The ordered bimodal mesoporous silica MCM-48 spheres were facile synthesized by mild- temperature post-synthesis H2O2 hydrothermal treatment of as-synthesized MCM-48. The results showed that H2O2 is indispensable for ...The ordered bimodal mesoporous silica MCM-48 spheres were facile synthesized by mild- temperature post-synthesis H2O2 hydrothermal treatment of as-synthesized MCM-48. The results showed that H2O2 is indispensable for simultaneously removing organic templates and forming ordered bimodal mesoporous silica MCM-48 spheres. The bimodal mesoporous MCM-48 was characterized by X-ray diffraction, transmission electron micrographs, FT-IR, and N2 adsorption-desorption, and a possible mechanism was proposed for the formation of bimodal mesoporous MCM-48.展开更多
A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the see...A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the seepage field and the concentration field were double,and the influences of sets,spaces,angles,continuity ratios,stiffnesses of fractures on the constitutive relationship of the medium were considered.Also,the relative two-dimensional program of finite element method was developed.Taking a hypothetical nuclear waste repository as a calculation example,the case in which the rockmass was unsaturated dual-porosity medium and radioactive nuclide leak was simulated numerically,and the temperatures,negative pore pressures,saturations,flow velocities,nuclide concentrations and principal stresses in the rockmass were investigated.The results show that the negative pore pressures and nuclide concentrations in the porosity and fracture present different changes and distributions.Even though the saturation degree in porosity is only about 1/10 that in fracture,the flow velocity of underground water in fracture is about three times that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity.The value of nuclide concentration in fracture is close to that in porosity.展开更多
In this paper, we consider Variational Iteration Method （VIM） and q-Homotopy Analysis Method （q-HAM） to sotve me partial differential equation resulted from Fingero Imbibition phenomena in double phase flow throug...In this paper, we consider Variational Iteration Method （VIM） and q-Homotopy Analysis Method （q-HAM） to sotve me partial differential equation resulted from Fingero Imbibition phenomena in double phase flow through porous media. We further compare the results obtained here with the solution obtained in [ 12] using Adomian Decomposition Method. Numerical results are obtained, using Mathematica 9, to show the effectiveness of these methods to our choice of problem especially for suitable values ofh and n.展开更多
A gas migration controlling equation was formulated based on the characteristics of the dual pore–fracture media of coal mass and in consideration of the matrix exchange between pores and fractures.A model of permeab...A gas migration controlling equation was formulated based on the characteristics of the dual pore–fracture media of coal mass and in consideration of the matrix exchange between pores and fractures.A model of permeability dynamic evolution was established by analyzing the variation in effective stress during gas drainage and the action mechanism of the effect of coal matrix desorption on porosity and fracture in the coal body.A coupling model can then be obtained to characterize gas compressibility and coal deformability under the gas–solid coupling of loading coal.In addition,a 3D model of boreholes was established and solved for gas drainage based on the relevant physical parameters of real mines.The comparison and analysis results for the law of gas migration and the evolution of coal body permeability around the boreholes before and after gas extraction between the dual media and the single-seepage field models can provide a theoretical basis for further research on the action mechanism of gas drainage.展开更多
基金supported by the National Natural Science Foundation of China(21337003,21477149)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB05050200)~~
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20872135） and the China National Tobacco Corporation （No.110200701007）.
文摘The ordered bimodal mesoporous silica MCM-48 spheres were facile synthesized by mild- temperature post-synthesis H2O2 hydrothermal treatment of as-synthesized MCM-48. The results showed that H2O2 is indispensable for simultaneously removing organic templates and forming ordered bimodal mesoporous silica MCM-48 spheres. The bimodal mesoporous MCM-48 was characterized by X-ray diffraction, transmission electron micrographs, FT-IR, and N2 adsorption-desorption, and a possible mechanism was proposed for the formation of bimodal mesoporous MCM-48.
基金Project(2010CB732101) supported by the National Basic Research Program of ChinaProject(51079145) supported by the National Natural Science Foundation of China
文摘A coupled thermo-hydro-mechanical-migratory model of dual-porosity medium for saturated-unsaturated ubiquitous-joint rockmass was established,in which the stress field and the temperature field were single,but the seepage field and the concentration field were double,and the influences of sets,spaces,angles,continuity ratios,stiffnesses of fractures on the constitutive relationship of the medium were considered.Also,the relative two-dimensional program of finite element method was developed.Taking a hypothetical nuclear waste repository as a calculation example,the case in which the rockmass was unsaturated dual-porosity medium and radioactive nuclide leak was simulated numerically,and the temperatures,negative pore pressures,saturations,flow velocities,nuclide concentrations and principal stresses in the rockmass were investigated.The results show that the negative pore pressures and nuclide concentrations in the porosity and fracture present different changes and distributions.Even though the saturation degree in porosity is only about 1/10 that in fracture,the flow velocity of underground water in fracture is about three times that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity.The value of nuclide concentration in fracture is close to that in porosity.
文摘In this paper, we consider Variational Iteration Method （VIM） and q-Homotopy Analysis Method （q-HAM） to sotve me partial differential equation resulted from Fingero Imbibition phenomena in double phase flow through porous media. We further compare the results obtained here with the solution obtained in [ 12] using Adomian Decomposition Method. Numerical results are obtained, using Mathematica 9, to show the effectiveness of these methods to our choice of problem especially for suitable values ofh and n.
基金supported by Chinese Ministry of Education (No.213022A)the National Natural Science Foundation of China (No.51574112)+4 种基金Henan Key Laboratory of Biogenic Traces and Sedimentary Minerals (No.OTMP1410)the Key Research Project of Higher Education Institution of Henan Province in 2015 (No.15A440001)the Doctor Funds of Henan Polytechnic University (No.B2015-05)the Basic and Advanced Technology Research Projects of Henan Province (No.162300410031)the Science and Technology Innovation Funds for Distinguished Young Scholar in Henan Province (No.164100510013)
文摘A gas migration controlling equation was formulated based on the characteristics of the dual pore–fracture media of coal mass and in consideration of the matrix exchange between pores and fractures.A model of permeability dynamic evolution was established by analyzing the variation in effective stress during gas drainage and the action mechanism of the effect of coal matrix desorption on porosity and fracture in the coal body.A coupling model can then be obtained to characterize gas compressibility and coal deformability under the gas–solid coupling of loading coal.In addition,a 3D model of boreholes was established and solved for gas drainage based on the relevant physical parameters of real mines.The comparison and analysis results for the law of gas migration and the evolution of coal body permeability around the boreholes before and after gas extraction between the dual media and the single-seepage field models can provide a theoretical basis for further research on the action mechanism of gas drainage.
