The authors give the solution to the problem of one-dimensional conso l idation of double-layered ground with the use of the differential quadrature me t hod. Case studies showed that the computational results for por...The authors give the solution to the problem of one-dimensional conso l idation of double-layered ground with the use of the differential quadrature me t hod. Case studies showed that the computational results for pore-water pressure in soil layer agreed with those of analytical solution; and that in the computat ional results for the interface of soil layer also agreed with those of the anal ytical solution except for the small discrepancies during shortly after the star t of computation. The advantages of the solution presented in this paper are tha t compared with the analytical solution, it avoids the cumbersome work in solvin g the transcendental equation for eigenvalues, and in the case of the Laplace transform s olution, it can resolve the precision problem in the numerical solution of long time inverse Laplace transform. Because of the matrix form of the solution in th is paper, it is convenient for formulating computational program for engineering practice. The formulas for calculating double-layered ground consolidation may be easily extended to the case of multi-layered soils.展开更多
This study deals with the enhanced solubilization of polycyclic aromatic hydrocarbons （PAHs） such as phenanthrene （PHE） and fluorene （FLR） in a pure cationic gemini （G6） and three conventional surfactants [pol...This study deals with the enhanced solubilization of polycyclic aromatic hydrocarbons （PAHs） such as phenanthrene （PHE） and fluorene （FLR） in a pure cationic gemini （G6） and three conventional surfactants [polyethylene glycol dodecyl ether （Brij35）, cetyltrimethyl ammonium bromide （CRAB） and sodium lauryl sulfate （SDS）] as well as in their equimolar binary combinations （G6-Brij35, G6-CTAB and G6-SDS）. Their solubilization efficiency toward PHE and FLR has been quantified in terms of the molar solubilization ratio （MSR） and the micelle-water partition coefficient （Kin）. The ideality/nonideality of the mixed micelles is discussed with the help of Clint, Rubingh and Rosen＇s approaches. These theories determine the deviation of experimental critical micelle concen- tration （CMC） values from ideal critical micelle concentration, which was measured by evaluating the interaction parameters （/3m and/3）. Negative values ofβm were observed in all the equimolar binary systems, which show synergism in the mixed micelles. Whereas at air/liquid interface synergism was observed in the systems G6-CrAB and G6-Brij35; G6-SDS exhibited an antagonistic effect. The order of MSR and Km was G6-CTAB 〉 G6- Brij35 〉 G6-SDS for phenanthrene as well as for fluorene.展开更多
文摘The authors give the solution to the problem of one-dimensional conso l idation of double-layered ground with the use of the differential quadrature me t hod. Case studies showed that the computational results for pore-water pressure in soil layer agreed with those of analytical solution; and that in the computat ional results for the interface of soil layer also agreed with those of the anal ytical solution except for the small discrepancies during shortly after the star t of computation. The advantages of the solution presented in this paper are tha t compared with the analytical solution, it avoids the cumbersome work in solvin g the transcendental equation for eigenvalues, and in the case of the Laplace transform s olution, it can resolve the precision problem in the numerical solution of long time inverse Laplace transform. Because of the matrix form of the solution in th is paper, it is convenient for formulating computational program for engineering practice. The formulas for calculating double-layered ground consolidation may be easily extended to the case of multi-layered soils.
文摘This study deals with the enhanced solubilization of polycyclic aromatic hydrocarbons （PAHs） such as phenanthrene （PHE） and fluorene （FLR） in a pure cationic gemini （G6） and three conventional surfactants [polyethylene glycol dodecyl ether （Brij35）, cetyltrimethyl ammonium bromide （CRAB） and sodium lauryl sulfate （SDS）] as well as in their equimolar binary combinations （G6-Brij35, G6-CTAB and G6-SDS）. Their solubilization efficiency toward PHE and FLR has been quantified in terms of the molar solubilization ratio （MSR） and the micelle-water partition coefficient （Kin）. The ideality/nonideality of the mixed micelles is discussed with the help of Clint, Rubingh and Rosen＇s approaches. These theories determine the deviation of experimental critical micelle concen- tration （CMC） values from ideal critical micelle concentration, which was measured by evaluating the interaction parameters （/3m and/3）. Negative values ofβm were observed in all the equimolar binary systems, which show synergism in the mixed micelles. Whereas at air/liquid interface synergism was observed in the systems G6-CrAB and G6-Brij35; G6-SDS exhibited an antagonistic effect. The order of MSR and Km was G6-CTAB 〉 G6- Brij35 〉 G6-SDS for phenanthrene as well as for fluorene.
