Exploration of new infrared(IR) nonlinear optical(NLO) materials is still in urgency owing to the indispensable roles in optoelectronic devices, resource exploration, and long-distance laser communication. The formida...Exploration of new infrared(IR) nonlinear optical(NLO) materials is still in urgency owing to the indispensable roles in optoelectronic devices, resource exploration, and long-distance laser communication. The formidable challenge is to balance the contradiction between wide band gaps and large second harmonic generation(SHG) effects in IR NLO materials. In the present work, we proposed new kinds of NLO active units, d^0 transition metal fluorooxofunctional groups for designing mid-IR NLO materials. By studying a series of d^0 transition metal oxyfluorides(TMOFs),the influences of fluorooxo-functional groups with different d^0 configuration cations on the band gap and SHG responses were explored. The results reveal that the fluorooxo-functional groups with different d^0 configuration cations can enlarge band gaps in mid-IR NLO materials. The first-principles calculations demonstrate that the nine alkali/alkaline earth metals d^0 TMOFs exhibit wide band gaps(all the band gaps >3.0 e V), large birefringence Δn(> 0.07), and two W/Mo TMOFs also exhibit large SHG responses. Moreover, by comparing with other fluorooxo-functional groups, it is found that introducing fluorine into building units is an effective way to enhance optical performance. These d^0 TMOFs with superior fluorooxo-functional groups represent a new exploration family of the mid-IR region, which sheds light on the design of mid-IR NLO materials possessing large band gap.展开更多
Bistatic SAR（Bi SAR）with illuminators of opportunity is a kind of flexible SAR system that consists of non-cooperative transmitters and a stationary or moving receiver,as Figure 1shows.In recent years,notable effort...Bistatic SAR（Bi SAR）with illuminators of opportunity is a kind of flexible SAR system that consists of non-cooperative transmitters and a stationary or moving receiver,as Figure 1shows.In recent years,notable efforts have been made to promote the development of this kind of system.Progress regarding Bi SAR with navigation satellites as transmitters before 2015,including the related theory and practice,has been well reviewed by Antoniou et al.and can be referred from[1].This paper reviews some of the progress in 2015and 2016,including novel signal processing approaches,advanced Bi SAR system configurations and potentially展开更多
基金supported by Tianshan Innovation Team Program (2018D14001)the National Natural Science Foundation of China (51922014 and 11774414)+2 种基金Shanghai Cooperation Organization Science and Technology Partnership Program (2017E01013)Xinjiang Program of Introducing High-Level Talents, Fujian Institute of Innovation, Chinese Academy of Sciences (FJCXY18010202)the Western Light Foundation of CAS (2017-XBQNXZ-B-006 and 2016QNXZ-B-9)
文摘Exploration of new infrared(IR) nonlinear optical(NLO) materials is still in urgency owing to the indispensable roles in optoelectronic devices, resource exploration, and long-distance laser communication. The formidable challenge is to balance the contradiction between wide band gaps and large second harmonic generation(SHG) effects in IR NLO materials. In the present work, we proposed new kinds of NLO active units, d^0 transition metal fluorooxofunctional groups for designing mid-IR NLO materials. By studying a series of d^0 transition metal oxyfluorides(TMOFs),the influences of fluorooxo-functional groups with different d^0 configuration cations on the band gap and SHG responses were explored. The results reveal that the fluorooxo-functional groups with different d^0 configuration cations can enlarge band gaps in mid-IR NLO materials. The first-principles calculations demonstrate that the nine alkali/alkaline earth metals d^0 TMOFs exhibit wide band gaps(all the band gaps >3.0 e V), large birefringence Δn(> 0.07), and two W/Mo TMOFs also exhibit large SHG responses. Moreover, by comparing with other fluorooxo-functional groups, it is found that introducing fluorine into building units is an effective way to enhance optical performance. These d^0 TMOFs with superior fluorooxo-functional groups represent a new exploration family of the mid-IR region, which sheds light on the design of mid-IR NLO materials possessing large band gap.
基金supported by the National Natural Science Foundation of China(Grant Nos.61120106004,61427802,61225005,61601031)ChangJiang Scholars Program(Grant No.T2012122)111 project of China(Grant No.B14010)
文摘Bistatic SAR（Bi SAR）with illuminators of opportunity is a kind of flexible SAR system that consists of non-cooperative transmitters and a stationary or moving receiver,as Figure 1shows.In recent years,notable efforts have been made to promote the development of this kind of system.Progress regarding Bi SAR with navigation satellites as transmitters before 2015,including the related theory and practice,has been well reviewed by Antoniou et al.and can be referred from[1].This paper reviews some of the progress in 2015and 2016,including novel signal processing approaches,advanced Bi SAR system configurations and potentially
