The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a const...The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.展开更多
To optimize the distance between the bells in pile design,this paper reports a series of small scale tests on the uplift capacity of double belled piles embedded in dry dense sand considering different bell space rati...To optimize the distance between the bells in pile design,this paper reports a series of small scale tests on the uplift capacity of double belled piles embedded in dry dense sand considering different bell space ratios.Finite element modelling is also performed to evaluate the range of soil failure around the piles during pile uplift displacement.Test results show that when bell space ratio is 6 or 8,the uplift capacity reaches the peak value.The upper bell bears more load than the lower one for the piles with bell space ratio less than 6,while the lower bell bears more load than the upper one for the piles with bell space ratio larger than 8.展开更多
基金Project (2012CBA01202) supported by the National Basic Research Program of ChinaProject (51174184) supported by the National Natural Science Foundation of China+2 种基金Project (KGZD-EW-201-1) supported by the Key Research Program of the Chinese Academy of SciencesProject (BK2013030) supported by Science and Technology Plan of Nantong City,ChinaProject (RERU2014016) supported by Open Subject of Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,China
文摘The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.
基金Project(51778346) supported by the National Natural Science Foundation of ChinaProject(2019GSF111007) supported by the Key Research and Development Project of Shandong Province of China+1 种基金Project(ZR201808040034) supported by the Natural Science Foundation of Shandong Province of ChinaProject(2015RCJJ010) supported by the Talent Introduction Research Start-up Fund Project of Shandong University of Science and Technology,China。
文摘To optimize the distance between the bells in pile design,this paper reports a series of small scale tests on the uplift capacity of double belled piles embedded in dry dense sand considering different bell space ratios.Finite element modelling is also performed to evaluate the range of soil failure around the piles during pile uplift displacement.Test results show that when bell space ratio is 6 or 8,the uplift capacity reaches the peak value.The upper bell bears more load than the lower one for the piles with bell space ratio less than 6,while the lower bell bears more load than the upper one for the piles with bell space ratio larger than 8.
