Novel transition metal complexes of bis(diarylsubstitutedthiophosphoryl)imines ligand derived from O,O-di(p-methoxylphenyl)thiophosphoryl chloride and O,O-di-(p-methoxylphenyl)thiophosphoryl amine with Cu(Ⅱ ),Co( Ⅱ)...Novel transition metal complexes of bis(diarylsubstitutedthiophosphoryl)imines ligand derived from O,O-di(p-methoxylphenyl)thiophosphoryl chloride and O,O-di-(p-methoxylphenyl)thiophosphoryl amine with Cu(Ⅱ ),Co( Ⅱ) ,Ni( Ⅱ) ,Fe(Ⅱ ) and Mn( Ⅱ ) were synthesized. The formation mechanism of complexes and their stereochemistry structures were investigated according to elemental analysis,infrared spectra and 31P-nuclear magnetic resonance spectra. The extractions of the ligand for different divalent metal ions,such as Zn(Ⅱ ),Cd( Ⅱ) ,Cu( Ⅱ) ,Ni( Ⅱ ),Fe( Ⅱ) ,Sn( Ⅱ) ,Mn( Ⅱ) ,Pd( Ⅱ) ,Hg( Ⅱ) and Fe(Ⅲ),were investigated in sulphate solution,respectively. The results show the metal atom is coordinated by 4 sulfur atoms in a square-planar fashion,and the titled compound has not only powerful ability to coordinate with cadmium from aqueous solution with a high extractive rate about 61.20% and a relatively weak complexation for other divalent metals with the extractive rate from 2.46% to 36.66%,but also a good selectivity to Fe(Ⅲ ).展开更多
基金Project([2004]52) supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars
文摘Novel transition metal complexes of bis(diarylsubstitutedthiophosphoryl)imines ligand derived from O,O-di(p-methoxylphenyl)thiophosphoryl chloride and O,O-di-(p-methoxylphenyl)thiophosphoryl amine with Cu(Ⅱ ),Co( Ⅱ) ,Ni( Ⅱ) ,Fe(Ⅱ ) and Mn( Ⅱ ) were synthesized. The formation mechanism of complexes and their stereochemistry structures were investigated according to elemental analysis,infrared spectra and 31P-nuclear magnetic resonance spectra. The extractions of the ligand for different divalent metal ions,such as Zn(Ⅱ ),Cd( Ⅱ) ,Cu( Ⅱ) ,Ni( Ⅱ ),Fe( Ⅱ) ,Sn( Ⅱ) ,Mn( Ⅱ) ,Pd( Ⅱ) ,Hg( Ⅱ) and Fe(Ⅲ),were investigated in sulphate solution,respectively. The results show the metal atom is coordinated by 4 sulfur atoms in a square-planar fashion,and the titled compound has not only powerful ability to coordinate with cadmium from aqueous solution with a high extractive rate about 61.20% and a relatively weak complexation for other divalent metals with the extractive rate from 2.46% to 36.66%,but also a good selectivity to Fe(Ⅲ ).
