性嵌段共聚物PVP b PMAA,PVA b PMAA的溶液性质.结果显示,这些共聚物溶液都表现出明显的聚电解质溶液的性质,并且随着分子链中PMAA链段长度的增加,共聚物溶液的聚电解质溶液特征也随之增强,表明这些共聚物都是高分子电解质,其溶液粘度取决于其中MAA单元的比例.展开更多
We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substr...We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substrate is patterned with a rectangular array of nanoscale holes. Because of the high quality of the pattern, using neutron reflectometry, we are able to map the surface-normal density distribution of the patterned silicon, the penetration of water into the pattern, and the distribution of a deposited film inside and outside of the etched holes. In this stud; 1,2-dilauroyl-sn-glycero-3-phosphocholine （DLPC） single bilayers were deposited on the hydrophilic patterned surface. For bilayers deposited either by vesicle fusion （VF） or by the Langmuir-Schaefer （L-S） technique, the most consistent model found to fit the data shows that the lipids form bilayer coatings on top of the substrate as well as the bottoms of the holes in an essentially conformal fashion. However, while there is a single bilayer on the unetched silicon surface, the lipids coating the bottoms of the holes form a complex bimodal structure consistent with a rough surface produced by the etching process. This study provides insight into film transfer both outside and inside regular nanopatterned features.展开更多
文摘研究了分子链中含有聚甲基丙烯酸(PMAA)链段的两亲性嵌段共聚物PS b PMAA和双亲水性嵌段共聚物PVP b PMAA,PVA b PMAA的溶液性质.结果显示,这些共聚物溶液都表现出明显的聚电解质溶液的性质,并且随着分子链中PMAA链段长度的增加,共聚物溶液的聚电解质溶液特征也随之增强,表明这些共聚物都是高分子电解质,其溶液粘度取决于其中MAA单元的比例.
文摘We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substrate is patterned with a rectangular array of nanoscale holes. Because of the high quality of the pattern, using neutron reflectometry, we are able to map the surface-normal density distribution of the patterned silicon, the penetration of water into the pattern, and the distribution of a deposited film inside and outside of the etched holes. In this stud; 1,2-dilauroyl-sn-glycero-3-phosphocholine （DLPC） single bilayers were deposited on the hydrophilic patterned surface. For bilayers deposited either by vesicle fusion （VF） or by the Langmuir-Schaefer （L-S） technique, the most consistent model found to fit the data shows that the lipids form bilayer coatings on top of the substrate as well as the bottoms of the holes in an essentially conformal fashion. However, while there is a single bilayer on the unetched silicon surface, the lipids coating the bottoms of the holes form a complex bimodal structure consistent with a rough surface produced by the etching process. This study provides insight into film transfer both outside and inside regular nanopatterned features.
