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甲醇荧光光谱的量子分析 被引量:5
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作者 陈肖静 朱拓 《光子学报》 EI CAS CSCD 北大核心 2008年第7期1433-1435,共3页
通过量子近似计算研究了甲醇的荧光光谱.将甲醇分子近似看成双原子分子,甲基和羟基分别为原子实,氧原子未共享电子对看成价电子.利用数值计算的方法对双原子分子电子能级差进行估算,得到电子能级差为一个仅与分子线度相关的函数.然后把... 通过量子近似计算研究了甲醇的荧光光谱.将甲醇分子近似看成双原子分子,甲基和羟基分别为原子实,氧原子未共享电子对看成价电子.利用数值计算的方法对双原子分子电子能级差进行估算,得到电子能级差为一个仅与分子线度相关的函数.然后把C-O键长作为分子线度代入前面得到的函数中,算出甲醇分子主跃迁能级差,并将所得结果与实验值进行对比,误差仅为2.2%,理论计算与实验结果吻合. 展开更多
关键词 荧光光谱 甲醇 量子理论 数值计算 双原子近似
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Electron-Helium Atom Collisions in the Presence of a Bichromatic Laser Field
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作者 ZHU Zun-Lue LIANG Ming-Chao SUN Jin-Feng 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第8期477-480,共4页
The differential cross section (DCS) for electron-helium atom collisions in the presence of a bichromatic CO2 laser field is investigated as a function of the scattering angle θ by employing first-Born approximati... The differential cross section (DCS) for electron-helium atom collisions in the presence of a bichromatic CO2 laser field is investigated as a function of the scattering angle θ by employing first-Born approximation (FBA) with a simple screening electric potential. We discuss in detail the influence of the scattering geometry, the photon energy and the number of photons exchanged on the DCSs. These illustrate that the three factors have important effects on the elastic scattering and the screening electric potential is effective. 展开更多
关键词 differential cross section bichromatic laser field first Born approximation scattering geometry
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